Disclosed herein is a solar thermochemical reactor comprising an outer member, an inner member disposed within an outer member, wherein the outer member surrounds the inner member and wherein the outer member has an aperture for receiving solar radiation and wherein an inner cavity and an outer cavity are formed by the inner member and outer member and a reactive material capable of being magnetically stabilized wherein the reactive material is disposed in the outer cavity between the inner member and the outer member.

Disclosed herein is a solar reactor comprising a reactor member; an aperture for receiving solar radiation, the aperture being disposed in a plane on a wall of the reactor member, where the plane is oriented at any angle other than parallel relative to the centerline of the reactor member; a plurality of absorber tubes, wherein the absorber tubes are oriented such that their respective centerlines are at an angle other than 90° relative to the centerline of the reactor member; and wherein the aperture has a hydraulic diameter that is from 0.2 to 4 times a hydraulic diameter of at least one absorber tube in the plurality of absorber tubes; and a reactive material, the reactive material being disposed in the plurality of absorber tubes.

Disclosed herein is a composite particle comprising a first non-metallic particle in which is dispersed a second non-metallic particle, where the first non-metallic particle and the second non-metallic particle are inorganic; and where a chemical composition of the first non-metallic particle is different from a chemical composition of the second non-metallic particle; and where the first non-metallic particle and the second non-metallic particle are metal oxides, metal carbides, metal nitrides, metal borides, metal silicides, metal oxycarbides, metal oxynitrides, metal boronitrides, metal carbonitrides, metal borocarbides, or a combination thereof.

A method for producing plasmonic nanomaterials that are catalytically or photocatalytically active by fabricating plasmonic nanostructures on substrates using electrodeposition into a nano-template structure and forming a plurality of nanorods in an array, wherein the nanorods are made from materials chosen from the group consisting of materials that are plasmonic and/or catalytic, and materials that are catalytically activated by depositing pure elemental metals, alloys, or alternating layers of different metals or alloys, and producing catalytic plasmonic nanomaterials. Catalytic plasmonic nanomaterials made from the above method. An optical reactor device that utilizes catalytic nanomaterials for photocatalytic synthesis of methanol or ammonia. A method of photocatalytic synthesis of methanol and ammonia by using catalytic plasmonic nanomaterial to convert CO.sub.2 and H.sub.2 to methanol and N.sub.2 and H.sub.2 to ammonia using optical power. A hybrid plasma-plasmonic reactor for the utilization of CO.sub.2 and CH.sub.4 to produce methanol, ethylene, and acetic acid.

Disclosed herein is a solar reactor comprising a reactor member; an aperture for receiving solar radiation, the aperture being disposed in a plane on a wall of the reactor member, where the plane is oriented at any angle other than parallel relative to the centerline of the reactor member; a plurality of absorber tubes, wherein the absorber tubes are oriented such that their respective centerlines are at an angle other than 90° relative to the centerline of the reactor member; and wherein the aperture has a hydraulic diameter that is from 0.2 to 4 times a hydraulic diameter of at least one absorber tube in the plurality of absorber tubes; and a reactive material, the reactive material being disposed in the plurality of absorber tubes.

Disclosed herein is a solar reactor comprising a reactor member; an aperture for receiving solar radiation, the aperture being disposed in a plane on a wall of the reactor member, where the plane is oriented at any angle other than parallel relative to the centerline of the reactor member; a plurality of absorber tubes, wherein the absorber tubes are oriented such that their respective centerlines are at an angle other than 90 relative to the centerline of the reactor member; and wherein the aperture has a hydraulic diameter that is from 0.2 to 4 times a hydraulic diameter of at least one absorber tube in the plurality of absorber tubes; and a reactive material, the reactive material being disposed in the plurality of absorber tubes.

The present invention relates to a process for performing a chemical reaction consisting of at least two sequential reversible steps characterized by being performed in a cycle, and to a reactor for performing such process.

A zero-emission, closed-loop and hybrid solar-produced syngas power cycle is introduced utilizing an oxygen transport reactor (OTR). The fuel is syngas produced within the cycle. The separated oxygen inside the OTR through the ion transport membrane (ITM) is used in the syngas-oxygen combustion process in the permeate side of the OTR. The combustion products in the permeate side of the OTR are CO.sub.2 and H.sub.2O. The combustion gases are used in a turbine for power production and energy utilization then a condenser is used to separate H.sub.2O from CO.sub.2. CO.sub.2 is compressed to the feed side of the OTR. H.sub.2O is evaporated after separation from CO.sub.2 and fed to the feed side of the OTR.

The present invention relates to photocatalytic materials for use in the conversion of CO.sub.2 to non-CO.sub.2 carbon containing products. The photocatalytic materials comprise a metal nanofiber and a carbon-based nanostructure bound to the surface of the metal nanofiber. Methods for preparing such materials are described, as well as their use in the conversion of CO.sub.2 to non-CO.sub.2 carbon containing products. For example, the photocatalytic materials of the invention may be used to convert CO.sub.2 to methanol and/or ethanol with high conversion rates.

A heat receiver, a reactor, and a heater utilize the heat of concentrated solar light for thermal decomposition and/or chemical reaction of coals, etc. The heat receiver includes: a side portion forming a substantially cylindrical side surface; a substantially circular bottom portion connected to the lower edge of the side portion; and a ceiling connected to the upper edge of the side portion. A substantially circular aperture is formed in the center of the ceiling. The heat receiver has a substantially cylindrical cavity and the opening portion is open. When the cavity has a diameter of D and a length of L, and the aperture has a diameter of d, d=D/2 or less and L=2D or more. Concentrated solar light entering the heat receiver is to be contained in the heat receiver to effectively utilize the solar light.