Disclosed is a phosphorus coal gasification reaction device for combined production of yellow phosphorus and syngas, including a stock bin, a mineral aggregate lock hopper, a phosphorous coal gasification reactor, a slag quench chamber and a slag lock hopper. In the phosphorous coal gasification reactor, a drying zone, a dry distillation zone, a combustion zone, a phosphate rock reduction zone, and a slag bath zone are formed from top to bottom. A gas product outlet communicating with the phosphorous coal gasification reactor is installed at a top of the phosphorous coal gasification reactor, two to eight fuel burners are symmetrically arranged on the combustion zone, and an auxiliary burner communicating with the slag bath zone is arranged at the bottom of the slag bath zone. The reactor device can improve the production capacity of the yellow phosphorus, and reduce the emission of CO.sub.2.

Disclosed is a phosphorus coal gasification reaction device for combined production of yellow phosphorus and syngas, including a stock bin, a mineral aggregate lock hopper, a phosphorous coal gasification reactor, a slag quench chamber and a slag lock hopper. In the phosphorous coal gasification reactor, a drying zone, a dry distillation zone, a combustion zone, a phosphate rock reduction zone, and a slag bath zone are formed from top to bottom. A gas product outlet communicating with the phosphorous coal gasification reactor is installed at a top of the phosphorous coal gasification reactor, two to eight fuel burners are symmetrically arranged on the combustion zone, and an auxiliary burner communicating with the slag bath zone is arranged at the bottom of the slag bath zone. The reactor device can improve the production capacity of the yellow phosphorus, and reduce the emission of CO.sub.2.

A system for combined production of yellow phosphorous and syngas is disclosed. The air separation unit, the pulverized coal preparation unit and the mineral aggregate forming unit are respectively connected to a gas inlet and a top feeding port of the phosphorus coal gasifier; phosphorus-containing syngas obtained from phosphorus coal gasifier is connected to a gas inlet of the separating washing unit through an outlet of the phosphorous coal gasifier; Yellow phosphorus products and crude syngas are respectively output from the output port of the separating washing unit; and then the crude syngas is purified to obtain refined syngas. A slag discharge port at the bottom of the phosphorus coal gasifier is connected to an input port of a slag cold quenching unit. The system can improve the available energy of yellow phosphorous production, the production capacity of yellow phosphorus and the yield of syngas, and reduce CO.sub.2 emission.

A method, apparatus and special phosphorus recovery device for recovering yellow phosphorus from an electric furnace phosphorus-producing furnace gas without the use of a spray cooling mode during the condensation of the electric furnace phosphorus-producing furnace gas. The method comprises the steps: 1) dedusting and purifying the electric furnace phosphorus-producing furnace gas by using a dry-type dedusting system, so that the solid content of the electric furnace phosphorus-producing furnace gas in less than or equal to 10-50 mg/m.sup.3; 2) conveying the purified furnace gas to a phosphorus recovery device, the phosphorus recovery device being provided with a heat exchange chamber formed by a shell and a recuperator arranged inside the heat exchange chamber; 3) feeding into an internal flow path of the recuperator a low-temperature medium, which conducts non-mixed heat transfer with the furnace gas under the isolation of the recuperator, so that the yellow phosphorus is condensed, separated out, and then vastly attached to the surface of the recuperator, and the tail gas arising from heat exchange is discharged out of the phosphorus recovery device; and 4) feeding a high-temperature medium for replacing the low-temperature medium into the internal flow path of the recuperator.

A method, apparatus and special phosphorus recovery device for recovering yellow phosphorus from an electric furnace phosphorus-producing furnace gas without the use of a spray cooling mode during the condensation of the electric furnace phosphorus-producing furnace gas. The method comprises the steps: 1) dedusting and purifying the electric furnace phosphorus-producing furnace gas by using a dry-type dedusting system, so that the solid content of the electric furnace phosphorus-producing furnace gas in less than or equal to 10-50 mg/m.sup.3; 2) conveying the purified furnace gas to a phosphorus recovery device, the phosphorus recovery device being provided with a heat exchange chamber formed by a shell and a recuperator arranged inside the heat exchange chamber; 3) feeding into an internal flow path of the recuperator a low-temperature medium, which conducts non-mixed heat transfer with the furnace gas under the isolation of the recuperator, so that the yellow phosphorus is condensed, separated out, and then vastly attached to the surface of the recuperator, and the tail gas arising from heat exchange is discharged out of the phosphorus recovery device; and 4) feeding a high-temperature medium for replacing the low-temperature medium into the internal flow path of the recuperator.

