The present disclosure provides methods, electrodes, and systems for electrochemical oxidation of polyfluoroalkyl and perfluroalkyl (PFAS) contaminants using Magnéli phase titanium suboxide ceramic electrodes/membranes. Magneli phase titanium suboxide ceramic electrodes/membranes can be porous and can be included in reactive electrochemical membrane filtration systems for filtration, concentration, and oxidation of PFASs and other contaminants.

A method of producing a porous carbon composite fibrous mats formed of a network of carbon fibers incorporated with porous carbon particles. The method includes electrospinning a polymer solution to form a porous layer of polymeric fibers and the polymeric fibers are doped with a precursor of conductive metal particles, wherein the polymer solution includes a polymer and the precursor of the conductive metal particles, electrospraying a metal organic framework suspension onto the porous layer of polymeric fibers, wherein the metal organic framework suspension includes metal organic framework particles, repeating the electrospinning and electrospraying in an alternating manner to form a porous network of polymeric fibers incorporated with the metal organic framework particles, and heating the porous network of polymeric fibers incorporated with the metal organic framework particles to form the porous carbon composite fibrous mats. The porous carbon composite fibrous mats and its applications thereof are also disclosed herein.

A device for removing ions from a solution. The device includes first and second intercalation hosts, an anion exchange membrane, a first compartment extending between the first intercalation host and the anion exchange membrane, and a second compartment extending between the second intercalation host and the anion exchange membrane. The first and/or second intercalation hosts include a mixture of first and second intercalation materials. The first and/or second intercalation hosts may include layers (e.g., alternating layers) of the first and second intercalation materials. The first and second intercalation materials are different.

An electrode for use in a device configured to remove ions from a solution. The electrode includes an intercalation material including a binary transition metal Prussian blue analogue compound, a ternary transition metal Prussian blue analogue compound, or a combination thereof. The binary compound may have a general formula: A.sub.xB.sub.yC.sub.z[Fe(CN).sub.6], where A=Li, Na, or K; B=Mn, Fe, Ni, Cu, or Zn; C=Mn, Fe, Ni, Cu, or Zn; 0≤x≤1; 0≤y≤1; and 0≤z≤1. The ternary compound may have the general formula: A.sub.xB.sub.yC.sub.zD.sub.w[Fe(CN).sub.6], where A=Li, Na, or K; B=Mn, Fe, Ni, Cu, or Zn; C=Mn, Fe, Ni, Cu, or Zn; D=Mn, Fe, Ni, Cu, or Zn; 0≤x≤1; 0≤y≤1; 0≤z≤1; 0≤w≤1.

Bismuth-based, chloride-storage electrodes and rechargeable electrochemical cells incorporating the chloride-storage electrodes are provided. Also provided are methods for making the electrodes and methods for using the electrochemical cells to remove chloride ions from a sample. The chloride-storage electrodes, which are composed of bismuth metal, can store chloride ions in their bulk by forming BiOCl via an oxidation reaction with bismuth in the presence of an oxygen source.

The present invention is directed to an electrochemical device for at least partially removing or reducing a target ionic species from an aqueous solution using faradic immobilization, the electrochemical device including at least one first electrode and at least one second electrode with different void fraction and surface area properties, due to differences in void fraction (also referred to as void ratio) of the at least one first and the at least one second electrode, water flows through an electrode with a high porosity, while the aqueous solution does not flow through an electrode with a low porosity. The asymmetry of the electrodes provides a desired voltage distribution across the device, which equates to a different voltage at each electrode, to control the speciation of the target ionic species at the anode and the cathode.

An electrical water filter device includes a plurality of porous electrodes and one or more porous separators. Each of the one or more porous separators is interposed between two adjacent porous electrodes. A respective porous electrode includes a connection portion extending outside an edge of a porous separators next to the respective porous electrode.

A boron doped diamond electrode and its preparation method and application, the electrode is deposited with a boron or nitrogen doped diamond layer or a boron or nitrogen doped diamond layer composite layer on the surface of the electrode substrate, or after a transition layer is disposed on the surface of the substrate, a boron or nitrogen doped diamond layer or a composite layer of boron or nitrogen doped diamond layer is disposed on the surface of transition layer. The preparation method is depositing or plating a boron or nitrogen doped diamond layer on the surface of the electrode substrate, or providing a transition layer on the surface of the electrode substrate, and then depositing or plating a boron or nitrogen doped diamond layer or a composite layer of boron or nitrogen doped diamond layer on the surface of the transition layer.

An electrochemical cell may include: an anode; a porous anodic current collector; a cathode; a porous cathodic current collector; and an alkali metal-conducting separator that separates the anode from the cathode and is disposed surrounding the anodic current collector. The cathode may include seawater. A battery module may include a plurality of the electrochemical cells, and a battery may include a plurality of the battery modules.

A water-processing electrochemical reactor that comprises a cylindrical inner anode (73), an outer tubular cathode (74), an intermediate chamber between the anode (73) and the cathode (74) and being crossed by the water, an outer shell (77) surrounding the cathode (74), a water inlet (71) and a water outlet (78), and a gas inlet (80) and gas outlet (79) connected to the outer shell (77) and to the gas chamber. The cathode surrounds the inner anode (73) and is porous to gas. A gas chamber is defined between the cathode (74) and the outer shell (77). The gas chamber contains a gas comprising oxygen and is at an overpressure that forces the gas through the porous cathode (74).