B01J31/2221

Compounds for coordinating with a metal, compositions containing such compounds, and methods of catalyzing reactions

A compound capable of coordinating with a metal includes a chemical structure as shown in claim 1, in which: EPD represents a group having an electron pair donor atom; B and B′ are each independently an aryl group, a heteroaryl group, an alkenyl group, or alkynyl group, or B and B′ form a spirocyclic group; and R.sub.1, R.sub.2, and R.sub.3 are selected from various substituents.

Heterobimetallic catalysts and site-differentiated ligands for preparation thereof

Phosphine phosphonate and phenoxyphosphine ligands bearing polyethylene glycol (PEG) chains are used as described herein to produce heterobimetallic catalysts. The ligands can be metallated selectively with palladium or nickel and secondary metal ions to provide well-defined heterobimetallic compounds. These heterobimetallic complexes exhibit accelerated reaction rates and greater thermal stability in olefin polymerization compared to other catalysts.

HETEROBIMETALLIC CATALYSTS AND SITE-DIFFERENTIATED LIGANDS FOR PREPARATION THEREOF

Phosphine phosphonate and phenoxyphosphine ligands bearing polyethylene glycol (PEG) chains are used as described herein to produce heterobimetallic catalysts. The ligands can be metallated selectively with palladium or nickel and secondary metal ions to provide well-defined heterobimetallic compounds. These heterobimetallic complexes exhibit accelerated reaction rates and greater thermal stability in olefin polymerization compared to other catalysts.

HETEROBIMETALLIC CATALYSTS AND SITE-DIFFERENTIATED LIGANDS FOR PREPARATION THEREOF

Phosphine phosphonate and phenoxyphosphine ligands bearing polyethylene glycol (PEG) chains are used as described herein to produce heterobimetallic catalysts. The ligands can be metallated selectively with palladium or nickel and secondary metal ions to provide well-defined heterobimetallic compounds. These heterobimetallic complexes exhibit accelerated reaction rates and greater thermal stability in olefin polymerization compared to other catalysts.

HETEROBIMETALLIC CATALYSTS AND SITE-DIFFERENTIATED LIGANDS FOR PREPARATION THEREOF

Phosphine phosphonate and phenoxyphosphine ligands bearing polyethylene glycol (PEG) chains are used as described herein to produce heterobimetallic catalysts. The ligands can be metallated selectively with palladium or nickel and secondary metal ions to provide well-defined heterobimetallic compounds. These heterobimetallic complexes exhibit accelerated reaction rates and greater thermal stability in olefin polymerization compared to other catalysts.

Compounds for Coordinating with a Metal, Compositions Containing Such Compounds, and Methods of Catalyzing Reactions

A compound capable of coordinating with a metal includes a chemical structure as shown in claim 1, in which: EPD represents a group having an electron pair donor atom; B and B are each independently an aryl group, a heteroaryl group, an alkenyl group, or alkynyl group, or B and B form a spirocyclic group; and R.sub.1, R.sub.2, and R.sub.3 are selected from various substituents.

Method of producing dialdehyde compound

A method of producing 1,5-pentanedial having an alkyl group at the 3-position, including a step of hydroformylating an aldehyde compound represented by the following general formula (1): ##STR00001##
wherein R.sup.1 represents an alkyl group having from 1 to 6 carbon atoms.

Particles, particle dispersion, particle-dispersed resin composition, producing method therefor, resin molded article, producing method therefor, catalyst particles, catalyst solution, catalyst composition, catalyst molded article, titanium complex, titanium oxide particles and producing method therefor

Organic-inorganic composite particles that can be dispersed in a solvent and/or a resin as primary particles having an organic group on the surface of inorganic particles, the organic-inorganic composite particles having negative birefringence.

POLYMERIZATION OF MICHAEL-TYPE MONOMERS
20190062467 · 2019-02-28 ·

Catalyst and initiator compounds for precision polymerization of Michael-type monomers, precatalytic bridged complexes, such as those having formula R.sub.1R.sub.2M.sub.Z1P.sub.Z2 or R.sub.1R.sub.2M.sub.z1S.sub.z, a system for precision polymerization, as well as processes for precision polymerization of Michael-type monomers, a process for preparing a bridged initiator and catalyst, a process for preparing a luminescent component, and polymers and components obtainable with the processes of the present invention are described.

METHOD OF PRODUCING DIALDEHYDE COMPOUND

A method of producing 1,5-pentanedial having an alkyl group at the 3-position, including a step of hydroformylating an aldehyde compound represented by the following general formula (1):

##STR00001##

wherein R.sup.1 represents an alkyl group having from 1 to 6 carbon atoms.