The present application provides a method of preparing sulfuryl fluoride, including the following steps of: S1) reacting sulfur trioxide steam with barium fluoride to acquire a mixed gas of barium sulphate and sulfuryl fluoride; S2) pickling the mixed gas acquired in step S1 with a concentrated sulfuric acid solution with a concentration of 70-98.3 wt. % to acquire a primary purified sulfuryl fluoride gas; S3) passing the primary purified sulfuryl fluoride gas acquired in step S2 through an aqueous solution with a concentration of 2-10 wt. % selected from at least one of the following: sodium sulfite, sodium bisulfite, sodium pyrosulfite, and sodium thiosulfate, to acquire a sulfuryl fluoride gas.

A method for efficiently preparing sulfuryl fluoride by using sulfuryl chloride fluorination includes sulfuryl fluoride synthesis, where a solvent and a hydrogen fluoride complex are added to a reaction kettle, the reaction system is cooled to 10? C. or less, and sulfuryl chloride is then added dropwise under atmospheric pressure while the temperature of the reaction system is controlled to 60? C. or less to obtain sulfuryl fluoride.

A method for preparing sulfuryl fluoride by electrofluorination is described. The method for preparing sulfuryl fluoride by electrofluorination comprises a step of subjecting sulfur dioxide and a hydrogen fluoride complex to an electrofluorination reaction in an electrolytic cell. By means of this, the production cost of sulfuryl fluoride can be reduced, and the purity and yield of sulfuryl fluoride can be improved, thus making it suitable for industrial production.

The present application provides a method of preparing sulfuryl fluoride, including the following steps of: S1) reacting sulfur trioxide steam with barium fluoride to acquire a mixed gas of barium sulphate and sulfuryl fluoride; S2) pickling the mixed gas acquired in step S1 with a concentrated sulfuric acid solution with a concentration of 70-98.3 wt. % to acquire a primary purified sulfuryl fluoride gas; S3) passing the primary purified sulfuryl fluoride gas acquired in step S2 through an aqueous solution with a concentration of 2-10 wt. % selected from at least one of the following: sodium sulfite, sodium bisulfite, sodium pyrosulfite, and sodium thiosulfate, to acquire a sulfuryl fluoride gas.