The present invention relates to a novel integrated system for providing nitrogen (N2) to a variety of industrial service applications such as, for example, process unit drying, pipeline purging, reactor cooling, vessel inerting, pipeline displacement.

The present invention provides a refrigerator, comprising: an adsorption container, an air compressor and a nitrogen storage tank. A sealed storage space is formed in a storage compartment of the refrigerator. The adsorption container with carbon molecular sieves disposed therein is disposed in the storage compartment. The air compressor is directly connected to the adsorption container through an air inlet pipe and configured to supply compressed air for the adsorption container in a controlled manner so as to allow the carbon molecular sieves to prepare nitrogen by means of the compressed air. A gas inlet end of the nitrogen storage tank is connected to the adsorption container, and a gas outlet end thereof is communicated with the storage space.

The present invention provides a refrigerating and freezing device. A first sealed space and a second sealed space are disposed in a storage space inside the refrigerating and freezing device. The refrigerating and freezing device is further provided with a nitrogen generation device, which comprises an adsorption device and an air compressor that supplies compressed air for the adsorption device. The adsorption device utilizes the compressed air to prepare nitrogen that is provided for the first sealed space and an oxygen-enriched gas that is provided for the second sealed space. The freshness preservation capability of the first sealed space is improved. The bioactivity of food in the second sealed space is guaranteed.

The present invention relates to a novel integrated system for providing nitrogen (N2) to a variety of industrial service applications such as, for example, process unit drying, pipeline purging, reactor cooling, vessel inerting, pipeline displacement.

A method of producing an oxide of manganese including reacting, in a first aqueous solution, a manganese salt and an alkali agent to form manganese hydroxide; separating the manganese hydroxide from the first solution; mixing the manganese hydroxide into an aqueous medium to form a manganese hydroxide suspension; mixing the manganese hydroxide suspension with alkali metal hydroxide to form a second aqueous solution; and oxidizing the manganese hydroxide in the second aqueous solution to form an oxide of manganese. The dried oxide of manganese includes birnessite, a maximum of 20% hausmannite, and a maximum of 10% feitknechtite, may further include a maximum of 400 ppm of anions, may have a specific surface area of at least 25 m.sup.2/g, and may have an average oxidation state of greater than 3.5.

The present invention provides a refrigerator, comprising: an adsorption container, an air compressor and a nitrogen storage tank. A sealed storage space is formed in a storage compartment of the refrigerator. The adsorption container with carbon molecular sieves disposed therein is disposed in the storage compartment. The air compressor is directly connected to the adsorption container through an air inlet pipe and configured to supply compressed air for the adsorption container in a controlled manner so as to allow the carbon molecular sieves to prepare nitrogen by means of the compressed air. A gas inlet end of the nitrogen storage tank is connected to the adsorption container, and a gas outlet end thereof is communicated with the storage space.

The present invention provides a refrigerating and freezing device. A first sealed space and a second sealed space are disposed in a storage space inside the refrigerating and freezing device. The refrigerating and freezing device is further provided with a nitrogen generation device, which comprises an adsorption device and an air compressor that supplies compressed air for the adsorption device. The adsorption device utilizes the compressed air to prepare nitrogen that is provided for the first sealed space and an oxygen-enriched gas that is provided for the second sealed space. The freshness preservation capability of the first sealed space is improved. The bioactivity of food in the second sealed space is guaranteed.

A method of producing an oxide of manganese including reacting, in a first aqueous solution, a manganese salt and an alkali agent to form manganese hydroxide; separating the manganese hydroxide from the first solution; mixing the manganese hydroxide into an aqueous medium to form a manganese hydroxide suspension; mixing the manganese hydroxide suspension with alkali metal hydroxide to form a second aqueous solution; and oxidizing the manganese hydroxide in the second aqueous solution to form an oxide of manganese. The dried oxide of manganese includes birnessite, a maximum of 20% hausmannite, and a maximum of 10% feitknechtite, may further include a maximum of 400 ppm of anions, may have a specific surface area of at least 25 m2/g, and may have an average oxidation state of greater than 3.5.

Apparatus, system, and method for geothermally driven ammonia production. Hydrogen is generated using energy obtained from the underground magma reservoir and nitrogen is captured from air using the energy obtained from the underground magma reservoir. At least a portion of the generated hydrogen is combined with at least a portion of the generated nitrogen and heated at least to a reaction temperature using the energy obtained from the underground magma reservoir. The heated hydrogen contacts the heated nitrogen for a residence time to form the ammonia.