A heat-sensitive recording material suitable for offset printing, having a web-shaped substrate, having a front side and a reverse side opposite the front side, a heat-sensitive recording layer disposed at least on one of the two sides of the web-shaped substrate having at least one dye precursor and at least one (color) developer reactive with the dye precursor. The heat-sensitive recording layer has particles including an organic surface whose extent in the direction of the thickness of web-shaped substrate and heat-sensitive recording layer is greater than the thickness of the heat-sensitive recording layer.

An object of the present invention is to provide a recording material or a recording sheet using, as a color-developing agent, a non-phenol-based compound good in color developing performance and the like. A compound represented by the following formula (I) is used as the color-developing agent: ##STR00001##
(wherein X represents CH.sub.2 or the like; R.sup.1 to R.sup.3 each independently represent a hydrogen atom, a halogen atom or the like; n1 and n3 each independently represent any integer of 1 to 5; two groups represented by R.sup.3 adjacent to each other on a benzene ring optionally bond to each other to form an optionally substituted 6-membered ring; and n2 represents any integer of 1 to 4).

A thermal adhesive paper including a base stock with a thermal ink layer covering at least a portion of the base stock top surface and an activatable adhesive layer covering at least a portion of the base stock bottom surface is described. The thermal adhesive layer can be used in a thermal printer for printing a transaction receipt, with the adhesive being selectively activated during printing. The activatable adhesive may be thermally activated, with a higher temperature needed to activate the adhesive than to activate the thermal ink.

The present invention relates to an N-(4-((4-(3-phenylureido)phenyl)sulfonyl)phenyl)benzenesulfonamide in the polymorphic form ω.sup.18.9, characterised by an x-ray powder diffractogram having the Bragg angles (2θ/CuK.sub.α) 10.9, 11.7, 14.6, 15.0, 15.8, 16.6, 17.6, 18.9, 19.4, 20.9, 21.2, 22.0, 23.3, 24.4, 24.7, 26.1, 27.4, 29.4, 34.2,

or in the polymorphic form α.sup.21.2, characterised by an x-ray powder diffractogram having the Bragg angles (2θ/CuK.sub.α) 8.7, 9.8, 10.8, 13.2, 13.9, 14.9, 15.2, 16.0, 17.4, 17.7, 18.7, 20.4, 21.2, 21.6, 22.3, 23.0, 23.3, 23.9, 24.4, 25.0, 25.8, 26.6, 28.1, 28.9, 29.4, 30.1, 30.6, 31.8, 34.5, 35.3, 35.6, 36.9, a method for production thereof, use thereof as a colour developer in a heat-sensitive recording material, and a heat-sensitive recording material comprising N-(4-((4-(3-phenylureido)phenyl)sulfonyl)phenyl)benzenesulfonamide in the polymorphic form ω.sup.18.9 or in the polymorphic form α.sup.21.2.

In one aspect, the present invention relates to a thermosensitive recording medium comprising at least: —a support layer; —a thermosensitive colouring layer over the support layer, the thermosensitive colouring layer containing a leuco dye; and —a protective layer over the thermosensitive colouring layer; wherein the thermosensitive colouring layer comprises a developer having the general formula (I) below: wherein R.sub.1 to R.sub.3 each independently represent a hydrogen atom, a halogen atom, a C1-C6 alkyl group, a C1-C6 alkoxyl group, a C1-C6 fluoroalkyl group; characterized in that the protective layer comprises particles of wax with an average particle size of at least 0.05 μm and at most 2.0 μm. In further aspects, the present invention relates to a label for attachment to a product comprising the thermosensitive recording medium of the invention, and to a consumer product package to which a thermosensitive recording medium or a label of the invention has been attached. ##STR00001##

A thermosensitive recording medium includes a support, and a thermosensitive recording layer disposed on or above the support, wherein the thermosensitive recording layer includes a non-phenolic color developer and a sensitizer that includes fatty acid amide, and wherein an amount of the fatty acid amide in the sensitizer is 60% by mass or greater.

The invention relates to a self-adhesive, heat-sensitive recording material, comprising a carrier substrate, a heat-sensitive, color-forming layer that is applied on one side of the carrier substrate and contains at least a non-phenolic color developer in and at least one color former, a siliconized layer on the upper side of the heat-sensitive, color-forming layer that is applied on the carrier substrate, as well as an adhesive layer on the side of the carrier substrate facing away from the heat-sensitive, color-forming layer.

Provided is a thermosensitive recording medium being excellent in oil resistance among various performances required for the thermosensitive recording medium, and being further excellent in heat resistance, plasticizer resistance, and printing (recording) run-ability.

That is a thermosensitive recording medium having a thermosensitive recording layer comprising a colorless or pale colored electron donating leuco dye and an electron accepting color developing agent on a substrate, wherein the thermosensitive recording layer contains at least two kinds of urea compounds. The two kinds of urea compounds comprise the first urea compound being represented by the following general formula 1, and the second urea compound being represented by the following general formula 2.

##STR00001##

wherein R.sup.1 represents a substituted or unsubstituted alkyl group, aralkyl group or aryl group, and R.sup.2 represents a hydrogen atom or an alkyl group,

##STR00002##

wherein R.sup.4 to R.sup.8 represent a hydrogen atom, a halogen atom, a nitro group, an amino group, an alkyl group, an alkoxy group, an aryloxy group, and the like, and m represents an integer of 0 to 2.

The present invention relates to an N-(4-((4-(3-phenylureido)phenyl)sulfonyl)phenyl)benzenesulfonamide in the polymorphic form ω.sup.18.9, characterised by an x-ray powder diffractogram having the Bragg angles (2θ/CuK.sub.α) 10.9, 11.7, 14.6, 15.0, 15.8, 16.6, 17.6, 18.9, 19.4, 20.9, 21.2, 22.0, 23.3, 24.4, 24.7, 26.1, 27.4, 29.4, 34.2, or in the polymorphic form α.sup.21.2, characterised by an x-ray powder diffractogram having the Bragg angles (2θ/CuK.sub.α) 8.7, 9.8, 10.8, 13.2, 13.9, 14.9, 15.2, 16.0, 17.4, 17.7, 18.7, 20.4, 21.2, 21.6, 22.3, 23.0, 23.3, 23.9, 24.4, 25.0, 25.8, 26.6, 28.1, 28.9, 29.4, 30.1, 30.6, 31.8, 34.5, 35.3, 35.6, 36.9, a method for production thereof, use thereof as a colour developer in a heat-sensitive recording material, and a heat-sensitive recording material comprising N-(4-((4-(3-phenylureido)phenyl)sulfonyl)phenyl)benzenesulfonamide in the polymorphic form ω.sup.18.9 or in the polymorphic form α.sup.21.2.

This heat-sensitive recording material is configured to contain, as a color-developing compound, at least one compound represented by one of formulas (1)-(3):

##STR00001##