A method for removing contaminants from a gas stream including contacting a gas stream comprising hydrocarbons and sulfur contaminants with a modified nanocomposite adsorbent. Also provided are compositions and processes for forming compositions of a modified nanocomposite adsorbent composition for removing sulfur contaminants from a hydrocarbon stream. Additionally, provided is system for removing sulfur impurities from a gaseous hydrocarbon stream, where the system includes a plurality of adsorbent vessels arranged in series, where the adsorbent vessels include an emulsion of a modified nanocomposite adsorbent composition.

A polymer/activated carbon composite made up of a branched polyethylenimine and magnetic cores involving Fe.sub.3O.sub.4 disposed activated carbon. The magnetic cores have activated carbonyl groups on the surface. A process for removing organic dyes, such as methyl red, as well as heavy metal ions from a polluted aqueous solution or an industrial wastewater utilizing the composite is introduced. A method of synthesizing the polymer/activated carbon composites is also specified.

The invention relates to a process for preparing core-shell particles comprising the steps of (i) providing a dispersion of primary magnetic particles having a mean diameter lower than 200 nm in a solvent; (ii) adding one or more (semi-)metal (oxyhydr)oxide(s) and/or one or more precursor(s) of a (semi-)metal (oxyhydr)oxide to said dispersion; (iii) optionally adding a hydrolysis agent for said one or more precursor(s); (iv) injecting the dispersion in a spray dryer; whereby a (semi-)metal (oxyhydr)oxide shell is formed on the magnetic particles during spray drying. The invention also relates to particles obtainable by said process, to a formulation of said particles in a solvent and to the use of said particles or said formulation for RNA or DNA extraction.

A modified natural sulfide ore material, a preparation method, and a use thereof are disclosed. A natural sulfide ore and a copper salt are used as raw materials. The natural sulfide ore is modified through mechanical grinding for activation, drying, and the like to synthesize a sulfide ore composite. The copper salt is subjected to a reaction to increase metal sites, produce fine microcrystalline particles, and change the crystal structure, such that active sites can be fully exposed. When contacting mercury in a gas phase and/or a liquid phase, the modified natural sulfide ore material can convert the mercury into a stable compound to realize the immobilization and removal of the mercury, which has advantages such as large mercury adsorption capacity, high adsorption rate, wide application temperature range, low cost, abundant raw material reserves, simple operation, and environmentally-friendly mercury removal products without secondary pollution and shows promising industrial application prospects.

A graphene coated crushed glass particle adsorbent is provided for the removal of heavy metals and other contaminants in from solutions such as wastewaters, contaminated surface water and groundwater. The adsorbent comprises crushed (e.g. recycled) glass coated with graphene nano-sheets using a staged thermal binding process and the silicas in the glass as a catalyst. The adsorbent may be configured for use in both in-situ and ex-situ treatment systems and is capable of removing heavy metals and other inorganic and organic contaminants. The strong adsorptive bond between contaminants and the graphene coating on crushed glass particles can also lead to alternative applications of the end of life adsorbent, such as base material in road and pavement (e.g. cement-like) construction materials.

Methods of sulfurizing metal containing particles in the absence of hydrogen are described. One method includes contacting a bed of metal containing particles with a gaseous stream comprising hydrogen sulfide and inert gas under reaction conditions sufficient to produce sulfided metal containing particles. The gaseous stream is introduced into a vertical reactor at an inlet positioned at the bottom portion of the reactor and any unreacted hydrogen sulfide and inert gas is removed at an outlet positioned above the inlet. The sulfided metal containing particles can be removed from the reactor and stored.

Methods for purifying biological macromolecules are provided. Aspects of the subject methods include contacting the biological macromolecule with an exemplary hydroxamate affinity tag to produce a tagged moiety followed by purification of the tagged moiety by immobilized metal affinity chromatography (IMAC). Also provided are kits comprising an exemplary subject hydroxamate affinity tag, an IMAC resin and a metal ion configured for loading onto the resin, wherein the metal ion is capable of binding to a compound containing the hydroxamate affinity tag.

The present invention relates to a method of synthesis of zeolitic LTA adsorbents containing intercrystalline mesoporosity and controlled particle size, which can, for example, be used in natural gas dehydration processes, seeking to comply not only with the specifications on moisture content in the natural gas, but also improving the efficiency of the gas drying process in regard to the adsorption kinetics, not compromising the adsorption capacity, water selectivity, and the regeneration cycles of the adsorbent. Another possible application of these compounds is as the support for catalysts for oil refining processes. The method of obtaining the zeolitic adsorbent solids, the purpose of this invention, consists of including an aging step of the reaction mixture in conjunction with the addition of N,N-dimethyl-N-[3-(trimethoxysilane)propyl]octadecyl ammonium chloride (TPOAC) to the reaction mixture.

An adsorbent is provided which can improve the fluorine adsorption capacity and the breakthrough time compared with conventional adsorbents, particularly an adsorbent which can be suitably used as a fluorine adsorbent. The adsorbent comprises rare earth compound particles comprising a rare earth oxycarbonate or a hydrate thereof.

Methods of sulfurizing metal containing particles in the absence of hydrogen are described. One method includes contacting a bed of metal containing particles with a gaseous stream comprising hydrogen sulfide and inert gas under reaction conditions sufficient to produce sulfided metal containing particles. The gaseous stream is introduced into a vertical reactor at an inlet positioned at the bottom portion of the reactor and any unreacted hydrogen sulfide and inert gas is removed at an outlet positioned above the inlet. The sulfided metal containing particles can be removed from the reactor and stored.