C01G17/006

Solid electrolyte and preparation method thereof, and electrochemical device and electronic device comprising solid electrolyte

Embodiments of the present application relate to a solid electrolyte and a preparation method thereof, and an electrochemical device and an electronic device comprising the solid electrolyte. The solid electrolyte comprises a lithium-containing transition metal sulfide being represented by the chemical formula of Li.sub.2−2a+bCd.sub.1+aM.sub.cGe.sub.1−dS.sub.4, where M is selected from the group consisting of Al, Ga, In, Si, Sn and a combination thereof, wherein 0<a≤0.25, 0≤b≤0.2, 0≤c≤0.2, and 0≤d≤0.2. The embodiments of the present application effectively improve the shortcomings of poor chemical stability of the conventional thiophosphate solid electrolyte in an atmospheric environment by providing the above solid electrolyte having a thio-LISICON structure and containing no phosphorus (P), so that the solid electrolyte has both good chemical stability and high ionic conductivity, thereby reducing the processing environment requirements and manufacturing cost of the solid electrolyte.

Tetrakis(trichlorosilyl)germane, process for the preparation thereof and use thereof

A novel process provides for the preparation of the chlorinated, uncharged substance tetrakis(trichlorosilyl)germane, and for the use thereof.

Gallium-68 generators and methods for making such generators
11195633 · 2021-12-07 · ·

Gallium-68 generators that are capable of producing gallium-68 from a germanium-68 source material are disclosed. The source material may be a matrix material (e.g., zeolite) in which germanium-68 is isomorphously substituted for central atoms in tetrahedra within the matrix material. Methods for forming gallium-68 generators are also disclosed.

Lithium mixed metal sulfide with high ionic conductivity

The present invention relates to a compound represented by the general formula Li.sub.2+2xM.sub.1−xZS.sub.4, wherein 0.3≤x≤0.9; wherein M is one or more elements selected from the group consisting of Pb, Mg, Ca, Ge and Sn; and wherein Z is one or more elements selected from the group consisting of Ge, Si, Sn and Al. The present invention also relates to a method for preparing the material of the present invention, comprising the steps of: (a) providing a mixture of lithium sulfide Li.sub.2S, sulfides MS and ZS.sub.2, in a stoichiometric ratio ensuring Li.sub.2+2xM.sub.1−xZS.sub.4 to be obtained, wherein M, Z and x are as defined above; (b) pelletizing the mixture prepared in step (a); (c) heating at a maximum plateau temperature. In still another aspect, the present invention relates to a use of the compound of the present invention as a solid electrolyte, in particular in an all solid-state lithium battery.

Oriented apatite type oxide ion conductor and method for producing same

An oriented apatite-type oxide ion conductor includes a composite oxide expressed as A.sub.9.33+x[T.sub.6.00−yM.sub.y]O.sub.26.0+z, where A represents one or two or more elements selected from the group consisting of La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Be, Mg, Ca, Sr, and Ba, T represents an element including Si or Ge or both, and M represents one or two or more elements selected from the group consisting of B, Ge, Zn, Sn, W, and Mo, and where x is from −1.00 to 1.00, y is from 0.40 to less than 1.00, and z is from −3.00 to 2.00.

INORGANIC SULFIDE SOLID ELECTROLYTE HAVING HIGH AIR STABILITY, AND PREPARATION METHOD AND USE THEREOF

An inorganic sulfide solid electrolyte having high air stability, and a preparation method and use thereof In the invention, some or all of P elements in a sulfide electrolyte are replaced with Sb elements, thereby providing an electrolyte having high air stability and ion mobility and applicable to an all-solid lithium secondary battery. The resulting inorganic sulfide electrolyte comprises the following materials: Li.sub.10M(P.sub.1-aSb.sub.a).sub.2S.sub.12, Li.sub.6(P.sub.1-aSb.sub.a)S.sub.5X and Li.sub.3(P.sub.1-aSb.sub.a)S.sub.4, where M is one or more of Ge, Si or Sn, X is one or more of F, Cl, Br or I, and 0.01≤a≤1.

Tris(trichlorosilyl)dichlorogallylgermane, process for the preparation thereof and use thereof

A process can be used for the preparation of tris(trichlorosilyl)dichlorogallylgermane, which is a chlorinated, uncharged substance.

Tetrakis(trichlorosilyl)germane, process for the preparation thereof and use thereof

A novel process provides for the preparation of the chlorinated, uncharged substance tetrakis(trichlorosilyl)germane, and for the use thereof.

PROCESS FOR MAKING SYNTHETIC MINERALS

Methods for making a synthetic mineral and methods for making synthetic mineral precursors and the products of said methods.

Light-absorbing material, method for producing the same, and solar cell including the same

A light-absorbing material includes a compound, wherein the compound has a perovskite crystal structure represented by the formula AMX.sub.3 where a Cs.sup.+ ion is located at an A-site, a Ge.sup.2+ ion is located at an M-site, and I.sup.− ions are located at X-sites, and at least a part of the compound has an orthorhombic perovskite crystal structure. An X-ray diffraction pattern of the compound measured using Cu Kα radiation may have a first peak at a diffraction angle (2θ) of 25.4° or more and 25.8° or less and a second peak at a diffraction angle (2θ) of 24.9° or more and 25.3° or less, and an intensity of the first peak may be 30% or more of an intensity of the second peak.