Patent classifications
B01J31/0289
Preparation and application of magnetic metallic oxide cross-linked acidic polyionic liquid
The present disclosure discloses the preparation and application of magnetic metallic oxide cross-linked acidic polyionic liquid, belonging to the technical field of solid acid catalysis. The catalyst prepared by the present disclosure has good Lewis acid site and Brnsted acid site, and has the characteristics of high speed, high efficiency, environment friendliness and the like when catalyzing preparation of furfural from xylose. The catalyst has the advantages of easy separation, multiple cycles of recycling and the like, and is green and pollution-free. The magnetic metal oxide cross-linked acidic polyionic liquid prepared by using the present disclosure has the characteristics of high speed, high efficiency, environment friendliness and the like when catalyzing preparation of furfural from xylose, and meanwhile, the catalyst has the advantages of easy separation, multiple cycles of recycling and the like, and is green and pollution-free.
Hydrocarbon processes using halometallate ionic liquid micro-emulsions
A process utilizing a micro-emulsion is described. The micro-emulsion formed by contacting an ionic liquid, a co-solvent, a hydrocarbon, an optional surfactant, and an optional catalyst promoter to form the micro-emulsion. The micro-emulsion comprises a hydrocarbon component comprising the hydrocarbon and an ionic liquid component comprising the ionic liquid. The ionic liquid comprises a halometallate anion and a cation. The co-solvent has a polarity greater than a polarity of the hydrocarbon. The ionic liquid is present in an amount of 0.05 wt % to 40 wt % of the micro-emulsion. A product mixture comprising a product is produced in a process zone containing the micro-emulsion.
Halometallate ionic liquid micro-emulsions
A micro-emulsion and a method of making the micro-emulsion are described. The micro-emulsion includes a hydrocarbon component, an ionic liquid component, and a co-solvent. The ionic liquid comprises a halometallate anion and a cation. The micro-emulsion can optionally include a surfactant, and a catalyst promoter. The co-solvent has a polarity greater than the polarity of the hydrocarbon. The ionic liquid is present in an amount of about 0.05 wt % to about 40 wt % of the micro-emulsion.
Method for generating oxygen from compositions comprising ionic liquids
The present invention is directed to a method for generating oxygen comprising providing at least one oxygen source, providing at least one ionic liquid, providing at least one metal oxide compound, wherein the oxygen source is a peroxide compound, the ionic liquid is in the liquid state at least in the temperature range from 10 C. to +50 C., and the metal oxide compound is an oxide of one single metal or of two or more different metals, said metal(s) being selected from the metals of groups 2 to 14 of the periodic table of the elements, and contacting the oxygen source, the ionic liquid, and the metal oxide compound.
Preparation and Application of Magnetic Metallic Oxide Cross-Linked Acidic Polyionic Liquid
The present disclosure discloses the preparation and application of magnetic metallic oxide cross-linked acidic polyionic liquid, belonging to the technical field of solid acid catalysis. The catalyst prepared by the present disclosure has good Lewis acid site and Brnsted acid site, and has the characteristics of high speed, high efficiency, environment friendliness and the like when catalyzing preparation of furfural from xylose. The catalyst has the advantages of easy separation, multiple cycles of recycling and the like, and is green and pollution-free. The magnetic metal oxide cross-linked acidic polyionic liquid prepared by using the present disclosure has the characteristics of high speed, high efficiency, environment friendliness and the like when catalyzing preparation of furfural from xylose, and meanwhile, the catalyst has the advantages of easy separation, multiple cycles of recycling and the like, and is green and pollution-free.
PERFLUORINATED AMIDE SALTS AND THEIR USES AS IONIC CONDUCTING MATERIALS
The invention concerns ionic compounds in which the anionic load has been delocalized. A compound disclosed by the invention is comprised of an amide or one of its salts, including an anionic portion combined with at least one cationic portion M.sup.+m in sufficient numbers to ensure overall electronic neutrality; the compound is further comprised of M as a hydroxonium, a nitrosonium NO.sup.+, an ammonium NH.sub.4.sup.+, a metallic cation with the valence m, an organic cation with the valence m, or an organometallic cation with the valence m. The anionic portion matches the formula R.sub.FSO.sub.xN.sup.?Z, where R.sub.F is a perflourinated group, x is 1 or 3, and Z is an electroattractive substituent. The compounds can be used notably for ionic conducting materials, electronic conducting materials, colorants and the catalysis of various chemical reactions.
HYDROCARBON PROCESSES USING HALOMETALLATE IONIC LIQUID MICRO-EMULSIONS
A process utilizing a micro-emulsion is described. The micro-emulsion formed by contacting an ionic liquid, a co-solvent, a hydrocarbon, an optional surfactant, and an optional catalyst promoter to form the micro-emulsion. The micro-emulsion comprises a hydrocarbon component comprising the hydrocarbon and an ionic liquid component comprising the ionic liquid. The ionic liquid comprises a halometallate anion and a cation. The co-solvent has a polarity greater than a polarity of the hydrocarbon. The ionic liquid is present in an amount of 0.05 wt % to 40 wt % of the micro-emulsion. A product mixture comprising a product is produced in a process zone containing the micro-emulsion.
Electrochemical devices employing novel catalyst mixtures
An electrochemical device comprises an anode and a cathode. An electrocatalyst mixture is placed between said anode and cathode. The electrocatalyst mixture comprises at least one Catalytically Active Element and, separately, at least one Helper Catalyst comprising an organic molecule, an organic ion, or a mixture of organic molecules and organic ions. The electrocatalyst mixture electrochemically converts carbon dioxide to one or more carbonaceous reaction products via the reaction: CO.sub.2+2e.sup.+2H.sup.+.fwdarw.carbonaceous reaction products, at overpotentials of 0.9 V or less.
USE OF IONIC LIQUIDS IN COMPOSITIONS FOR GENERATING OXYGEN
The present invention is directed to the use of an ionic liquid as a dispersant or solvent and as a heat sink in a composition for generating oxygen, the composition further comprising at least one oxygen source formulation, and at least one metal oxide compound formulation, wherein the oxygen source formulation comprises a peroxide compound, the ionic liquid is in the liquid state at least in a temperature range from 10 C. to +50 C., and the metal oxide compound formulation comprises a metal oxide compound which is an oxide of one single metal or of two or more different metals, said metal(s) being selected from the metals of groups 2 to 14 of the periodic table of the elements.
METHOD FOR GENERATING OXYGEN FROM COMPOSITIONS COMPRISING IONIC LIQUIDS
The present invention is directed to a method for generating oxygen comprising providing at least one oxygen source, providing at least one ionic liquid, providing at least one metal oxide compound, wherein the oxygen source is a peroxide compound, the ionic liquid is in the liquid state at least in the temperature range from 10 C. to +50 C., and the metal oxide compound is an oxide of one single metal or of two or more different metals, said metal(s) being selected from the metals of groups 2 to 14 of the periodic table of the elements, and contacting the oxygen source, the ionic liquid, and the metal oxide compound.