Methods are provided for improved recovery of organic salts, such as ionic liquids or organic salts comprising quaternary organic cations, in an industrial alumina production process, such as the Bayer process. These methods include (i) using an organic salt for the removal of impurities in an industrial process for the production of alumina; (ii) subjecting the spent organic salt to a recycling operation that generates at least one exit stream having a measureable amount of the organic salt {e.g., by entrainment or by solubility of the organic salt in the exit stream); (iii) collecting and treating the exit stream (s) with an inorganic salt, in an amount effective to induce phase separation; and (iv) recovering the organic phase containing the recovered organic salt. These methods and compositions allow alumina refinery plants to use organic salts for removal of industrial process streams in an economical manner, due to the efficient recovery of the organic salt.

Methods are provided for improved recovery of organic salts, such as ionic liquids or organic salts comprising quaternary organic cations, in an industrial alumina production process, such as the Bayer process. These methods include (i) using an organic salt for the removal of impurities in an industrial process for the production of alumina; (ii) subjecting the spent organic salt to a recycling operation that generates at least one exit stream having a measureable amount of the organic salt {e.g., by entrainment or by solubility of the organic salt in the exit stream); (iii) collecting and treating the exit stream (s) with an inorganic salt, in an amount effective to induce phase separation; and (iv) recovering the organic phase containing the recovered organic salt. These methods and compositions allow alumina refinery plants to use organic salts for removal of industrial process streams in an economical manner, due to the efficient recovery of the organic salt.

A method for isolating a humic substance from alumina process liquor is provided herein. Separate from or within the method, bauxite is processed to form the alumina process liquor. The method includes providing a diallyldimethylammonium chloride-containing polymer. The method further includes providing an amine-containing polymer. The method further includes combining the diallyl dimethyl ammonium chloride, the amine-containing polymer, and the alumina process liquor, to isolate the humic substance from the alumina process liquor.

A method for isolating a humic substance from alumina process liquor is provided herein. Separate from or within the method, bauxite is processed to form the alumina process liquor. The method includes providing a diallyldimethylammonium chloride-containing polymer. The method further includes providing an amine-containing polymer. The method further includes combining the diallyl dimethyl ammonium chloride, the amine-containing polymer, and the alumina process liquor, to isolate the humic substance from the alumina process liquor.

A method for controlling the concentration of impurities in Bayer liquors, the method comprising the steps of adding an oxide and/or a hydroxide of a metal other than aluminium to a Bayer liquor with a desired TA forming a layered double hydroxide; and incorporating at least one impurity in the layered double hydroxide, wherein the impurities are selected from the group comprising chloride, fluoride, sulfate and TOC.

A Bayer process increases oxalate removal in the red side of the Bayer process and at least substantially minimises, for example by at least substantially suppressing, precipitation of oxalates in the white side of the Bayer process.

A method for isolating a humic substance from alumina process liquor is provided herein. Separate from or within the method, bauxite is processed to form the alumina process liquor. The method includes providing a diallyldimethylammonium chloride-containing polymer. The method further includes providing an amine-containing polymer. The method further includes combining the diallyl dimethyl ammonium chloride, the amine-containing polymer, and the alumina process liquor, to isolate the humic substance from the alumina process liquor.

A Bayer process increases oxalate removal in the red side of the Bayer process and at least substantially minimises, for example by at least substantially suppressing, precipitation of oxalates in the white side of the Bayer process.

A Bayer process increases oxalate removal in the red side of the Bayer process and at least substantially minimises, for example by at least substantially suppressing, precipitation of oxalates in the white side of the Bayer process.

A Bayer process increases oxalate removal in the red side of the Bayer process and at least substantially minimises, for example by at least substantially suppressing, precipitation of oxalates in the white side of the Bayer process.