Described herein are compositions, methods, and systems for printing metal three-dimensional objects. In an example, described is a method of printing a three-dimensional object comprising: (i) depositing a metal powder build material, wherein the metal powder build material has an average particle size of from about 10 μm to about 250 μm; (ii) selectively applying a binder fluid on at least a portion of the metal powder build material, wherein the binder fluid comprises an aqueous liquid vehicle and latex polymer particles dispersed in the aqueous liquid vehicle; (iii) heating the selectively applied binder fluid on the metal powder build material to a temperature of from about 40° C. to about 180° C.; and (iv) repeating (i), (ii), and (iii) at least one time to form the three-dimensional object.

A cemented carbide having an eta phase and a Ni—Al binder is provided. The binder includes intermetallic γ′-Ni.sub.3Al-precipitates embedded in a substitutional solid solution matrix including Al and Ni. Further, the cemented carbide has a surface zone free from eta phase. A method of making a cutting tool is also provided.

A cemented carbide having an eta phase and a Ni—Al binder is provided. The binder includes intermetallic γ′-Ni.sub.3Al-precipitates embedded in a substitutional solid solution matrix including Al and Ni. Further, the cemented carbide has a surface zone free from eta phase. A method of making a cutting tool is also provided.

A method for producing fine copper particles includes producing fine copper particles having a coating film containing cuprous oxide on a surface by heating copper or a copper compound in a reducing flame formed by a burner. The fine copper particles are produced by adjusting a mixing ratio between a combustible gas and a combustion supporting gas which form the reducing flame such that a volume ratio of CO/CO.sub.2 is in a range of 1.5 to 2.4.

The invention relates to a method for additive manufacture of a workpiece under protective gas, wherein a workpiece is assembled from a sequence of workpiece contours, each of which is manufactured by selective sintering or melting of a powdery or wire-like material by applying an energy beam thereto, wherein a workpiece contour is manufactured under the effect of a protective gas consisting of carbon dioxide and an inert gas. According to the invention, the chemical composition of each workpiece contour is modified according to a specified program by variation of the composition of the protective gas. Heat treatment occurring after manufacture of the workpiece contour provides for defined mechanical and technological quality values of the workpiece contour. A workpiece having zones with defined mechanical and technological quality values is produced in this manner.

The invention relates to a method for additive manufacture of a workpiece under protective gas, wherein a workpiece is assembled from a sequence of workpiece contours, each of which is manufactured by selective sintering or melting of a powdery or wire-like material by applying an energy beam thereto, wherein a workpiece contour is manufactured under the effect of a protective gas consisting of carbon dioxide and an inert gas. According to the invention, the chemical composition of each workpiece contour is modified according to a specified program by variation of the composition of the protective gas. Heat treatment occurring after manufacture of the workpiece contour provides for defined mechanical and technological quality values of the workpiece contour. A workpiece having zones with defined mechanical and technological quality values is produced in this manner.

While a molten metal of copper heated to a temperature, which is higher than the melting point of copper by 250 to 700° C. (preferably 350 to 650° C. and more preferably 450 to 600° C.), is allowed to drop, a high-pressure water is sprayed onto the heated molten metal of copper in a non-oxidizing atmosphere (such as an atmosphere of nitrogen, argon, hydrogen or carbon monoxide) to rapidly cool and solidify the heated molten metal of copper to produce a copper powder which has an average particle diameter of 1 to 10 μm and a crystallite diameter Dx.sub.(200) of not less than 40 nm on (200) plane thereof, the content of oxygen in the copper powder being 0.7% by weight or less.

An example of a composition includes a host metal present in an amount ranging from about 95.00 weight percent to about 99.99 weight percent, based on a total weight of the composition. A flow additive is present in an amount ranging from about 0.01 weight percent to about 5.00 weight percent, based on the total weight of the composition. The flow additive consists of a metal containing compound that is reducible to an elemental metal in a reducing environment at a reducing temperature less than or equal to a sintering temperature of the host metal. The elemental metal is capable of being incorporated into a bulk metal phase of the host metal in a final metal object. The composition is spreadable, having a Hausner Ratio less than 1.25.

An example of a composition includes a host metal present in an amount ranging from about 95.00 weight percent to about 99.99 weight percent, based on a total weight of the composition. A flow additive is present in an amount ranging from about 0.01 weight percent to about 5.00 weight percent, based on the total weight of the composition. The flow additive consists of a metal containing compound that is reducible to an elemental metal in a reducing environment at a reducing temperature less than or equal to a sintering temperature of the host metal. The elemental metal is capable of being incorporated into a bulk metal phase of the host metal in a final metal object. The composition is spreadable, having a Hausner Ratio less than 1.25.

A component obtainable by a process which includes providing a composition and sintering the composition at a sintering temperature of from 1250° C. to 1400° C. for a period of from 3 to 15 minutes. The composition includes hard material particles with an inner core of fused tungsten carbide and an outer shell of tungsten carbide, and a binder metal selected from Co, Ni, Fe and alloys with at least one metal selected from Co, Ni and Fe.