The present invention concerns a catalyst and pre-treatment process for acidic charges consisting of sulfated zirconia and cerium for the production of biofuels, characterized in that the catalyst has greater activity and resistance to deactivation with acidic charges.

A composition for coating an overhead conductor is disclosed comprising: (i) a reflective agent; (ii) a photocatalytic 0 agent comprising ≥70 wt % anatase titanium dioxide (TiO.sub.2) having an average particle size (“aps”)≤100 nm; (iii) a polyorganosiloxane binder; and (iv) a superhydrophobic agent comprising either: surface functionalised silica nanoparticles, a functional polysiloxane or a polymethylsilsesquioxane.

A composition for coating an overhead conductor is disclosed comprising: (i) a reflective agent; (ii) a photocatalytic 0 agent comprising ≥70 wt % anatase titanium dioxide (TiO.sub.2) having an average particle size (“aps”)≤100 nm; (iii) a polyorganosiloxane binder; and (iv) a superhydrophobic agent comprising either: surface functionalised silica nanoparticles, a functional polysiloxane or a polymethylsilsesquioxane.

The present invention is related to the isomerization process in which a light naphtha stream comprising of paraffinic (mono and single branched), naphthenic and aromatic hydrocarbons in the range of C.sub.5-C.sub.7 is contacted with the solid catalyst in multiple reaction zones and in presence of hydrogen to produce high octane gasoline predominantly comprising of paraffins (single and di-branched) and naphthenes. The process scheme comprises of more than one isomerization reaction section operating at different temperatures and other operating conditions. The catalyst employed in these reaction sections is a high coordination sulfated mixed metal oxide catalyst which contains at least one noble metal and sulfated zirconia in addition to the other components. The process of the present invention also comprises more than one fractionation section and recycling of a particular stream to the reaction zone for improving the isomerization of light naphtha.

The present invention provides an exhaust gas purification catalyst including an alkaline earth metal supported in a highly dispersed state on a porous carrier. A catalyst layer of the exhaust gas purification catalyst provided by the invention has an alkaline earth metal-supporting region including a porous carrier, a catalyst metal belonging to the platinum group, and a sulfate of at least one type of alkali earth metal supported on the porous carrier. In a cross-section of this region, a Pearson correlation coefficient R.sub.Ae/M is at least 0.5 as calculated using α and β for each pixel obtained by carrying out area analysis by FE-EPMA under conditions of pixel size of 0.34 μm×0.34 μm, and measured pixel number 256×256, and by measuring the characteristic X-ray intensity (α:cps) of the alkaline earth metal element (Ae) and the characteristic X-ray intensity (β:cps) of the main constituent element of the inorganic compound constituting the porous carrier for each pixel.

The present invention provides an exhaust gas purification catalyst including an alkaline earth metal supported in a highly dispersed state on a porous carrier. A catalyst layer of the exhaust gas purification catalyst provided by the invention has an alkaline earth metal-supporting region including a porous carrier, a catalyst metal belonging to the platinum group, and a sulfate of at least one type of alkali earth metal supported on the porous carrier. In a cross-section of this region, a Pearson correlation coefficient R.sub.Ae/M is at least 0.5 as calculated using α and β for each pixel obtained by carrying out area analysis by FE-EPMA under conditions of pixel size of 0.34 μm×0.34 μm, and measured pixel number 256×256, and by measuring the characteristic X-ray intensity (α:cps) of the alkaline earth metal element (Ae) and the characteristic X-ray intensity (β:cps) of the main constituent element of the inorganic compound constituting the porous carrier for each pixel.

A method 10 for processing hydrocarbons for recycling includes the steps of: a) heating solid and/or liquid hydrocarbons in a chamber 16 in the absence of air, to convert at least some of the hydrocarbons into hydrocarbon gas; b) reacting the hydrocarbon gas in a reactor 20 or conduit with a catalyst 22 including a transition metal or transition metal salt, and a carbide, to break the hydrocarbon gas down into hydrocarbon products; and c) collecting the hydrocarbon products or conveying the hydrocarbon products elsewhere for use.

A cerium-zirconium based mixed oxide composition have: (a) a Ce:Zr molar ratio of 1 or less, and (b) a cerium oxide content of 10-50% by weight. The composition has (i) a surface area of at least 18 m.sup.2/g, and a total pore volume as measured by N.sub.2 physisorption of at least 0.11 cm.sup.3/g, after ageing at 1100° C. in an air atmosphere for 6 hours, (ii) a surface area of at least 42 m.sup.2/g, and a total pore volume as measured by N.sub.2 physisorption of at least 0.31 cm.sup.3/g, after ageing at 1000° C. in an air atmosphere for 4 hours, and (iii) Dynamic Oxygen Storage Capacity (D-OSC) value as measured by H.sub.2-TIR of greater than 500 μmol/g at 600° C. after aging at 800° C. in an air atmosphere for 2 hours. A process contacts the exhaust gas with the composition Another process is for preparing the composition.

A method of removing CO from a mixture of CO and saturated and unsaturated hydrocarbons CO to CO.sub.2 is provided. In one embodiment, the method is to contact feed stream with an oxygen transfer agent; and then oxidize at least a portion of the CO to CO.sub.2 to produce a stream enriched in CO.sub.2. The saturated and unsaturated hydrocarbons in the feed are not further oxidized during the oxidation. The oxygen transfer agent includes at least one of: i) water; ii) at least one reducible metal oxide; iii) at least one reducible chalcogen; or mixtures thereof. In another embodiment, the CO is converted to methane. The unsaturated hydrocarbons in the feed are not hydrogenated. In both of these alternatives, the CO.sub.2 or methane are then removed. Systems for removing the CO are also provided.

A method of removing CO from a mixture of CO and saturated and unsaturated hydrocarbons CO to CO.sub.2 is provided. In one embodiment, the method is to contact feed stream with an oxygen transfer agent; and then oxidize at least a portion of the CO to CO.sub.2 to produce a stream enriched in CO.sub.2. The saturated and unsaturated hydrocarbons in the feed are not further oxidized during the oxidation. The oxygen transfer agent includes at least one of: i) water; ii) at least one reducible metal oxide; iii) at least one reducible chalcogen; or mixtures thereof. In another embodiment, the CO is converted to methane. The unsaturated hydrocarbons in the feed are not hydrogenated. In both of these alternatives, the CO.sub.2 or methane are then removed. Systems for removing the CO are also provided.