The subject of the invention is the development of a new process for producing phosphorus P4 from phosphoric acid. In this process, the phosphoric acid and a hydrophilic source of carbon and of hydrogen (biomass, kerogen, “STEP” purification plant sludge, organic polymer) are mixed, and the mixture is treated at a temperature of 80 to 150° C. in order to ensure grafting of the phosphates on the carbon backbone. The production of the phosphorus P4 is carried out by heat treatment of the precursor at a temperature at which phosphorus is produced. The temperature range is from 550° C. to 950° C. This process can be carried out at temperatures below those of conventional phosphorus production without the occurrence of the production of solid by-products normally formed in conventional phosphorus production. The process can be used to produce phosphoric acid for food or medical use.

The present disclosure provides a method for producing value-added by-product yellow phosphorus slag through an unconventional electric furnace process, derived from yellow phosphorus. This method is related to the technical field of comprehensive utilization of mineral resources. The disclosed method involves the following steps: mixing mid-low-grade phosphate rock, silica, coke, and a cosolvent to create a blended material, subjecting the blended material to high-temperature reduction in a yellow phosphorus electric furnace to yield yellow phosphorus and water-quenched slag, and then drying the water-quenched slag using yellow phosphorus tail gas to obtain the yellow phosphorus slag. According to this disclosure, a P.sub.2O.sub.5CaOSiO.sub.2MgOR multi-component system is established using the blended material.

The present disclosure provides a method for producing value-added by-product yellow phosphorus slag through an unconventional electric furnace process, derived from yellow phosphorus. This method is related to the technical field of comprehensive utilization of mineral resources. The disclosed method involves the following steps: mixing mid-low-grade phosphate rock, silica, coke, and a cosolvent to create a blended material, subjecting the blended material to high-temperature reduction in a yellow phosphorus electric furnace to yield yellow phosphorus and water-quenched slag, and then drying the water-quenched slag using yellow phosphorus tail gas to obtain the yellow phosphorus slag. According to this disclosure, a P.sub.2O.sub.5CaOSiO.sub.2MgOR multi-component system is established using the blended material.

A method, apparatus and special phosphorus recovery device for recovering yellow phosphorus from an electric furnace phosphorus-producing furnace gas without the use of a spray cooling mode during the condensation of the electric furnace phosphorus-producing furnace gas. The method comprises the steps: 1) dedusting and purifying the electric furnace phosphorus-producing furnace gas by using a dry-type dedusting system, so that the solid content of the electric furnace phosphorus-producing furnace gas in less than or equal to 10-50 mg/m.sup.3; 2) conveying the purified furnace gas to a phosphorus recovery device, the phosphorus recovery device being provided with a heat exchange chamber formed by a shell and a recuperator arranged inside the heat exchange chamber; 3) feeding into an internal flow path of the recuperator a low-temperature medium, which conducts non-mixed heat transfer with the furnace gas under the isolation of the recuperator, so that the yellow phosphorus is condensed, separated out, and then vastly attached to the surface of the recuperator, and the tail gas arising from heat exchange is discharged out of the phosphorus recovery device; and 4) feeding a high-temperature medium for replacing the low-temperature medium into the internal flow path of the recuperator.

A method, apparatus and special phosphorus recovery device for recovering yellow phosphorus from an electric furnace phosphorus-producing furnace gas without the use of a spray cooling mode during the condensation of the electric furnace phosphorus-producing furnace gas. The method comprises the steps: 1) dedusting and purifying the electric furnace phosphorus-producing furnace gas by using a dry-type dedusting system, so that the solid content of the electric furnace phosphorus-producing furnace gas in less than or equal to 10-50 mg/m.sup.3; 2) conveying the purified furnace gas to a phosphorus recovery device, the phosphorus recovery device being provided with a heat exchange chamber formed by a shell and a recuperator arranged inside the heat exchange chamber; 3) feeding into an internal flow path of the recuperator a low-temperature medium, which conducts non-mixed heat transfer with the furnace gas under the isolation of the recuperator, so that the yellow phosphorus is condensed, separated out, and then vastly attached to the surface of the recuperator, and the tail gas arising from heat exchange is discharged out of the phosphorus recovery device; and 4) feeding a high-temperature medium for replacing the low-temperature medium into the internal flow path of the recuperator.