Disclosed are apparatuses, systems, methods, and devices for generating hydrogen pyrolysis of hydrocarbons (methane, diesel, JP8, etc.) in a reactor. The reactor includes multiple channels in parallel. A hydrocarbon flows in a channel and decomposes into hydrogen and carbon. Hydrogen gas flows out and some of the carbon will deposit on the channel wall. Once carbon deposition reaches a predetermined level, the hydrocarbon flow stops, and air or oxygen is caused to flow into the channels to oxidize carbon into carbon monoxide or carbon dioxide and supply heat to neighboring channels. Simultaneously, the hydrocarbon will flow into neighboring channels causing decomposition into hydrogen and carbon in the neighboring channels. When the carbon coating in the neighboring channels reaches a predetermined level, the gas flow is switched again to air or oxygen. In this way, each channel alternates between decomposing the hydrocarbon and oxidizing the deposited carbon.

An apparatus and a method are used for investigating the naphtha reforming process in catalyst test devices with reactors arranged in parallel. The apparatus has a plurality of reactors arranged in parallel with reaction chambers (R1, R2, . . . ), a product fluid supply, a process control, and at least one analysis unit. Each individual reactor has an outlet line for the product fluid stream, wherein the analysis unit is operatively connected to each outlet line for the product fluid stream and the apparatus is functionally connected to the control of the apparatus. In carrying out the method, naphtha-containing reactant fluid streams are brought into contact with catalysts in the individual reactors and the product fluid streams are subsequently supplied to the online analysis unit from the respective outlet lines of the individual reactors and analyzed. Using the evaluation of the online analytical characterization data, the process parameters of the respective reactor unit are adapted. The process steps of analytical characterization, evaluation, and adaptation of process parameters are repeated for the duration of the investigation.

Devices and methods for controlling the properties of chemical species during time-dependent processes. A device includes a reactor for containing one or more chemical species of a time-dependent process, an extraction pump for automatically and continuously extracting an amount of the one or more chemical species from the reactor, one or more detectors for measuring property changes of the one or more extracted chemical species and generating a continuous stream of data related to the one or more property changes to the one or more chemical species during a time interval, and a process controller configured to fit the continuous stream of data to a mathematical function to predict one or more properties of the one or more chemical species at a future time point and make one or more process decisions based on the prediction of one or more properties at the future time point.

Provided herein is a gas mixer for the safe mixing of a hydrocarbon containing gas with a gaseous oxidant. The gas mixer and method for mixing described includes a closed mixing vessel where bubbles of gas injected at the bottom of the vessel are mixed during their rise to the top of the vessel, forming a homogeneous mixture that can safely be removed. This simple design and method allows for safe mixing of gases and is applicable to catalytic oxidative processes such as oxidative dehydrogenation of paraffins where there is a risk of thermal runaway of reactions.

A process for the production of syngas comprising the steps of providing a feed gas comprising a hydrocarbon, carbon dioxide and optionally steam, contacting a flow of said feed gas with a metal oxide to form syngas, wherein the mole fraction of carbon dioxide or in the case the feed gas comprises steam, the sum of the mole fractions of carbon dioxide and steam, in the feed gas is between 0.3 and 0.7; and/or wherein the mole fraction of the hydrocarbon in the feed gas is between 0.3 to 0.5, wherein the feed gas is contacted with the metal oxide at a temperature of between 1050K and 1600K.

