Methods and systems directed to recovery of lithium (e.g., lithium salts) from liquid streams are provided. In some embodiments, methods relate to obtaining lithium (e.g., as a solid lithium salt) by removing at least a portion of liquid from a feed stream to form a concentrated stream with respect to solubilized lithium cations. Liquid removal may include transporting at least a portion of the feed stream to an osmotic unit and/or a humidifier. Some methods include removing impurities (e.g., non-lithium cations) from the concentrated stream (e.g., via precipitation and/or crystallization). In some embodiments, solutions containing solubilized lithium cations and anions are electrochemically-treated such that first solubilized anions are replaced with second, different anions. In some embodiments, solid lithium salt containing at least a portion of the lithium cations and the second anions is obtained (e.g., via precipitation and/or crystallization following concentration of the electrochemically-treated solution in a humidifier).

Novel iron-phosphate nanoparticles have been synthesized here. These are less than 12 nanometers in dimension. They are deemed useful for remediation of heavy metals and radionuclides and can be applied to insitu remediation of contaminated soils and contaminated waters.

The present subject matter relates to a composition for in-situ remediation of soil and aquifer comprising of a water miscible oil; a solvent (for dissolving the vegetable oil to form a solution); and a catalyst (selected from enzymes biocatalysts, particularly lipases, alkaline compounds, heat or combinations thereof). The present subject matter provides a process for the preparation of the composition and application of the same for surface remediation. Further, the present subject matter provides an in-situ alcoholysis remediation method to reduce contaminant concentrations in aquifer and soil by enabling the generation of both soluble and slowly fermenting electron donors required for the anaerobic remediation of organohalide compounds contaminating soils and groundwater. The method of remediation includes mixing an engineered water-soluble oil or water miscible oil with a solvent and adding a catalyst to groundwater to promote the formation of fatty acid alkyl esters, carboxylic acid salts and glycerol.

In one aspect, composite particles are described herein. A composite particle comprises a substrate, composite metallic or metal oxide nanoparticles supported by the substrate and an amphiphilic or hydrophilic component associated with the substrate, wherein the composite metallic or metal oxide nanoparticles comprise iron and at least one additional transition metal.

Methods of passively sampling PFAS in the environment, PFAS sorbents, apparatus and systems (apparatus plus conditions) for sampling groundwater, porewater, and surface water are described.

A system for decomposing a waste material in an unlined landfill including a landfill site having at least one waste disposal zone for receiving the waste material. The system also includes a remediation system configured for extracting a mixture of leachate and groundwater from groundwater within or adjacent to the landfill site and feeding the mixture into the at least one waste disposal zone along with air and other nutrients to enhance a rate of decay of the waste material within the at least one waste disposal zone.

A method for reducing nitrates, nitrites, and/or hydroxylamine in water using a homogeneous reduced copper tetra-substituted fluorinated pinacolate ligand catalyst complex. The method includes dissolving a copper(II) tetra-substituted fluorinated pinacolate ligand pre-catalyst complex in water having an excess amount of nitrates, nitrites, and/or hydroxylamine therein. The dissolved copper(II) tetra-substituted fluorinated pinacolate ligand pre-catalyst complex in the water is subjected to electrochemical reduction to form a homogeneous reduced copper tetra-substituted fluorinated pinacolate ligand catalyst complex. The homogeneous reduced copper tetra-substituted fluorinated pinacolate ligand catalyst complex reduces the nitrates, nitrites, and/or hydroxylamine in the water to compounds with nitrogen in a lower oxidation state with the homogeneous reduced copper tetra-substituted fluorinated pinacolate ligand catalyst complex.

Highly mesoporous activated carbon products are disclosed with mesoporosities characterized by mesopore volumes of 0.7 to 1.0 cubic centimeters per gram or greater. Also disclosed are activated carbon products characterized by a Molasses Number of about 500 to 1000 or greater. Also disclosed are activated carbon products characterized by a Tannin Value of about 100 to 35 or less. The activated carbon products may be further characterized by total pore volumes of at least 0.85 cubic centimeters per gram and BET surface areas of at least about 800 square meters per gram. The activated carbon product may be derived from a renewable feedstock.

A method for deep treatment of household waste leachate by a biochemical process is provided, including: arranging one anoxic tank and two aerobic tanks in series; introducing the household waste leachate into the primary anoxic reactor, and diluting the household waste leachate to an concentration acceptable to microorganisms; introducing the diluted household waste leachate into the primary aerobic reactor, and subjecting the diluted household waste leachate to an pre-nitrification reaction to obtain a reactant; introducing the reactant into the secondary aerobic reactor, and subjecting the reactant to a main nitrification reaction to convert ammonia nitrogen into nitrate nitrogen and nitrite nitrogen by nitrification of nitrobacteria; refluxing the nitrification liquid to the primary anoxic reactor, converting the nitrate nitrogen and nitrite nitrogen into nitrogen gas by denitrobacteria in the primary anoxic reactor, and discharging the nitrogen gas into atmosphere, thereby finishing an denitrification process.

The present application relates to a novel method for reductive degradation of perfluoroalkyl-containing compounds, such as perfluoroalkyl sulfonates, by activated carbon (AC) supported zero valent iron-nickle nanoparticles (nNi.sup.0Fe.sup.0).