The present disclosure provides a method for generating higher hydrocarbon(s) from a stream comprising compounds with two or more carbon atoms (C.sub.2+), comprising introducing methane and an oxidant (e.g., O.sub.2) into an oxidative coupling of methane (OCM) reactor. The OCM reactor reacts the methane with the oxidant to generate a first product stream comprising the C.sub.2+ compounds. The first product stream can then be directed to a separations unit that recovers at least a portion of the C.sub.2+ compounds from the first product stream to yield a second product stream comprising the at least the portion of the C.sub.2+ compounds.

Methods are provided for the production of nitrogen, hydrogen, and carbon dioxide from an exhaust gas. Exhaust gas from combustion in a fuel rich (or reducing) atmosphere is primarily composed of CO.sub.2, CO, N.sub.2, H.sub.2O, and H.sub.2. CO may be converted to CO.sub.2 and H.sub.2 via the water gas shift reaction. Carbon dioxide may then be effectively separated from nitrogen and hydrogen to produce a carbon dioxide stream and a nitrogen/hydrogen stream. The nitrogen/hydrogen stream may then be effectively separated to produce a high purity nitrogen stream and a high purity hydrogen stream. The process may be done in any order, such as separating the nitrogen first or the carbon dioxide first.

Disclosed herein are new processes for adsorbing oxygen using adsorbent compositions comprising RHO zeolites kinetically selective for oxygen. The RHO zeolites can be used in pressure swing adsorption processes for separating oxygen from oxygen containing streams, such as for, but not limited to, purifying a crude argon feed stream or separating oxygen from an air feed stream.

Systems and methods for producing a product gas are provided. In one embodiment, a system includes at least one separation bed to separate adsorbable components from a gas source, a valving means to selectively direct gas from the gas source to the at least one separation bed, at least one sensing device associated with the at least one separation bed to sense the progress of an adsorption zone within the separation bed, and a controller. The controller includes logic to read the output of the at least one sensing device and control the gas separation process based on the progress of the adsorption zone.

Disclosed herein are new processes for adsorbing oxygen using adsorbent compositions comprising RHO zeolites kinetically selective for oxygen. The RHO zeolites can be used in pressure swing adsorption processes for separating oxygen from oxygen containing streams, such as for, but not limited to, purifying a crude argon feed stream or separating oxygen from an air feed stream.

The present disclosure provides a method for generating higher hydrocarbon(s) from a stream comprising compounds with two or more carbon atoms (C.sub.2+), comprising introducing methane and an oxidant (e.g., O.sub.2) into an oxidative coupling of methane (OCM) reactor. The OCM reactor reacts the methane with the oxidant to generate a first product stream comprising the C.sub.2+ compounds. The first product stream can then be directed to a separations unit that recovers at least a portion of the C.sub.2+ compounds from the first product stream to yield a second product stream comprising the at least the portion of the C.sub.2+ compounds.

Systems and methods for producing a product gas are provided. In one embodiment, a system includes at least one separation bed to separate adsorbable components from a gas source, a valving means to selectively direct gas from the gas source to the at least one separation bed, at least one sensing device associated with the at least one separation bed to sense the progress of an adsorption zone within the separation bed, and a controller. The controller includes logic to read the output of the at least one sensing device and control the gas separation process based on the progress of the adsorption zone.

Methods are provided for the production of nitrogen, hydrogen, and carbon dioxide from an exhaust gas. Exhaust gas from combustion in a fuel rich (or reducing) atmosphere is primarily composed of CO.sub.2, CO, N.sub.2, H.sub.2O, and H.sub.2. CO may be converted to CO.sub.2 and H.sub.2 via the water gas shift reaction. Carbon dioxide may then be effectively separated from nitrogen and hydrogen to produce a carbon dioxide stream and a nitrogen/hydrogen stream. The nitrogen/hydrogen stream may then be effectively separated to produce a high purity nitrogen stream and a high purity hydrogen stream. The process may be done in any order, such as separating the nitrogen first or the carbon dioxide first.

This invention refers to a microporous crystalline material of zeolitic nature that has, in its calcined state and in the absence of defects in its crystalline matrix manifested by the presence of silanols, the empirical formula
x(M.sub.1/nXO.sub.2):yYO.sub.2:gGeO.sub.2:(1-g)SiO2 in which M is selected between H.sup.+, at least one inorganic cation of charge +n, and a mixture of both, X is at least one chemical element of oxidation state +3, Y is at least one chemical element with oxidation state +4 different from Si, x takes a value between 0 and 0.2, both included, y takes a value between 0 and 0.1, both included, g takes a value between 0 and 0.5, both included that has been denoted ITQ-55, a method for its preparation and its use.

This invention refers to a microporous crystalline material of zeolitic nature that has, in its calcined state and in the absence of defects in its crystalline matrix manifested by the presence of silanols, the empirical formula
x(M.sub.1/nXO.sub.2):yYO.sub.2:gGeO.sub.2:(1g)SiO2 in which M is selected between H.sup.+, at least one inorganic cation of charge +n, and a mixture of both, X is at least one chemical element of oxidation state +3, Y is at least one chemical element with oxidation state +4 different from Si, x takes a value between 0 and 0.2, both included, y takes a value between 0 and 0.1, both included, g takes a value between 0 and 0.5, both included
that has been denoted ITQ-55, as well as a method for its preparation. This invention also relates to uses of the crystalline material of zeolitic nature for adsorption of fluid components, membrane separation of fluid components, storage of fluid components, and catalysis of various conversion reactions.