A system and method for production of ammonia are presented. The system includes a reactor adapted to receive therein through a first input of the reactor sulfate ammonia and a reacting agent through a second input of the reactor, wherein the reactor is heated to a temperature not to exceed a predetermined temperature to create a chemical reaction between a sulfate ammonia and the reacting agent; and a purifier adapted to accept ammonia from the reactor and perform a purification process to purify the ammonia to a predetermined degree of purification.

Described herein is a process for the production of potassium sulfate and ammonium sulfate from syngenite. Specifically, the syngenite is produced from waste liquors and low value minerals and is used to produce valuable secondary products. Specifically, instead of performing the decomposition reaction in one step at high temperature, this process performs the reaction in 2 steps at temperatures lower than the decomposition temperature of ammonium bicarbonate: a first step to reach the equilibrium and produce saturated potassium sulfate brine, and a second step to complete the syngenite decomposition reaction.

The present disclosure relates to a process for the production of potassium sulphate based mineral fertilizers, by means of an exchange reaction between potassium chloride and ammonium sulphate (2KCl+(NH.sub.4).sub.2SO.sub.4<.fwdarw.K.sub.2SO.sub.4+2NH.sub.4Cl) in controlled conditions. The process, subject of the invention, makes it possible to obtain, in a single reaction stage, a crystalline product classifiable as low-chlorine-content mineral fertilizer, containing potassium sulphate, with K.sub.2O in an amount of between 40% and 50% by dry weight, ammoniacal nitrogen in an amount of less than 5% by dry weight and chlorine in an amount of less than 3% by dry weight, with a high potassium-conversion efficiency (calculated as the ratio between what the amount found in the solid main product and the amount introduced as KCl to the reaction with ammonium sulphate) and a by-product, which can be used directly as NK fertilizer (containing nitrogen (N) and potassium oxide (K.sub.2O) both in an amount comprised between 15% and 20% by dry weight) or as raw material for the production of complex fertilizers.

The present disclosure relates to a process for the production of potassium sulphate based mineral fertilizers, by means of an exchange reaction between potassium chloride and ammonium sulphate (2KCl+(NH.sub.4).sub.2SO.sub.4<.fwdarw.K.sub.2SO.sub.4+2NH.sub.4Cl) in controlled conditions. The process, subject of the invention, makes it possible to obtain, in a single reaction stage, a crystalline product classifiable as low-chlorine-content mineral fertilizer, containing potassium sulphate, with K.sub.2O in an amount of between 40% and 50% by dry weight, ammoniacal nitrogen in an amount of less than 5% by dry weight and chlorine in an amount of less than 3% by dry weight, with a high potassium-conversion efficiency (calculated as the ratio between what the amount found in the solid main product and the amount introduced as KCl to the reaction with ammonium sulphate) and a by-product, which can be used directly as NK fertilizer (containing nitrogen (N) and potassium oxide (K.sub.2O) both in an amount comprised between 15% and 20% by dry weight) or as raw material for the production of complex fertilizers.

A process for treating an ammonium fluorosulfate byproduct includes providing an ammonium fluorosulfate byproduct including primarily ammonium fluorosulfate and lesser amounts of fluorosulfonic acid and bis(fluorosulfonyl) imide, mixing the ammonium fluorosulfate byproduct with water, reacting the mixture of the ammonium fluorosulfate byproduct and the water at a hydrolysis reaction temperature to hydrolyze the ammonium fluorosulfate, the fluorosulfonic acid and the bis(fluorosulfonyl) imide to form ammonium bisulfate and aqueous hydrogen fluoride; and separating the ammonium bisulfate from the aqueous hydrogen fluoride.

