A device including an LED light source optically coupled to a phosphor selected from [Y,Gd,Tb,La,Sm,Pr,Lu].sub.3[Al,Ga].sub.5−aO.sub.12−3/2a:Ce.sup.3+ (wherein 0<a<0.5), beta-SiAlON:Eu.sup.2+, [Sr,Ca,Ba][Al,Ga,In].sub.2S.sub.4:Eu.sup.2+, alpha-SiAlON doped with Eu.sup.2+ and/or Ce.sup.3+, Ca.sub.1−h−rCe.sub.hEu.sub.rAl.sub.1−h[Mg,Zn].sub.hSiN.sub.3, (where 0<h<0.2, 0<r<0.2), Sr(LiAl.sub.3N.sub.4):Eu.sup.2+, [Ca,Sr]S:Eu.sup.2+ or Ce.sup.3+, [Ba,Sr,Ca].sub.bSi.sub.gN.sub.m:Eu.sup.2+ (wherein 2b+4g=3m), quantum dot materials, and combinations thereof; and a green-emitting U.sup.6+-doped phosphor having a composition selected from the group consisting of U.sup.6+-doped phosphate-vanadate phosphors, U.sup.6+-doped halide phosphors, U.sup.6+-doped oxyhalide phosphors, U.sup.6+-doped silicate-germanate phosphors, U.sup.6+-doped alkali earth oxide phosphors, and combinations thereof, is presented.

The invention discloses use of a uranium-containing compound as a scintillator. The uranium-containing compound is a uranium-containing organic-inorganic hybrid compound or a uranium-containing inorganic compound. The uranium-containing organic-inorganic hybrid compound is a uranium-containing organic carboxylate or a uranium-containing organophosphate. The uranium-containing inorganic compound is a uranium-containing non-metallate, a uranium-containing metal salt, or a uranium-containing halide. The invention discloses the uranium-containing organic-inorganic compound or the uranium-containing inorganic compound having intrinsic scintillating ability, and provides a new concept and method for the development of (organic-inorganic, inorganic) scintillators of various chemical compositions and configurations with the uranium element.

A device including an LED light source optically coupled to a green-emitting U.sup.6+-doped phosphor having a composition selected from the group consisting of U.sup.6+-doped phosphate-vanadate phosphors, U.sup.6+-doped halide phosphors, U.sup.6+-doped oxyhalide phosphors, U.sup.6+-doped silicate-germanate phosphors, U.sup.6+-doped alkali earth oxide phosphors, and combinations thereof, is presented. The U.sup.6+-doped phosphate-vanadate phosphors are selected from the group consisting of compositions of formulas (A1)-(A12). The U.sup.6+-doped halide phosphors are selected from the group consisting of compositions for formulas (B1)-(B3). The U.sup.6+-doped oxyhalide phosphors are selected from the group consisting of compositions of formulas (C1)-(C5). The U.sup.6+-doped silicate-germanate phosphors are selected from the group consisting of compositions of formulas (D1)-(D11). The U.sup.6+-doped alkali earth oxide phosphors are selected from the group consisting of formulas (E1)-(E11).

A device including an LED light source optically coupled to a green-emitting U.sup.6+-doped phosphor having a composition selected from the group consisting of U.sup.6+-doped phosphate-vanadate phosphors, U.sup.6+-doped halide phosphors, U.sup.6+-doped oxyhalide phosphors, U.sup.6+-doped silicate-germanate phosphors, U.sup.6+-doped alkali earth oxide phosphors, and combinations thereof, is presented. The U.sup.6+-doped phosphate-vanadate phosphors are selected from the group consisting of compositions of formulas (A1)-(A12). The U.sup.6+-doped halide phosphors are selected from the group consisting of compositions for formulas (B1)-(B3). The U.sup.6+-doped oxyhalide phosphors are selected from the group consisting of compositions of formulas (C1)-(C5). The U.sup.6+-doped silicate-germanate phosphors are selected from the group consisting of compositions of formulas (D1)-(D11). The U.sup.6+-doped alkali earth oxide phosphors are selected from the group consisting of formulas (E1)-(E11).

