A method of making a hydrodesulfurization catalyst having nickel and molybdenum sulfides deposited on a support material containing mesoporous silica that is optionally modified with zirconium. The method of making the hydrodesulfurization catalyst involves a single-step calcination and reduction procedure. The utilization of the hydrodesulfurization catalyst in treating a hydrocarbon feedstock containing sulfur compounds (e.g. dibenzothiophene, 4,6-dimethyldibenzothiophene) to produce a desulfurized hydrocarbon stream is also provided.

A catalyst precursor composition for forming a phenol alkylation catalyst, the composition comprising: 70 to 98 weight percent of abase oxide comprising: magnesium oxide with a Brunauer-Emmett-Teller surface area from 75 meter.sup.2/gram to 220 meter.sup.2/gram, preferably from 75 meter.sup.2/gram to 140 meter.sup.2/gram, more preferably from 90 meter.sup.2/gram to 130 meter.sup.2/gram; or magnesium carbonate with a Brunauer-Emmett-Teller surface area of from 100 meter.sup.2/gram to 220 meter.sup.2/gram, preferably from 120 meter.sup.2/gram to 200 meter.sup.2/gram; or a combination thereof; at least one metal promoter precursor comprising an iron precursor, a manganese, a vanadium precursor, or a copper precursor; and a pore former, a lubricant, a coke inhibitor; and optionally, a strength additive; and optionally a binder, and a method of alkylating phenol using a catalyst derived from the catalyst precursor.

A combination of bismuth oxyhalides is provided, which is a photooxidant, antibacterial and antiviral. The combination of bismuth oxyhalides is added to a filter medium (e.g., a multistage filter) to decompose VOCs and/or eliminate bacteria and/or viruses. Suitable designs of multistage filters are also provided.

Claimed herein is a method of applying amorphous Co—SiOx to activate PMS and produce SO.sub.4..sup.− due to the formation of Co(II)-O.sub.v, pairs via the substitution of Si by Co. The inherent Co significantly change the electronic structure of O and Si atoms in the Co—SiOx via final state effects and increase the conductivity in terms of more effective electron transfers. The claimed method using Co—SiOx functions as a more effective oxidative catalyst for the faster degradation of pollutants. The simplicity of the synthetic procedures indicates that the conductive Co—SiOx could be used for the activation of PMS and other electrochemical applications on a wider scale.

A layered catalyst reactor system and process for hydrotreatment of hydrocarbon feedstocks. The layered catalyst system reactors comprise vertical bed layers including a demetallization catalyst layer, multiple layers of supported hydrotreating catalyst layer, and multiple alternating layers of supported hydrocracking catalysts and self-supported hydrotreating catalysts. The arrangement of the catalyst layers mitigates the risk of temperature run-aways, with improvements in hydrotreatment performance.

A layered catalyst reactor system and process for hydrotreatment of hydrocarbon feedstocks. The layered catalyst system reactors comprise vertical bed layers including a demetallization catalyst layer, multiple layers of supported hydrotreating catalyst layer, and multiple alternating layers of supported hydrocracking catalysts and self-supported hydrotreating catalysts. The arrangement of the catalyst layers mitigates the risk of temperature run-aways, with improvements in hydrotreatment performance.

The present invention relates to the field of catalysts, and provides a porous layered transition metal dichalcogenide (TMD) and a preparation method and use thereof. The preparation method includes the following steps: (1) mixing silica microspheres, a transition metal salt and an elemental chalcogen, and pressing to obtain a tablet, the silica microspheres having a same or different particle diameters; and (2) sintering the tablet under hydrogen, and removing the silica microspheres to obtain the porous layered TMD. The porous layered TMD prepared by the method of the present invention has a high lattice edge exposure, which provides more active sites and higher catalytic activity, so the porous layered TMD can effectively catalyze the oxidation of alcohols to aldehydes or sulfides to sulfoxides under visible light irradiation.

The present invention relates to the field of catalysts, and provides a porous layered transition metal dichalcogenide (TMD) and a preparation method and use thereof. The preparation method includes the following steps: (1) mixing silica microspheres, a transition metal salt and an elemental chalcogen, and pressing to obtain a tablet, the silica microspheres having a same or different particle diameters; and (2) sintering the tablet under hydrogen, and removing the silica microspheres to obtain the porous layered TMD. The porous layered TMD prepared by the method of the present invention has a high lattice edge exposure, which provides more active sites and higher catalytic activity, so the porous layered TMD can effectively catalyze the oxidation of alcohols to aldehydes or sulfides to sulfoxides under visible light irradiation.

The present invention relates to a molding catalyst and a method for producing the same, wherein the molding catalyst is used in the Deacon process for commercial production of chlorine using hydrogen chloride oxidation reaction, exhibits only a small reduction in catalytic activity even when exposed to harsh reaction conditions to thus be durable, and has superb mechanical strength to be suitable for use in a fixed bed catalytic reactor.

Disclosed is high conversion and high carbon yielding CARGEN catalyst and a method of preparing the same. The catalyst comprises transition metals that may be supported or unsupported. The preparation method involves mixing a metal material with or without a support in a standard ball milling apparatus to produce a fine and homogenous solid mixture of the transition metal oxide and support. The catalyst is used in the CARGEN system.