A process for treating an ammonium fluorosulfate byproduct includes providing an ammonium fluorosulfate byproduct including primarily ammonium fluorosulfate and lesser amounts of fluorosulfonic acid and bis(fluorosulfonyl) imide, mixing the ammonium fluorosulfate byproduct with water, reacting the mixture of the ammonium fluorosulfate byproduct and the water at a hydrolysis reaction temperature to hydrolyze the ammonium fluorosulfate, the fluorosulfonic acid and the bis(fluorosulfonyl) imide to form ammonium bisulfate and aqueous hydrogen fluoride; and separating the ammonium bisulfate from the aqueous hydrogen fluoride.

A method for preparing a cathode active material precursor for a secondary battery, including: moving a co-precipitation filtrate generated after a co-precipitation reaction to a co-precipitation filtrate storage tank; removing a metal hydroxide by passing the co-precipitation filtrate through a filter; reacting the co-precipitation filtrate from which the metal hydroxide is removed with sulfuric acid or nitric acid to produce an ammonium sulfate or an ammonium nitrate while removing ammonia from the co-precipitation filtrate from which the metal hydroxide is removed; cooling and crystallizing the co-precipitation filtrate from which the metal hydroxide and ammonia are removed to precipitate a sodium sulfate; filtering the precipitated sodium sulfate to separate the precipitated sodium sulfate from the co-precipitation filtrate from which the metal hydroxide and ammonia are removed; drying the sodium sulfate separated from the co-precipitation filtrate and moving the co-precipitation filtrate separated from the sodium sulfate to a circulation concentration tank; and heating the co-precipitation filtrate stored in the circulation concentration tank to a predetermined temperature for recycling and performing N.sub.2 purging or bubbling, is provided.

A method for preparing a cathode active material precursor for a secondary battery, including: moving a co-precipitation filtrate generated after a co-precipitation reaction to a co-precipitation filtrate storage tank; removing a metal hydroxide by passing the co-precipitation filtrate through a filter; reacting the co-precipitation filtrate from which the metal hydroxide is removed with sulfuric acid or nitric acid to produce an ammonium sulfate or an ammonium nitrate while removing ammonia from the co-precipitation filtrate from which the metal hydroxide is removed; cooling and crystallizing the co-precipitation filtrate from which the metal hydroxide and ammonia are removed to precipitate a sodium sulfate; filtering the precipitated sodium sulfate to separate the precipitated sodium sulfate from the co-precipitation filtrate from which the metal hydroxide and ammonia are removed; drying the sodium sulfate separated from the co-precipitation filtrate and moving the co-precipitation filtrate separated from the sodium sulfate to a circulation concentration tank; and heating the co-precipitation filtrate stored in the circulation concentration tank to a predetermined temperature for recycling and performing N.sub.2 purging or bubbling, is provided.

A process for treating an ammonium fluorosulfate byproduct includes providing an ammonium fluorosulfate byproduct including primarily ammonium fluorosulfate and lesser amounts of fluorosulfonic acid and bis(fluorosulfonyl) imide, mixing the ammonium fluorosulfate byproduct with water, reacting the mixture of the ammonium fluorosulfate byproduct and the water at a hydrolysis reaction temperature to hydrolyze the ammonium fluorosulfate, the fluorosulfonic acid and the bis(fluorosulfonyl) imide to form ammonium bisulfate and aqueous hydrogen fluoride; and separating the ammonium bisulfate from the aqueous hydrogen fluoride.

A process for treating an ammonium fluorosulfate byproduct includes providing an ammonium fluorosulfate byproduct including primarily ammonium fluorosulfate and lesser amounts of fluorosulfonic acid and bis(fluorosulfonyl) imide, mixing the ammonium fluorosulfate byproduct with water, reacting the mixture of the ammonium fluorosulfate byproduct and the water at a hydrolysis reaction temperature to hydrolyze the ammonium fluorosulfate, the fluorosulfonic acid and the bis(fluorosulfonyl) imide to form ammonium bisulfate and aqueous hydrogen fluoride; and separating the ammonium bisulfate from the aqueous hydrogen fluoride.