Patent classifications
C01F7/30
Alumina material
Provided is alumina material comprising alumina and zirconium, wherein in a radial distribution function obtained by Fourier-transforming an extended X-ray absorption fine structure (EXAFS) spectrum of a K absorption edge of the zirconium in the alumina material, the value of I.sub.B/I.sub.A is 0.5 or less where I.sub.A is a maximum intensity among the intensities of peaks present at 0.1 nm to 0.2 nm, and I.sub.B is a maximum intensity among the intensities of peaks present at 0.28 nm to 0.35 nm.
Methods for preparing high-purity boehmite and porous gamma-alumina nano-powder
Disclosed are methods for preparing high-purity boehmite and porous gamma-alumina nano-powder, comprising: adding aluminum isopropoxide into water and stirring the aluminum isopropoxide added water, then adding aluminum hydroxide generated by hydrolysis of high-purity aluminum powder into that stirred water, stirring that aluminum hydroxide added water to obtain a mixed system; carrying out hydrothermal reaction on the mixed system, performing centrifuging, washing, drying and crushing to the reacted mixed system, obtaining high-purity boehmite; calcining the high-purity boehmite to obtain porous gamma (γ)-alumina nano-powder. By strictly controlling the addition of isopropanolic aluminum and the temperature as well as the duration of the hydrothermal reaction, the product boehmite γ-AlOOH obtains good character in terms of crystalline structure, purity, morphology and dispersion; γ-Al.sub.2O.sub.3 obtained after calcining remains basically the same morphology as that of boehmite powder with good powder dispersion and no major changes.
Methods for preparing high-purity boehmite and porous gamma-alumina nano-powder
Disclosed are methods for preparing high-purity boehmite and porous gamma-alumina nano-powder, comprising: adding aluminum isopropoxide into water and stirring the aluminum isopropoxide added water, then adding aluminum hydroxide generated by hydrolysis of high-purity aluminum powder into that stirred water, stirring that aluminum hydroxide added water to obtain a mixed system; carrying out hydrothermal reaction on the mixed system, performing centrifuging, washing, drying and crushing to the reacted mixed system, obtaining high-purity boehmite; calcining the high-purity boehmite to obtain porous gamma (γ)-alumina nano-powder. By strictly controlling the addition of isopropanolic aluminum and the temperature as well as the duration of the hydrothermal reaction, the product boehmite γ-AlOOH obtains good character in terms of crystalline structure, purity, morphology and dispersion; γ-Al.sub.2O.sub.3 obtained after calcining remains basically the same morphology as that of boehmite powder with good powder dispersion and no major changes.
PLATE-LIKE ALUMINA PARTICLE AND METHOD FOR MANUFACTURING PLATE-LIKE ALUMINA PARTICLE
A plate-like alumina particle, in which a ratio I (006)/I (113) of a peak intensity 1(006) at 20=41.6±0.3 degrees which corresponds to a (006) face to a peak intensity I(113) at 20=43.3±0.3 degrees which corresponds to a (113) face of diffraction peaks obtained by X-ray diffraction measurement using a Cu—Kα ray, is 0.2 or more. A method for manufacturing the plate-like alumina particle including mixing an aluminum compound including an aluminum element, a molybdenum compound including a molybdenum element, and a shape-controlling agent to produce a mixture and firing the mixture.
PLATE-LIKE ALUMINA PARTICLE AND METHOD FOR MANUFACTURING PLATE-LIKE ALUMINA PARTICLE
A plate-like alumina particle, in which a ratio I (006)/I (113) of a peak intensity 1(006) at 20=41.6±0.3 degrees which corresponds to a (006) face to a peak intensity I(113) at 20=43.3±0.3 degrees which corresponds to a (113) face of diffraction peaks obtained by X-ray diffraction measurement using a Cu—Kα ray, is 0.2 or more. A method for manufacturing the plate-like alumina particle including mixing an aluminum compound including an aluminum element, a molybdenum compound including a molybdenum element, and a shape-controlling agent to produce a mixture and firing the mixture.
Aluminum oxide article
An aluminum oxide article containing at least aluminum atoms and oxygen atoms is described. When observed under a transmission electron microscope, a cross section of the aluminum oxide article contains crystallized parts, in which a crystal lattice image is recognizable, and a non-crystallized part, in which no crystal lattice image is recognizable, and has an island-and-sea structure consisting of isolated parts containing the crystallized parts and the continuous non-crystallized part. The isolated parts correspond to island parts in the island-and-sea structure, the continuous non-crystallized part corresponds to a sea part, and a plurality of the island parts are uniformly distributed in the sea part. An aluminum oxide for improving the battery performance of a lithium ion secondary battery, the scratch resistance and hardness of a cured film, and the gas barrier properties of a gas barrier film is provided.
Aluminum oxide article
An aluminum oxide article containing at least aluminum atoms and oxygen atoms is described. When observed under a transmission electron microscope, a cross section of the aluminum oxide article contains crystallized parts, in which a crystal lattice image is recognizable, and a non-crystallized part, in which no crystal lattice image is recognizable, and has an island-and-sea structure consisting of isolated parts containing the crystallized parts and the continuous non-crystallized part. The isolated parts correspond to island parts in the island-and-sea structure, the continuous non-crystallized part corresponds to a sea part, and a plurality of the island parts are uniformly distributed in the sea part. An aluminum oxide for improving the battery performance of a lithium ion secondary battery, the scratch resistance and hardness of a cured film, and the gas barrier properties of a gas barrier film is provided.
ALUMINA PARTICLES, RESIN COMPOSITION, MOLDED BODY, AND METHOD FOR PRODUCING ALUMINA PARTICLES
Provided are alumina particles containing molybdenum and with their shape controlled. The alumina particles contain phosphorus and molybdenum. The alumina particles are preferably plate-like or card house-like. The phosphorus is preferably unevenly distributed in surface layers of the alumina particles. Also provided are a resin composition containing the alumina particles and a resin, a molded body made by molding the resin composition, and a method for producing the alumina particle including a step of firing the aluminum compound in the presence of a molybdenum compound and a phosphorous compound.
COMPOSITE PARTICLE AND METHOD OF PRODUCING COMPOSITE PARTICLE
The composite particle of the present invention includes an alumina particle having a card-house structure which is formed of three or more pieces of plate-like alumina and in which the pieces of plate-like alumina are fixed to each other; and an inorganic coating part provided on a surface of the plate-like alumina.
COMPOSITE PARTICLE AND METHOD OF PRODUCING COMPOSITE PARTICLE
The composite particle of the present invention includes an alumina particle having a card-house structure which is formed of three or more pieces of plate-like alumina and in which the pieces of plate-like alumina are fixed to each other; and an inorganic coating part provided on a surface of the plate-like alumina.