The present invention discloses a method for preparing stable 3D polymer objects with surface micro-nanostructures. The method includes the following steps: Step (1): Synthesizing a thermoset 2D polymer object with surface microstructures. The polymer network contains reversible exchangeable bonds. Step (2): deforming synthesized polymer to an arbitrary desired shape above the reshaping temperature with an external force applied. The permanent reshaping temperature falls in the range of 50-130° C. and external stress is held for 5 min-24 hours Step (3): after cooling, a permanent 3D polymer object with surface microstructure is obtained. Step (2-3) can be repeated for many cycles and the 2D polymer object can be arbitrarily and cumulatively deformed to get a complex 3D structures. The polymer networks contain reversible exchangeable bonds and bond exchange catalysts in the present invention. The method disclosed in present invention is simple and efficient for preparing complex 3D polymer objects with surface micro-nanostructures.

A composite structure for stab protection includes layers of flat structures placed on top of each other, and an embedding material, wherein, in at least some of the layers placed on top of each other, the flat structures of adjacent layers are offset relative to one another, the flat structures of the composite structure are at least partially embedded in the embedding material, and the composite structure includes separated connecting elements, wherein before they are separated, the separated connecting elements have connected at least some of the flat structures of adjacent layers with one another.

A two-way shape memory polymer composite material is provided, which comprises two interpenetrating network polymers, wherein one polymer is a shape memory polymer made of crystalline cross-linked polymer, the other one is a cross-linked elastomeric material. The composite material is formed by interpenetration of two network polymers, wherein one network polymer will shrink under heating and the other network polymer acts as the segment for energy storage. When the first polymer network shrinks under heating, it presses the second polymer network, while the heating is cancelled the pressed second polymer network will enforce the first polymer network to recover the original shape, therefore it has the behavior of two-way shape memory.

The present invention discloses a method for preparing stable 3D polymer objects with surface micro-nanostructures. The method includes the following steps: Step (1): Synthesizing a thermoset 2D polymer object with surface microstructures. The polymer network contains reversible exchangeable bonds. Step (2): deforming synthesized polymer to an arbitrary desired shape above the reshaping temperature with an external force applied. The permanent reshaping temperature falls in the range of 50-130 C. and external stress is held for 5 min-24 hours Step (3): after cooling, a permanent 3D polymer object with surface microstructure is obtained. Step (2-3) can be repeated for many cycles and the 2D polymer object can be arbitrarily and cumulatively deformed to get a complex 3D structures. The polymer networks contain reversible exchangeable bonds and bond exchange catalysts in the present invention. The method disclosed in present invention is simple and efficient for preparing complex 3D polymer objects with surface micro-nanostructures.

A composite structure for stab protection includes layers of flat structures placed on top of each other, and an embedding material, wherein, in at least some of the layers placed on top of each other, the flat structures of adjacent layers are offset relative to one another, the flat structures of the composite structure are at least partially embedded in the embedding material, and the composite structure includes separated connecting elements, wherein before they are separated, the separated connecting elements have connected at least some of the flat structures of adjacent layers with one another.