The production method of the present disclosure includes heat-treating a material mixture containing a compound containing Y, a compound containing Gd, NH.sub.4α, Liβ, and Caγ.sub.2 in an inert gas atmosphere. The compound containing Y is at least one selected from the group consisting of Y.sub.2O.sub.3 and Yδ.sub.3, and the compound containing Gd is at least one selected from the group consisting of Gd.sub.2O.sub.3 and Gdε.sub.3. The material mixture contains at least one selected from the group consisting of Y.sub.2O.sub.3 and Gd.sub.2O.sub.3, and α, β, γ, δ, and ε are each independently at least one selected from the group consisting of F, Cl, Br, and I.

The production method of the present disclosure includes heat-treating a material mixture containing a compound containing Y, a compound containing Gd, NH.sub.4α, Liβ, and Caγ.sub.2 in an inert gas atmosphere. The compound containing Y is at least one selected from the group consisting of Y.sub.2O.sub.3 and Yδ.sub.3, and the compound containing Gd is at least one selected from the group consisting of Gd.sub.2O.sub.3 and Gdε.sub.3. The material mixture contains at least one selected from the group consisting of Y.sub.2O.sub.3 and Gd.sub.2O.sub.3, and α, β, γ, δ, and ε are each independently at least one selected from the group consisting of F, Cl, Br, and I.

A production method for producing a halide, the method includes a heat treatment step of heat-treating a mixed material containing (NH.sub.4).sub.aYα.sub.3+a, (NH.sub.4).sub.bSmβ.sub.3+b, Liγ, and Caδ.sub.2 in an inert gas atmosphere, wherein α, β, γ, and δ are each independently at least one selected from the group consisting of F, Cl, Br, and I, and the following three formulas: 0≤a≤3, 0≤b≤3, and 0<a+b≤6, are satisfied.

A production method for producing a halide, the method includes a heat treatment step of heat-treating a mixed material containing (NH.sub.4).sub.aYα.sub.3+a, (NH.sub.4).sub.bSmβ.sub.3+b, Liγ, and Caδ.sub.2 in an inert gas atmosphere, wherein α, β, γ, and δ are each independently at least one selected from the group consisting of F, Cl, Br, and I, and the following three formulas: 0≤a≤3, 0≤b≤3, and 0<a+b≤6, are satisfied.

A positive electrode material of the present disclosure includes: a material represented by the following composition formula (1); and a carbon material capable of occluding at least one selected from the group consisting of a simple substance of halogen and a halide, Li.sub.aM.sub.bX.sub.c . . . Formula (1) where a, b, and c are each a value greater than 0, M includes at least one selected from the group consisting of metal elements other than Li and metalloid elements, and X includes a halogen element.

The present invention provides a rare-earth halide scintillating material and application thereof. The rare-earth halide scintillating material has a chemical formula of RE.sub.aCe.sub.bX.sub.3, wherein RE is a rare-earth element La, Gd, Lu or Y, X is one or two of halogens Cl, Br and I, 0≤a≤1.1, 0.01≤b≤1.1, and 1.0001≤a+b≤1.2. By taking a +2 valent rare-earth halide having the same composition as a dopant to replace a heterogeneous alkaline earth metal halide in the prior art for doping, the rare-earth halide scintillating material is relatively short of a halogen ion. The apparent valence state of a rare-earth ion is between +2 and +3. The rare-earth halide scintillating material belongs to non-stoichiometric compounds, but still retains a crystal structure of an original stoichiometric compound, and has more excellent energy resolution and energy response linearity than the stoichiometric compound.

The present invention provides a rare-earth halide scintillating material and application thereof. The rare-earth halide scintillating material has a chemical formula of RE.sub.aCe.sub.bX.sub.3, wherein RE is a rare-earth element La, Gd, Lu or Y, X is one or two of halogens Cl, Br and I, 0≤a≤1.1, 0.01≤b≤1.1, and 1.0001≤a+b≤1.2. By taking a +2 valent rare-earth halide having the same composition as a dopant to replace a heterogeneous alkaline earth metal halide in the prior art for doping, the rare-earth halide scintillating material is relatively short of a halogen ion. The apparent valence state of a rare-earth ion is between +2 and +3. The rare-earth halide scintillating material belongs to non-stoichiometric compounds, but still retains a crystal structure of an original stoichiometric compound, and has more excellent energy resolution and energy response linearity than the stoichiometric compound.

The present invention relates to a rare earth halide scintillating material. The material has a general chemical formula La.sub.1-xCe.sub.xBr.sub.3+y, wherein 0.001x1, and 0.0001y0.1. The rare earth halide scintillating material involved in the present invention has excellent scintillation properties of high light output, high energy resolution, and fast decay.

The present invention relates to a rare earth halide scintillating material. The material has a general chemical formula La.sub.1-xCe.sub.xBr.sub.3+y, wherein 0.001x1, and 0.0001y0.1. The rare earth halide scintillating material involved in the present invention has excellent scintillation properties of high light output, high energy resolution, and fast decay.

The present application relates to a technical filed of energy sources and illumination, and discloses a rare earth oxide nanosheet composite modified by an organic ligand, a preparation method and an organic light-emitting diode (OLED) luminescent film. The rare earth oxide nanosheet composite modified by the organic ligand is obtained by adding the organic ligand in the rare earth nanosheet sol for ultrasonic coordination; and a mole ratio of the rare earth nanosheet sol to the organic ligand is 1:(3-9).