The invention discloses use of a uranium-containing compound as a scintillator. The uranium-containing compound is a uranium-containing organic-inorganic hybrid compound or a uranium-containing inorganic compound. The uranium-containing organic-inorganic hybrid compound is a uranium-containing organic carboxylate or a uranium-containing organophosphate. The uranium-containing inorganic compound is a uranium-containing non-metallate, a uranium-containing metal salt, or a uranium-containing halide. The invention discloses the uranium-containing organic-inorganic compound or the uranium-containing inorganic compound having intrinsic scintillating ability, and provides a new concept and method for the development of (organic-inorganic, inorganic) scintillators of various chemical compositions and configurations with the uranium element.

A device including an LED light source optically coupled to a green-emitting U.sup.6+-doped phosphor having a composition selected from the group consisting of U.sup.6+-doped phosphate-vanadate phosphors, U.sup.6+-doped halide phosphors, U.sup.6+-doped oxyhalide phosphors, U.sup.6+-doped silicate-germanate phosphors, U.sup.6+-doped alkali earth oxide phosphors, and combinations thereof, is presented. The U.sup.6+-doped phosphate-vanadate phosphors are selected from the group consisting of compositions of formulas (A1)-(A12). The U.sup.6+-doped halide phosphors are selected from the group consisting of compositions for formulas (B1)-(B3). The U.sup.6+-doped oxyhalide phosphors are selected from the group consisting of compositions of formulas (C1)-(C5). The U.sup.6+-doped silicate-germanate phosphors are selected from the group consisting of compositions of formulas (D1)-(D11). The U.sup.6+-doped alkali earth oxide phosphors are selected from the group consisting of formulas (E1)-(E11).

A method of synthesizing rubidium uranium fluoride crystals. The method includes combining uranium-based feedstock with a mineralizer solution that includes a rubidium fluoride. The feedstock and mineralizer solution are pressurized and a thermal gradient applied thereto such that a first portion of the feedstock and the mineralizer solution is heated to a temperature that is greater than a temperature of a second portion of the feedstock and the mineralizer solution. Uranium nutrient enters the mineralizer solution from the feedstock in the first portion and uranium nutrient precipitates to spontaneously form crystals in the second portion.

A method of synthesizing uranium dioxide crystals. The method of synthesizing includes combining a uranium-based feedstock with a mineralizer solution. The uranium-based feedstock is selected from uranium dioxide, uranium tetrafluoride, uranium tetrachloride, triuranium octoxide, and uranium trioxide. The feedstock and mineralizer solution are pressurized, and then a thermal gradient is applied thereto such that a first portion of the feedstock and the mineralizer solution is heated to a temperature that is greater than a temperature of a second portion of the feedstock and the mineralizer solution. The uranium nutrient enters the mineralizer solution from the feedstock in the first portion and uranium nutrient precipitates to spontaneously form crystals in the second portion.

A method of synthesizing alkali uranium fluorophosphate crystals. The method includes combining a uranium-based feedstock with a mineralizer solution. The mineralizer solution includes an alkali nutrient, a phosphate, and a fluoride. The feedstock and mineralizer solution are pressurized and a thermal gradient applied thereto such that a first portion of the feedstock and the mineralizer solution is heated to a temperature that is greater than a temperature of a second portion of the feedstock and the mineralizer solution. Uranium nutrient enters the mineralizer solution from the feedstock in the first portion and uranium nutrient precipitates to spontaneously form crystals in the second portion.

A method of manufacturing particles of UO.sub.2 for a porous matrix of a target for use in the manufacture of .sup.99Mo, comprising: infiltrating a solution of uranyl nitrate into a polymer template (62); either (i) introducing an alkali chemical to the uranyl nitrate infiltrated polymer template (64), causing precipitation of uranium oxide/hydroxide, and converting the uranium oxide/hydroxide to U.sub.3O.sub.8 (68) and concurrently removing the polymer template (70), by heating the infiltrated polymer template; or (ii) converting the uranyl nitrate to U.sub.3O.sub.8 (66) and concurrently removing the polymer template (74), by heating the infiltrated polymer template; and reducing the U.sub.3O.sub.8 to UO.sub.2 via heating in a reducing atmosphere (72).