This invention provides a method for forming a multilayer coating film, the method comprising forming a multilayer coating film that has excellent blackness, high reflectance of an infrared laser, and excellent coating film performance. The method for forming a multilayer coating film includes forming a first colored coating film containing a titanium oxide pigment, in which the diffuse reflectance at a wavelength of 905 nm or diffuse reflectance at a wavelength of 1550 nm, or both, is 40% or more; forming a second colored coating film containing at least one pigment selected from the group consisting of (A1) a perylene black pigment, (A2) a black metal oxide complex pigment, and (A3) two or more pigments selected from the group consisting of blue pigments, red pigments, yellow pigments, and green pigments; forming a third colored coating film containing a carbon black pigment; and forming a clear coating film; wherein the multilayer coating film has a lightness L*(45°) of 3 or less and a chroma C*(45°) of 1 or less, and wherein the diffuse reflectance at a wavelength of 905 nm or the diffuse reflectance at a wavelength of 1550 nm of the multilayer coating film, or both, is 10% or more.

This invention provides a method for forming a multilayer coating film, the method comprising forming a multilayer coating film that has excellent blackness, high reflectance of an infrared laser, and excellent coating film performance. The method for forming a multilayer coating film includes forming a first colored coating film containing a titanium oxide pigment, in which the diffuse reflectance at a wavelength of 905 nm or diffuse reflectance at a wavelength of 1550 nm, or both, is 40% or more; forming a second colored coating film containing at least one pigment selected from the group consisting of (A1) a perylene black pigment, (A2) a black metal oxide complex pigment, and (A3) two or more pigments selected from the group consisting of blue pigments, red pigments, yellow pigments, and green pigments; forming a third colored coating film containing a carbon black pigment; and forming a clear coating film; wherein the multilayer coating film has a lightness L*(45° of 3 or less and a chroma C*(45° of 1 or less, and wherein the diffuse reflectance at a wavelength of 905 nm or the diffuse reflectance at a wavelength of 1550 nm of the multilayer coating film, or both, is 10% or more.

A PCM steel sheet for a home appliance and a refrigerator including the same. The PCM steel sheet may include a steel sheet, a basecoat layer provided on the steel sheet, a hairline layer formed on the basecoat layer, a clearcoat layer provided on the hairline layer, and a primer layer between the steel sheet and the basecoat layer to provide adhesion. The PCM steel sheet for a home appliance does not include a metal mesh layer. The PCM steel sheet for a home appliance may have a brightness (flop index) of about 20 or more.