The present application relates to a cerium-tin-based composite oxide catalyst for catalyzing purification of a nitrogen oxide, a preparation method and an application thereof. The catalyst has the following chemical composition: a cerium-tin oxide and an M oxide, wherein the M is selected from any one of or a combination of at least two of P, Ti, Zr, V, Mn, Fe, Cu, Al, Si, Ni, Hf, Nb, Ta, Cr, Mo, W, or Re. According to the present application, a cerium-tin-based composite oxide catalyst having the characteristics such as high catalytic activity, high hydrothermal stability, excellent N.sub.2 generation selectivity, a wide operation temperature window, and adaptation to high space velocity reaction conditions is prepared by means of a non-toxic and harmless raw material and a simple method, and the present application is applicable to a device for catalyzing purification of a mobile source nitrogen oxide represented by diesel vehicle exhaust gas and a fixed source nitrogen oxide represented by flue gas from a coal-fired power plant.

The present disclosure discloses a simple preparation method of green acid-modified cyclodextrin, belonging to the field of cyclodextrin modification. Cyclodextrin and succinic acid are mutually modified by an esterification reaction in the presence of catalyst, and acid-modified cyclodextrin with different modification degrees is obtained by controlling reaction time at a high temperature or under a microwave action. The prepared modified cyclodextrin does not involve the use of toxic and harmful reagents, the modification reaction is simple, green and controllable, and the loading capacity of the modified cyclodextrin to guest molecules is remarkably improved compared with the loading capacity of the original cyclodextrin, so that the modified cyclodextrin has great application potential in the health fields such as food, medicines, and cosmetics.

An object of the present invention is to provide an exhaust gas purification catalyst having improved exhaust gas purifying performance (in particular, improved NOx purifying performance) at low to medium temperature, and, in order to achieve the object, the present invention provides an exhaust gas purification catalyst (10A) including: a substrate (20); and a catalyst layer (30 or 40) formed on the substrate (20), wherein the catalyst layer (30 or 40) contains rhodium element, phosphorus element and a rare earth element other than cerium element, wherein a ratio of a mass of the phosphorus element contained in the catalyst layer (30 or 40) to the mass of the rhodium element contained in the catalyst layer (30 or 40) is from 1 to 10, and wherein a ratio of a mass of the rare earth element other than cerium element in terms of an oxide thereof contained in the catalyst layer (30 or 40) to the mass of the rhodium element contained in the catalyst layer (30 or 40) is from 1 to 5.

Provided are self-binding suspensions and coated substrates prepared using self-binding suspensions. Also provided are methods of preparing self-binding suspensions. Methods may include preparing a binder solution; preparing a titanium dioxide-zinc oxide suspension using ultrasonication; mixing the binder solution with the titanium dioxide-zinc oxide suspension and a surfactant to form a self-binding suspension composition; and coating a glass substrate with the self-binding suspension composition to form a coated glass substrate.

Disclosed herein is a method of treating an aqueous solution containing impurities including a perfluoroalkyl substance and/or a polyfluoroalkyl substance, comprising introducing the aqueous solution into a batch or semi-batch photocatalytic reactor with a microparticulate catalyst configured to reduce chain length of the perfluoroalkyl substance and/or polyfluoroalkyl substance, forming a treated aqueous stream, the reactor including a catalyst flow controller configured to automatically increase the catalyst concentration in the reactor while agitating the catalyst-containing solution during reaction, and removing catalyst particles from the treated aqueous stream to form a purified aqueous stream. In some cases, the feed to the reactor is atomized. Corresponding systems also are disclosed.

The present invention relates to the technical field of flue gas denitration catalysts, and discloses a hydrogenated TiO.sub.2 denitration catalyst and a preparation method and use thereof. The hydrogenated TiO.sub.2 denitration catalyst has a crystal form of anatase form, with oxygen vacancies and surface hydroxyl groups; wherein the hydrogenated TiO.sub.2 denitration catalyst contains TiO.sub.2, SO.sub.3 and P.sub.2O.sub.5, and based on the total weight of the hydrogenated TiO.sub.2 denitration catalyst, the content of TiO.sub.2 is 98-99.8% by weight, the content of SO.sub.3 is 0.2-1% by weight, and the content of P.sub.2O.sub.5 is 0.1-0.2% by weight. The hydrogenated TiO.sub.2 denitration catalyst has high denitration activity at 300-400° C. and N.sub.2 selectivity as high as 85% or more, and can be used in NH.sub.3—SCR denitration.

The present invention relates to the technical field of flue gas denitration catalysts, and discloses a hydrogenated TiO.sub.2 denitration catalyst and a preparation method and use thereof. The hydrogenated TiO.sub.2 denitration catalyst has a crystal form of anatase form, with oxygen vacancies and surface hydroxyl groups; wherein the hydrogenated TiO.sub.2 denitration catalyst contains TiO.sub.2, SO.sub.3 and P.sub.2O.sub.5, and based on the total weight of the hydrogenated TiO.sub.2 denitration catalyst, the content of TiO.sub.2 is 98-99.8% by weight, the content of SO.sub.3 is 0.2-1% by weight, and the content of P.sub.2O.sub.5 is 0.1-0.2% by weight. The hydrogenated TiO.sub.2 denitration catalyst has high denitration activity at 300-400° C. and N.sub.2 selectivity as high as 85% or more, and can be used in NH.sub.3—SCR denitration.

Provided is a method for generating hydrogen at a desired rate, using a hydrogen storage material that can be stored and transported safely and inexpensively. The method according to the present invention for producing a silanol compound and hydrogen includes subjecting a hydrosilane compound and water to a reaction with each other in the presence of a solid catalyst to give a silanol compound and hydrogen. The solid catalyst includes hydroxyapatite and gold particles supported on the hydroxyapatite, where the gold particles have an average particle size of 2.5 nm or less. The reaction in the method according to the present invention for producing a silanol compound and hydrogen is preferably performed in an air atmosphere. The reaction in the method according to the present invention for producing a silanol compound and hydrogen can be performed with application of substantially no heat and no activated energy rays.

Provided is a method for generating hydrogen at a desired rate, using a hydrogen storage material that can be stored and transported safely and inexpensively. The method according to the present invention for producing a silanol compound and hydrogen includes subjecting a hydrosilane compound and water to a reaction with each other in the presence of a solid catalyst to give a silanol compound and hydrogen. The solid catalyst includes hydroxyapatite and gold particles supported on the hydroxyapatite, where the gold particles have an average particle size of 2.5 nm or less. The reaction in the method according to the present invention for producing a silanol compound and hydrogen is preferably performed in an air atmosphere. The reaction in the method according to the present invention for producing a silanol compound and hydrogen can be performed with application of substantially no heat and no activated energy rays.

This invention is related to the synthesis of organic carbonates from carbon dioxide and epoxides. It is particularly focused on the production of propylene cyclic carbonate from propylene oxide. The proposed catalytic materials includes a support made of aluminum oxyhydroxide (Catapal B®), nitric acid, acetic acid and/or phosphoric acid. An important stage is the physical and chemical conditioning of the catalytic materials and to this end, experimental methodologies such as spheronization and thermal treatments were implemented prior the evaluation process.