Patent classifications
B01J39/12
Process for a mild aqueous synthesis of titanium phosphates—ion—exchangers having solely—H2PO4 active groups
The invention relates to a process for performing a aqueous synthesis of titanium phosphates (TiP) having solely —H2PO4 groups, which process is characterised by the following steps: providing titanium (IV) oxysulphate, TiOSO4, in an aqueous solution or in a powder and H2SO4, substantially without transition divalent metal ions, including cobalt (II) and copper (II), heating of the thus formed aqueous solution to above 50° C., but below 85° C. for at least 30 minutes, providing a controlled amount of H3PO4 to said aqueous solution, to form an aqueous solution containing a molar ratio between TIO2 and P2Os being controlled to about 1:1, not above 1:1.5 and not below 1:0.7, stirring the thus formed aqueous solution for at least 3 hours to form precipitates of titanium phosphate, and allowing ageing of said solution, without stirring, acidic washing of the formed precipitate using HCI or other acids to obtain TiO(OH)(H2PO4)-H2O having solely —H2PO4 ion-exchange chemical groups and allowing said precipitates to dry to a powder product, substituting protons in the powder product TiO(OH)(H2PO4)-H2O to sodium cations by treatment of the latter with solutions of sodium carbonate and allowing the thus formed powder of Na—TiP1 to dry.
Process for a mild aqueous synthesis of titanium phosphates—ion—exchangers having solely—H2PO4 active groups
The invention relates to a process for performing a aqueous synthesis of titanium phosphates (TiP) having solely —H2PO4 groups, which process is characterised by the following steps: providing titanium (IV) oxysulphate, TiOSO4, in an aqueous solution or in a powder and H2SO4, substantially without transition divalent metal ions, including cobalt (II) and copper (II), heating of the thus formed aqueous solution to above 50° C., but below 85° C. for at least 30 minutes, providing a controlled amount of H3PO4 to said aqueous solution, to form an aqueous solution containing a molar ratio between TIO2 and P2Os being controlled to about 1:1, not above 1:1.5 and not below 1:0.7, stirring the thus formed aqueous solution for at least 3 hours to form precipitates of titanium phosphate, and allowing ageing of said solution, without stirring, acidic washing of the formed precipitate using HCI or other acids to obtain TiO(OH)(H2PO4)-H2O having solely —H2PO4 ion-exchange chemical groups and allowing said precipitates to dry to a powder product, substituting protons in the powder product TiO(OH)(H2PO4)-H2O to sodium cations by treatment of the latter with solutions of sodium carbonate and allowing the thus formed powder of Na—TiP1 to dry.
SORBENT CARTRIDGE DESIGNS
Sorbent cartridges having a flow control insert to improve the functional capacity of a sorbent cartridge is provided. Flow control inserts can include a plurality of flow channels filled with sorbent material through which fluid to be regenerated can travel in the sorbent cartridge.
SORBENT CARTRIDGE DESIGNS
Sorbent cartridges having a flow control insert to improve the functional capacity of a sorbent cartridge is provided. Flow control inserts can include a plurality of flow channels filled with sorbent material through which fluid to be regenerated can travel in the sorbent cartridge.
Sorbent for a dialysis device
There is provided a sorbent for removing metabolic waste products from a dialysis liquid, the sorbent comprising a layer of immobilized uremic toxin-treating enzyme particles intermixed with cation exchange particles.
Sorbent for a dialysis device
There is provided a sorbent for removing metabolic waste products from a dialysis liquid, the sorbent comprising a layer of immobilized uremic toxin-treating enzyme particles intermixed with cation exchange particles.
Sorbent for a dialysis device
There is provided a sorbent for removing metabolic waste products from a dialysis liquid, the sorbent comprising a layer of immobilized uremic toxin-treating enzyme particles intermixed with cation exchange particles.
ION CAPTURE COMPOSITION FOR INGESTION
The invention is directed to ion-capture compositions for ingestion and methods of use thereof. An aspect of the invention is drawn towards a method for selectively capturing at least one ion from the digestive system of a subject, the method comprising administering orally to the subject the ion-capture composition.
ION CAPTURE COMPOSITION FOR INGESTION
The invention is directed to ion-capture compositions for ingestion and methods of use thereof. An aspect of the invention is drawn towards a method for selectively capturing at least one ion from the digestive system of a subject, the method comprising administering orally to the subject the ion-capture composition.
Amorphous inorganic anion exchanger, resin composition for electronic component sealing, and process for producing amorphous bismuth compound
The amorphous inorganic anion exchanger of the present invention is represented by Formula (1) and has an average primary particle size observed with an electron microscope of at least 1 nm but no greater than 500 nm and an NO.sub.3 content of no greater than 1 wt % of the whole:
BiO(OH) Formula (1).