The present invention provides a catalyst for catalytic reduction of an industrial flue gas SO.sub.2 with CO to prepare sulfur, a method for preparing the same and use thereof. A CeO.sub.2 nanocarrier is prepared by using a hydrothermal method, La and Y are loaded as active components, pre-sulfurization is conducted with 6% of SO.sub.2 and 3% of CO, and finally, the catalyst is prepared. The catalyst has high reactivity and sulfur selectivity and strong stability. The by-product sulfur generated by the reaction is recovered with a solvent CS.sub.2, and the solvent CS.sub.2 is recovered by using a distillation process. The preparation method is low in cost, causes no secondary pollution and is high in sulfur recovery rate. The problem of low sulfur production in China at present is solved.

Methods and systems are provided for treating the tail gas stream of a sulfur recovery plant. The methods including generating a tail gas stream from a sulfur recovery plant, treating the tail gas stream with a hydrogen sulfide removal unit and a hydrogen selective membrane unit, generating a stream low in hydrogen sulfide and a stream rich in hydrogen. The hydrogen sulfide rich stream is recycled to the sulfur recovery unit. The hydrogen selective membrane unit includes a glassy polymer membrane selective for hydrogen over hydrogen sulfide and carbon dioxide.

Methods and systems are provided for treating the tail gas stream of a sulfur recovery plant. The methods including generating a tail gas stream from a sulfur recovery plant, treating the tail gas stream with a hydrogen sulfide removal unit and a hydrogen selective membrane unit, generating a stream low in hydrogen sulfide and a stream rich in hydrogen. The hydrogen sulfide rich stream is recycled to the sulfur recovery unit. The hydrogen selective membrane unit includes a glassy polymer membrane selective for hydrogen over hydrogen sulfide and carbon dioxide.

The present invention provides a catalyst for catalytic reduction of an industrial flue gas SO.sub.2 with CO to prepare sulfur, a method for preparing the same and use thereof. A CeO.sub.2 nanocarrier is prepared by using a hydrothermal method, La and Y are loaded as active components, pre-sulfurization is conducted with 6% of SO.sub.2 and 3% of CO, and finally, the catalyst is prepared. The catalyst has high reactivity and sulfur selectivity and strong stability. The by-product sulfur generated by the reaction is recovered with a solvent CS.sub.2, and the solvent CS.sub.2 is recovered by using a distillation process. The preparation method is low in cost, causes no secondary pollution and is high in sulfur recovery rate. The problem of low sulfur production in China at present is solved.

A desulfurization system removes sulfur ingredients included in synthetic gas generated from gasification of coal in a high temperature dry state. The system includes a desulfurization reactor, a desulfurization cyclone, and first and second regeneration reactors branched with the desulfurization cyclone. A first oxidizing agent is injected to a first oxidizing agent inlet of the first regeneration reactor, and a second oxidizing agent is injected to a second oxidizing agent inlet of the second regeneration reactor. A controller operates one of the first and second regeneration reactors in a regeneration mode, controlling the other to operate in a desulfurization mode.

The present invention relates to a method for removing sulphur dioxide from gaseous effluent, wherein a mixture of gaseous outlet gasses or gaseous effluent includes sulphur dioxide and carbon monoxide, and wherein, to perform a catalytic reduction, a catalyst is used to catalyze a reaction between carbon monoxide and sulphur dioxide to produce carbon dioxide and sulphur.

A desulfurization system removes sulfur ingredients included synthetic gas generated from gasification of coal in a high temperature dry state. The system includes a desulfurization reactor, a desulfurization cyclone, and first and second regeneration reactors branched in the desulfurization cyclone. A first oxidizing agent is injected to a first oxidizing agent inlet of the first regeneration reactor, and a second oxidizing agent is injected to a second oxidizing agent inlet of the second regeneration reactor. A controller operates one of the first and second regeneration reactors in a regeneration mode, controlling the other to operate in a desulfurization mode.