Patent classifications
B01J31/0261
Method for producing epoxyalkane and solid oxidation catalyst
The present invention provides: a method for producing an epoxyalkane capable of obtaining an epoxide in a high yield while attaining a high olefin conversion rate and a high selectivity for epoxides even when an olefin includes a long carbon chain, and a solid oxidation catalyst. The method for producing an epoxyalkane of the present invention comprises reacting an olefin with an oxidant in the presence of a solid oxidation catalyst, wherein the solid oxidation catalyst comprises a transition metal and a carrier that supports the transition metal, and the carrier is a composite of a metal oxide with a phosphonic acid.
METHOD OF PRODUCING ACRYLONITRILE DIMER
The present invention relates to a method of producing an acrylonitrile dimer, the method including: feeding an acrylonitrile monomer, a nonpolar solvent, an alcohol solvent, and a phosphorus-based catalyst to a dimerization reactor to perform a dimerization reaction and reaction product to a distillation column; feeding the acrylonitrile monomer, the nonpolar solvent, and the alcohol solvent from the distillation column to the dimerization reactor; feeding an acrylonitrile dimer and the phosphorus-based catalyst from the distillation column to an extraction device; oxidizing the phosphorus-based catalyst by feeding water including an acid component to the extraction device to inactivate the phosphorus-based catalyst; and separating the inactivated phosphorus-based catalyst and the acrylonitrile dimer.
Process and formulation for producing a polyamide having low caprolactam concentration and specific relative viscosity
A base polyamide composition comprising a nylon mixture having caprolactam units from 1 wppb to 50 wppm catalyst composition; and greater than 0.75 wt % residual caprolactam, wherein the base polyamide composition has a delta end group level ranging from 30 μeq/gram to 90 μeq/gram.
PROCESS AND FORMULATION FOR PRODUCING A POLYAMIDE HAVING LOW CAPROLACTAM CONCENTRATION AND SPECIFIC RELATIVE VISCOSITY
A base polyamide composition comprising a nylon mixture having caprolactam units from 1 wppb to 50 wppm catalyst composition; and greater than 0.75 wt % residual caprolactam, wherein the base polyamide composition has a delta end group level ranging from 30 μeq/gram to 90 μeq/gram.
METHOD FOR PRODUCING EPOXYALKANE, AND SOLID OXIDATION CATALYST
The present invention provides: a method for producing an epoxyalkane capable of obtaining an epoxide in a high yield while attaining a high olefin conversion rate and a high selectivity for epoxides even when an olefin includes a long carbon chain, and a solid oxidation catalyst used in the method. The method for producing an epoxyalkane of the present invention comprises reacting an olefin with an oxidant in the presence of a solid oxidation catalyst, wherein the solid oxidation catalyst comprises a transition metal and a carrier that supports the transition metal, and the carrier is a metal oxide having a silyl group represented by the following general formula (1):
R.sup.1R.sup.2R.sup.3Si— (1) wherein R.sup.1, R.sup.2, and R.sup.3 are each independently a single bond, a hydrocarbon group, a halogenated hydrocarbon group, an alkoxy group, or a halogen, and at least one of R.sup.1, R.sup.2, and R.sup.3 is a hydrocarbon group having 3 or more carbon atoms or a halogenated hydrocarbon group having 3 or more carbon atoms.
METHOD FOR PRODUCING EPOXYALKANE AND SOLID OXIDATION CATALYST
The present invention provides: a method for producing an epoxyalkane capable of obtaining an epoxide in a high yield while attaining a high olefin conversion rate and a high selectivity for epoxides even when an olefin includes a long carbon chain, and a solid oxidation catalyst. The method for producing an epoxyalkane of the present invention comprises reacting an olefin with an oxidant in the presence of a solid oxidation catalyst, wherein the solid oxidation catalyst comprises a transition metal and a carrier that supports the transition metal, and the carrier is a composite of a metal oxide with a phosphonic acid.
Process and formulation for producing a polyamide having low caprolactam concentration and specific relative viscosity
A base polyamide composition comprising a nylon mixture having caprolactam units from 1 wppb to 50 wppm catalyst composition; and greater than 0.75 wt % residual caprolactam, wherein the base polyamide composition has a delta end group level ranging from 30 eq/gram to 90 eq/gram.
PROCESS AND FORMULATION FOR PRODUCING A POLYAMIDE HAVING LOW CAPROLACTAM CONCENTRATION AND SPECIFIC RELATIVE VISCOSITY
A base polyamide composition comprising a nylon mixture having caprolactam units from 1 wppb to 50 wppm catalyst composition; and greater than 0.75 wt % residual caprolactam, wherein the base polyamide composition has a delta end group level ranging from 30 neq/gram to 90 neq/gram.
Method for producing epoxyalkane, and solid oxidation catalyst
The present invention provides: a method for producing an epoxyalkane capable of obtaining an epoxide in a high yield while attaining a high olefin conversion rate and a high selectivity for epoxides even when an olefin includes a long carbon chain, and a solid oxidation catalyst used in the method. The method for producing an epoxyalkane of the present invention comprises reacting an olefin with an oxidant in the presence of a solid oxidation catalyst, wherein the solid oxidation catalyst comprises a transition metal and a carrier that supports the transition metal, and the carrier is a metal oxide having a silyl group represented by the following general formula (1):
R.sup.1R.sup.2R.sup.3Si(1) wherein R.sup.1, R.sup.2, and R.sup.3 are each independently a single bond, a hydrocarbon group, a halogenated hydrocarbon group, an alkoxy group, or a halogen, and at least one of R.sup.1, R.sup.2, and R.sup.3 is a hydrocarbon group having 3 or more carbon atoms or a halogenated hydrocarbon group having 3 or more carbon atoms.
BRØNSTED-ACIDIC FLUOROALKYL PHOSPHONATES
The invention relates to Brnsted-acidic fluoroalkyl phosphonates as bifunctional catalysts and to processes for the preparation thereof.