C01B2203/1619

HEAT AND HYDROGEN GENERATION DEVICE

A burner combustion chamber (3), a reformer catalyst (4) to which burner combustion gas is fed, and a heat exchange part (13a) for heating the air fed to the burner (7) are provided. When the temperature of the reformer catalyst (4) exceeds the allowable catalyst temperature (TX) or when it is predicted the temperature of the reformer catalyst (4) will exceed the allowable catalyst temperature (TX), the air circulation route for guiding air to the burner (7) is switched from a high temperature air circulation route (13) for guiding air heated by the heat exchange part (13a) to the burner (7) to a low temperature air circulation route (14) for guiding air not flowing within the heat exchange part (13a) and lower in temperature than the air heated at the heat exchange part (13a) to the burner (7).

METHOD FOR IMPROVING THE HOMOGENIZATION OF THE TEMPERATURES IN A STEAM METHANE REFORMER BY ADJUSTING THE POWER DISTRIBUTION

A method of improving an endothermic process in a furnace utilizing steps a) calibrating the simplified physical model of step c3) by measuring one or more tube temperature for at least a tube impacted by the throttling of a burner in standard and in throttled state, b) acquiring information on a tube temperature for the tubes present in the furnace with all the burners present in the furnace under standard non-throttled conditions, c) getting a map of burners to throttle including c1) choosing at least one parameter representative of the performances of the furnace with a target of improvement, c2) choosing at least one or more power ratio for the burner throttling; c3) utilizing the information of step b) and a simplified physical model of the impact of throttling a burner on the tube temperature, c4) getting a map of burners to throttle, step d) throttling the burners.

FUEL REFORMING APPARATUS
20230219813 · 2023-07-13 ·

A fuel reforming apparatus includes a pre-reformer that converts a fuel gas to methane by bringing the fuel gas into a reaction with water, a reformer that generates a mixture gas including hydrogen by bringing the fuel gas pre-reformed by the pre-reformer into a reaction with the water, a reformer burner that supplies heat to the reformer, and an exhaust gas supply line that causes an exhaust gas discharged from the reformer burner to be supplied to the pre-reformer as a heat source for the reaction of the pre-reformer.

STEAM/CARBON RATIO DETECTION AND CONTROL
20220389338 · 2022-12-08 ·

An ejector receives steam at a primary inlet and natural gas at a secondary inlet. A computer responds to a signal indicating current in the load of a fuel cell as well as a signal indicating temperature of a steam reformer to move a linear actuator to control a needle that adjusts the size of the steam orifice. Reformate is fed to a separator scrubber which cools the reformate to its dew point indicated by a sensor. From that, a controller generates the fuel/carbon ratio for display and to bias a signal on a line regulating the amount of steam passing through an ejector to the inlet of the reformer. Alternatively, the reformate may be cooled to its dew point by a controllable heat exchanger in response to pressure and temperature signals.

REFORMING DEVICE AND REFORMING SYSTEM

A reforming device is provided with: a reformer in which an ammonia gas is burnt by air to generate heat to reform the ammonia gas utilizing the generated heat; a supply pipe through which a gas comprising the ammonia gas and air to be fed to the reformer flows; a gas inlet which is arranged in the supply pipe and through which the ammonia gas and air are introduced into the inside of the supply pipe in such a manner that a tubular flow can be generated; an igniter which can ignite the ammonia gas introduced into the inside of the supply pipe through the gas inlet; and an ammonia gas inlet which is arranged in the supply pipe on a side closer to the reformer than the gas inlet and through which the ammonia gas is introduced into the inside of the supply pipe.

Hydrogen purification devices

Hydrogen purification devices and their components are disclosed. In some embodiments, the devices may include at least one foil-microscreen assembly disposed between and secured to first and second end frames. The at least one foil-microscreen assembly may include at least one hydrogen-selective membrane and at least one microscreen structure including a non-porous planar sheet having a plurality of apertures forming a plurality of fluid passages. The planar sheet may include generally opposed planar surfaces configured to provide support to the permeate side. The plurality of fluid passages may extend between the opposed surfaces. The at least one hydrogen-selective membrane may be metallurgically bonded to the at least one microscreen structure. In some embodiments, the devices may include a permeate frame having at least one membrane support structure that spans at least a substantial portion of an open region and that is configured to support at least one foil-microscreen assembly.

Device for measuring the inner temperature of a reforming tube

A device for measuring the internal temperature of a reforming tube including a first structure having an axial part of tubular shape positioned in the lengthwise direction of a reforming tube and a radial part projecting radially towards the central axis of the reforming tube, a second structure of oblong shape having at least one thermocouple made of welded Nicrosil/Nisil conductors arranged longitudinally against the axial part and radially against the radial part, and an outer sheath enveloping the first structure and the second structure.

COMBUSTION CONTROL APPARATUS OF LPG REFORMING SYSTEM AND METHOD FOR CONTROLLING THE SAME
20220341591 · 2022-10-27 · ·

A combustion control apparatus of an Liquefied Petroleum Gas (LPG) reforming system and a method for controlling the same may include a burner provided to supply heat to a reformer, a flame temperature analyzer configured to analyze a flame temperature of the burner, an air flow rate calculator configured to determine an initial value of a flow rate of air to be supplied to the burner depending on a flow rate of fuel gas supplied to the burner, and an air flow rate controller electrically connected to the air flow rate calculator and the flame temperature analyzer and configured to select the flow rate of the air at which the flame temperature transmitted by the flame temperature analyzer reaches a maximum while changing the flow rate of the air from the initial value and to control supply of the selected flow rate of the air to the burner.

CPOX reactor control system and method

A fuel reformer module (8005) for initiating catalytic partial oxidation (CPOX) to reform a hydrocarbon fuel oxidant mixture (2025, 3025) to output a syngas reformate (2027) to solid oxide fuel cell stack (2080, 5040). A solid non-porous ceramic catalyzing body (3030) includes a plurality of catalyst coated fuel passages (3085). A thermally conductive element (9005, 10005, 11005, 13005), with a coefficient of thermal conductivity of 50 W/m° K or greater is thermally conductively coupled with the catalyzing body. A first thermal sensor (8030) is thermally conductively coupled with the thermally conductive element. A second thermal sensor is thermally conductively coupled with a surface of the fuel cell stack. A control method independently modulates an oxidant input flow rate, based on first thermal sensor signal values, a hydrocarbon fuel input flow rate, based on second thermal sensor signal values.

METHOD AND DEVICE FOR DETECTING INTERNAL CARBON DEPOSITION OF A SOLID OXIDE FUEL CELL SYSTEM
20220328853 · 2022-10-13 ·

A method and a device for detecting internal carbon deposition of a solid oxide fuel cell system. The method comprises the following steps: adjusting a temperature in a reformer of the solid oxide fuel cell system so that a mixed gas discharged from the reformer is at a detection temperature; sampling the mixed gas; detecting a gas sample to obtain a mole fraction of each gas, and calculating an equilibrium constant K1 of a Boudouard reaction according to the obtained mole fraction; calculating an equilibrium constant K2 of the Boudouard reaction according to thermodynamics; comparing K1 and K2, if K1 is less than K2, determining that there will be no carbon deposition in the solid oxide fuel cell system; and if K1 is greater than K2, determining that there will be carbon deposition in the solid oxide fuel cell system. By using the method, a carbon deposition condition in the solid oxide fuel cell system can be detected to effect early warning regarding the solid oxide fuel cell system and take preventive measures