A catalyst comprising a microporous crystalline metallosilicate having a Constraint Index of 12, or 10, or 8, or 6 or less, a binder, a Group 1 alkali metal or a compound thereof and/or a Group 2 alkaline earth metal or a compound thereof, a Group 10 metal or a compound thereof, and, optionally, a Group 11 metal or a compound thereof; wherein the catalyst is calcined in a first calcining step before the addition of the Group 10 metal or compound thereof and optionally the Group 11 metal or compound thereof; and wherein the first calcining step includes heating the catalyst to first temperatures of greater than 500° C.; and wherein the catalyst is calcined in a second calcining step after the addition of the Group 10 metal or compound thereof and optionally the Group 11 metal or compound thereof wherein the second calcining step includes heating the catalyst to temperatures of greater than 400° C.

A source material gas (31) is supplied to a catalyst (30), a first heating medium (21) is caused to flow through a first heat exchange section (22) so that a temperature of a surface of the first heat exchange section (22) on a catalyst side is maintained higher than a dew point of a reacted gas (32), a second heating medium (51) is caused to flow through a second heat exchange section (52) so that a temperature of a surface of the second heat exchange section (52) on a space (4) side is maintained not higher than the dew point of the reacted gas (32), and a liquid obtained by condensation in the space (4) is allowed to fall down so as to be separated from the source material gas.

A catalyst comprising a microporous crystalline metallosilicate having a Constraint Index of 12, or 10, or 8, or 6 or less, a binder, a Group 1 alkali metal or a compound thereof and/or a Group 2 alkaline earth metal or a compound thereof, a Group 10 metal or a compound thereof, and, optionally, a Group 11 metal or a compound thereof; wherein the catalyst is calcined in a first calcining step before the addition of the Group 10 metal or compound thereof and optionally the Group 11 metal or compound thereof; and wherein the first calcining step includes heating the catalyst to first temperatures of greater than 500° C.; and wherein the catalyst is calcined in a second calcining step after the addition of the Group 10 metal or compound thereof and optionally the Group 11 metal or compound thereof wherein the second calcining step includes heating the catalyst to temperatures of greater than 400° C.

The invention relates to synthesis of methyl carbamate (MC) and dimethyl carbonate (DMC) in presence of stripping inert gas or superheated methanol vapors using packed column reactor and bubble column reactor.

A reactor apparatus for loading a carrier medium with hydrogen and/or unloading it therefrom includes a reactor housing chargeable with carrier medium and having a carrier medium feed orifice, having a carrier medium removal orifice, having a base and having a hydrogen gas orifice. The reactor apparatus further includes at least one heat transfer element for supplying heat into the reactor housing. Catalyst has been provided in the reactor housing.

A reactor includes a reaction unit, a first pipe, a second pipe, a composition analysis unit connected to the first pipe, a regulating unit connected to the second pipe so as to regulate a flow rate or the like of a second fluid, a control unit causing the regulating unit to regulate the flow rate or the like of the second fluid in accordance with a composition of a product analyzed by the composition analysis unit so that a temperature of a third fluid is controlled to lead the composition of the product to keep a predetermined reaction rate or yield, and a first temperature measurement unit connected to the first pipe so as to measure the temperature of the third fluid. The control unit acquires the information on the temperature of the third fluid from the first temperature measurement unit.

A reactor includes a reaction unit, a first pipe, a second pipe, a composition analysis unit connected to the first pipe, a regulating unit connected to the second pipe so as to regulate a flow rate or the like of a second fluid, a control unit causing the regulating unit to regulate the flow rate or the like of the second fluid in accordance with a composition of a product analyzed by the composition analysis unit so that a temperature of a third fluid is controlled to lead the composition of the product to keep a predetermined reaction rate or yield, and a first temperature measurement unit connected to the first pipe so as to measure the temperature of the third fluid. The control unit acquires the information on the temperature of the third fluid from the first temperature measurement unit.

A heat treatment device causing a first fluid and a second fluid to flow therethrough includes heat transfer bodies including first flow channels through which the first fluid flows and second flow channels through which the second fluid flows adjacent to the first flow channels without contact, and pipe-like members detachably placed in the first flow channels and each including a pipe wall having an outer wall surface conforming to a wall surface defining each first flow channel and an inner wall surface with which the first fluid comes into contact.

An apparatus for hydrocarbon conversion, the apparatus including a reactor and a reactor insert secured and disposed within an interior cavity of the reactor, is described. The reactor is configured to permit addition of a feed stream comprising a hydrocarbon at an upstream end of the reactor and to permit discharge of a product stream at a downstream end of the reactor. The reactor insert is configured to provide heat to the interior cavity to promote conversion of hydrocarbons as the feed stream moves from the upstream end of the reactor to the downstream end of the reactor. The products of the conversion reaction are discharged at the downstream end as part of the product stream. A method for hydrocarbon conversion using the apparatus is also described.

A reactor apparatus for loading a carrier medium with hydrogen and/or unloading it therefrom includes a reactor housing chargeable with carrier medium and having a carrier medium feed orifice, having a carrier medium removal orifice, having a base and having a hydrogen gas orifice. The reactor apparatus further includes at least one heat transfer element for supplying heat into the reactor housing. Catalyst has been provided in the reactor housing.