A method for forming a multilayer coating film comprising the steps of: (1) applying a base paint (X) to a substrate to form a base coating film, (2) applying an effect pigment dispersion (Y) to the base coating film formed in step (1) to form an effect coating film, (3) applying a clear paint (Z) to the effect coating film formed in step (2) to form a clear coating film, and (4) heating the uncured base coating film, the uncured effect coating film, and the uncured clear coating film formed in steps (1) to (3) to thereby simultaneously cure these three coating films; wherein the effect pigment dispersion (Y) contains water, a black pigment (A), a vapor deposition metal flake pigment (B), and a rheology control agent (C).

Provided is an aqueous coating composition that can exhibit high coating film performance even when cured at a relatively low temperature. The present invention pertains to an aqueous coating composition comprising (A) a hydroxyl group-containing resin and (B) a blocked polyisocyanate compound. The weight average molecular weight of the blocked polyisocyanate compound (B) is in a range of 20,000-200,000.

The multilayer coating film formation method for forming a multilayer coating film on a substrate comprises the steps of: applying an undercoat paint composition (X) comprising an antioxidant (a1) to a substrate to form at least one layer of an uncured first coating film; applying a topcoat paint composition (Y) containing a carboxy-containing polymer (b1) and an epoxy-containing acrylic resin (b2) to the first coating film to form an uncured second coating film; and simultaneously heating the uncured first coating film and the uncured second coating film to cure the films.

Provided is a method for forming a multilayer coating film, the method being capable of forming a high-brightness white multilayer coating film which is excellent in terms of brilliant feeling, smoothness, and weather resistance and with which white stains are suppressed. In this method for forming a multilayer coating film to form a brilliant coating film, a white multilayer coating film is formed by: sequentially applying a first coloring paint (P1), a second aqueous coloring paint (P2), a third aqueous coloring paint (P3), and a clear coat paint (P4) on a cured electrodeposition coating film formed on a steel sheet; and forming a first colored coating film, a second colored coating film, a third colored coating film, and a clear coat coating film which each have a particular composition, brightness, film thickness, and the like.

An object is to provide an aqueous coating material composition having high viscosity expression property as well as a viscosity property of decreasing viscosity with increase in shear velocity; in particular, to provide an aqueous coating material composition that can form a multilayer coating film having excellent smoothness, clarity, flip-flop property, adhesion, and water resistance; in addition, to provide a method for forming a multilayer coating film using such aqueous coating material composition, as well as a coated article that has been coated with such aqueous coating material composition. As a solution, an aqueous coating material composition is provided that contains a polyester resin (A), acrylic resin particles (B), a curing agent (C), and a coloring pigment (D), wherein the polyester resin (A) is a resin containing a trifunctional or higher polyfunctional polycarboxylic acid (a1) and a polyol (a2) as monomer components.

Disclosed is a method for forming a multilayer coating film, including applying a first and second aqueous base coat, and a clear coat to an object, and thereafter simultaneously heating and curing the three-layer coating film. The first aqueous base coat includes a water-soluble or water-dispersible polyurethane resin having a glass transition temperature of −20° C. or below and a weight average molecular weight of 30,000 to 500,000, and a crosslinkable resin having a weight average molecular weight of 600 or more. The first aqueous base coat-coated film has a breaking strength of 2050 N/cm2 or more and a loss tangent (tan δ) at −20° C. of 0.075 or more. The migration amount of a melamine resin from the second aqueous base coat-coated film layer to the first aqueous base coat-coated film layer is within 3% by mass of a total resin solid content of the first aqueous base coat.

Provided is a method for forming a multilayer coating film, the method being capable of forming a high-brightness white multilayer coating film which is excellent in terms of brilliant feeling, smoothness, and weather resistance and with which white stains are suppressed. In this method for forming a multilayer coating film to form a brilliant coating film, a white multilayer coating film is formed by: sequentially applying a first coloring paint (P1), a second aqueous coloring paint (P2), a third aqueous coloring paint (P3), and a clear coat paint (P4) on a cured electrodeposition coating film formed on a steel sheet; and forming a first colored coating film, a second colored coating film, a third colored coating film, and a clear coat coating film which each have a particular composition, brightness, film thickness, and the like.

The multilayer coating film formation method for forming a multilayer coating film on a substrate comprises the steps of: applying an undercoat paint composition (X) comprising an antioxidant (a1) to a substrate to form at least one layer of an uncured first coating film; applying a topcoat paint composition (Y) containing a carboxy-containing polymer (b1) and an epoxy-containing acrylic resin (b2) to the first coating film to form an uncured second coating film; and simultaneously heating the uncured first coating film and the uncured second coating film to cure the films.

The present disclosure is to provide a laminated film for decorating a three-dimensional molded product by vacuum forming which has a crack and strain-free uneven design on the clear coating film layer being an outermost layer at the time of use and provide a good design property to a molded product. A laminated film for decorating a three-dimensional molded product by vacuum forming, having a base material film layer (A), a clear coating film layer (B), and a design layer (C), wherein at least one face of the base material film layer (A) bordering the clear coating film layer (B) has an uneven design.

A method for forming a multilayer coating film comprising the steps of: (1) applying a base paint (X) to a substrate to form a base coating film, (2) applying an effect pigment dispersion (Y) to the base coating film formed in step (1) to form an effect coating film, (3) applying a clear paint (Z) to the effect coating film formed in step (2) to form a clear coating film, and (4) heating the uncured base coating film, the uncured effect coating film, and the uncured clear coating film formed in steps (1) to (3) to thereby simultaneously cure these three coating films; wherein the effect pigment dispersion (Y) contains water, a black pigment (A), a vapor deposition metal flake pigment (B), and a rheology control agent (C).