The invention relates to a system for producing polyolefin. The system comprises a gas phase reactor (1) for polymerizing an olefin to obtain polymerization product. The gas phase reactor (1) comprises a gas distribution plate (11) arranged inside the gas phase reactor (1); a first outlet (12) for continuously withdrawing polymerization product from the gas phase reactor (1) as a first product stream, the first outlet (12) being arranged above the gas distribution plate (11); and a second outlet (13) for continuously withdrawing polymerization product from the gas phase reactor (1) as a second product stream, the second outlet (13) being arranged above the gas distribution plate (11). The system further comprises a first outlet tank (2) in fluid communication with the first outlet (12) via a first passage (22), wherein the first passage (22) comprises a first valve means (221) for controlling the flow of the first product stream in the first passage (22) and wherein the first outlet tank (2) is arranged to receive the first product stream and to concentrate the first product stream; a product receiver tank (3) in fluid communication with the second outlet (13) via a second passage (31), wherein the second passage (31) comprises a second valve means (311) for controlling the flow of the second product stream in the second passage (31), and wherein the product receiver tank (3) is arranged to receive the second product stream; and a control means in communication with the first valve means (221) and the second valve means (311) and arranged to control the operation of the first valve means (221) and the second valve means (311) so that flow in only one of the first passage (22) and the second passage (31) is allowed at a time.

The invention relates also to a process for recovering polymerization product from a gas phase reactor (1). The gas phase reactor (1) is suitable for polymerizing an olefin to obtain polymerization product and comprises a gas distribution plate (11) arranged inside the gas phase reactor (1); a first outlet (12) for continuously withdrawing polymerization product from the gas phase reactor (1), the first outlet (12) being arranged above the gas distribution plate (11); and a second outlet (13) for continuously withdrawing polymerization product from the gas phase reactor (1), the second outlet (13) being arranged above the gas distribut

A fluid flow conduit according to one embodiment comprises: a body comprising a channel-defining surface which defines a principal flow channel extending in a longitudinal direction, wherein the body defines an interior flow region comprising the principal flow channel; an inlet for introducing fluid into the interior flow region, the inlet shaped so that an average velocity of fluid entering the interior flow region from the inlet is oriented in an inlet flow direction non-parallel to the longitudinal direction; and an outlet for conveying fluid out of the principal flow channel, the outlet spaced apart from the inlet in the longitudinal direction such that fluid that passes from the inlet to the outlet passes through at least a portion of the principal flow channel; wherein the fluid flow conduit defines a recess in the interior flow region and facing the inlet.

Systems and methods are provided for improving the operation of groups of reverse flow reactors by operating reactors in a regeneration portion of the reaction cycle to have improved flue gas management. The flue gas from reactor(s) at a later portion of the regeneration step can be selectively used for recycle back to the reactors as a diluent/heat transport fluid. The flue gas from a reactor earlier in a regeneration step can be preferentially used as the gas vented from the system to maintain the desired volume of gas within the system. This results in preferential use of higher temperature flue gas for recycle and lower temperature flue gas for venting from the system. This improved use of flue gas within a reaction system including reverse flow reactors can allow for improved reaction performance while reducing or minimizing heat losses during the regeneration portion of the reaction cycle.

A carbon compound manufacturing system includes: a recovery unit; a conversion unit; a synthesis unit; a first flow path to supply the supply gas to the recovery unit; a second flow path connecting the recovery and the conversion units; a third flow path connecting the conversion and the synthesis units; at least one of first to third detectors to respectively measure a flow rate of the supply gas flowing through the first flow path to generate a first data signal, a flow rate of the carbon dioxide flowing through the second flow path to generate a second data signal, and a value of voltage or current to the conversion unit to generate a third data signal; and an integration controller to collate at least one data of the first to third data signals with a corresponding plan data to generate at least one of first to third control signals.

Described herein are two-stage catalytic heating systems and methods of operating thereof. A system comprises a first-stage catalytic reactor and a second-stage catalytic reactor, configured to operate in sequence and at different operating conditions, For example, the first-stage catalytic reactor is supplied with fuel and oxidant at fuel-rich conditions. The first-stage catalytic reactor generates syngas. The syngas is flown into the second-stage catalytic reactor together with some additional oxidant. The second-stage catalytic reactor operates at fuel-lean conditions and generates exhaust. Splitting the overall fuel oxidation process between the two catalytic reactors allows operating these reactors away from the stoichiometric fuel-oxidant ratio and avoiding excessive temperatures in these reactors. As a result, fewer pollutants are generated during the operation of two-stage catalytic heating systems. For example, the temperatures are maintained below 1.000° C. at all oxidation stages.