C01B7/09

RECOVERY OF BROMINE FROM WASTE BROMIDE BRINES
20230234846 · 2023-07-27 ·

A process includes supplying a bromide brine and removing organic compounds from the bromide brine. The method also includes acidifying the bromide brine to form a stream containing hydrobromic acid and separating the hydrobromic acid from the stream containing hydrobromic acid.

GAS TO HYDROGEN PROCESS WITH CO-PRODUCTION OF CARBON

The disclosure relates in its first aspect to a process of conversion of a gaseous stream comprising methane into hydrogen (51) and carbon (25), the process is remarkable in that it comprises a step (a) of providing a first gaseous stream (3, 7); a step (b) of bromination and synthesis in which the first gaseous stream (3, 7) is put in contact with a second stream (53) comprising bromine resulting in the formation of a third stream (15) comprising methyl bromides and hydrogen bromide, and of a fourth stream (25) comprising carbon including graphite and/or carbon black; a step (c) of separation performed on the third stream (15) to recover a hydrogen bromide-rich stream (41) which is then oxidized in a step (d) to produce a stream (51) comprising hydrogen. The second aspect relates to the installation for performing the process of the first aspect and the third aspect concerns the use of bromine in such process.

A METHOD OF SEPARATING AND RECOVERING BROMINE FROM PRINTED CIRCUIT BOARD INCINERATION ASH BY TWO-STEP PROCESS
20230192488 · 2023-06-22 ·

The invention relates to the field of efficient separation and recovery of bromine by full wet method, especially to a two-step separating method of bromide and recovery of lead and zinc from printed circuit board Incineration ash. It mainly includes first sodium hydroxide alkaline leaching, secondary sodium peroxide alkaline leaching, pH adjustment, separate lead and zinc, bromide evaporation and crystallization to recover crude bromide and other steps. Compared with traditional comprehensive recovery process of ash, the invention uses sodium hydroxide to dissolve bromide, lead and zinc, and uses the strong oxidation of sodium peroxide in alkaline environment, copper bromide and other bromine are oxidized and leached; through two-step method, the efficient leaching of bromine, lead and zinc is realized, silver and other precious metals are enriched at the same time. It is beneficial to subsequent recovery of precious metals and has the characteristics of short tail liquid discharge.

Evaporative gas generating device, method for producing evaporative gas, hydrogen bromide production device, and method for producing hydrogen bromide
09835325 · 2017-12-05 · ·

An evaporative gas generating device and a method for producing evaporative gas. A hydrogen bromide production device and a method for producing hydrogen bromide are also disclosed. The hydrogen bromide production device is provided with an evaporative gas generating device (1) that generates bromine gas, and a reactor (3) that reacts the bromine gas with hydrogen gas to form hydrogen bromide. The evaporative gas generating device (1) is provided with a container (10) that accommodates liquid bromine (B), and heating jackets (35, 36) that supply heat to a wall surface of the container (10), and heat and evaporate the liquid bromine (B) within a liquid accommodating part (15) of the container (10) to raise the temperature of the bromine gas within the evaporative gas accommodating part (16).

ELECTROLYTIC STRIPPING AGENT FOR JIG

An object of the invention is to provide a jig electrolytic stripper that can sufficiently remove palladium adhered to the current-conducting portion of a plating jig, that can remove palladium adhered to the insulating-material-coated portion of the jig, and that exhibits reduced erosion of the metal of the current-conducting portion of the jig. The jig electrolytic stripper comprises the following components (A) to (C): (A) at least one member selected from the group consisting of nitric acid and salts thereof, (B) at least one member selected from the group consisting of ammonia, ammonium salts, ethylene amine compounds, alkyl diamine compounds, and amino acids, and (C) a bromide.

PROCESSES USEFUL IN THE MANUFACTURE OF CYCLODODECASULFUR

Methods for producing cyclododecasulfur are disclosed, that include the steps of: oxidizing a bromide in aqueous solution to produce a mixture of molecular bromine, tribromide, and bromide; reducing water to produce hydrogen and a hydroxide; and reacting a metallasulfur derivative with the molecular bromine, to produce cyclododecasulfur and a metallabromide derivative.

Gas to olefins processes with coproduction of hydrogen
11739035 · 2023-08-29 ·

The present disclosure relates in its first aspect to a process of converting a stream comprising methane into chemicals, said process being remarkable in that it comprises the steps of providing a first stream (1, 5, 11) comprising methane, providing a second stream (79) which is a bromine-rich stream, putting into contact said first stream (15) with said second stream (79) to obtain a third stream (21) comprising at least unreacted methane, methyl bromide, dibromomethane, and hydrogen bromide and removing said dibromomethane from said third stream (21), to produce a dibromomethane stream (103) and a fourth stream (27) comprising unreacted methane, methyl bromide and hydrogen bromide; wherein the fourth stream (27) is converted into chemicals. In its second aspect, the present disclosure concerns an installation for carrying out the process of the first aspect.

PROCESS FOR RECOVERY AND SEPARATION OF BROMINE AND WATER FROM OXIDATION OF HYDROGEN BROMIDE
20220009775 · 2022-01-13 ·

A hydrogen bromide (HBr) oxidation/quench system includes a heat exchanger reactor and an adiabatic catalytic reactor in fluid communication with the heat exchanger reactor. The system also includes a quench vessel, the quench vessel in fluid communication with the adiabatic catalytic reactor. The quench vessel has a flange. In addition, the system includes a joined three phase separator and absorber column, wherein both the three phase separator and the absorber column are in fluid communication with the quench vessel and an aqueous stripping column in fluid communication the heat exchanger reactor and the absorber column.

Electrolytic stripping agent for jig

An object of the invention is to provide a jig electrolytic stripper that can sufficiently remove palladium adhered to the current-conducting portion of a plating jig, that can remove palladium adhered to the insulating-material-coated portion of the jig, and that exhibits reduced erosion of the metal of the current-conducting portion of the jig. The jig electrolytic stripper comprises the following components (A) to (C): (A) at least one member selected from the group consisting of nitric acid and salts thereof, (B) at least one member selected from the group consisting of ammonia, ammonium salts, ethylene amine compounds, alkyl diamine compounds, and amino acids, and (C) a bromide.

GAS TO OLEFINS PROCESSES WITH COPRODUCTION OF HYDROGEN

The present disclosure relates in its first aspect to a process of converting a stream comprising methane into chemicals, said process being remarkable in that it comprises the steps of providing a first stream (1, 5, 11) comprising methane, providing a second stream (79) which is a bromine-rich stream, putting into contact said first stream (15) with said second stream (79) to obtain a third stream (21) comprising at least unreacted methane, methyl bromide, dibromomethane, and hydrogen bromide and removing said dibromomethane from said third stream (21), to produce a dibromomethane stream (103) and a fourth stream (27) comprising unreacted methane, methyl bromide and hydrogen bromide; wherein the fourth stream (27) is converted into chemicals. In its second aspect, the present disclosure concerns an installation for carrying out the process of the first aspect.