A radiation-resistant laser optical fiber preform core rod at least includes one type of activated ion (Yb.sup.3+, Er.sup.3+) and one or more types of co-doped ion (Al.sup.3+, P.sup.5+, Ge.sup.4+, Ce.sup.3+, F.sup.−), and —OD group of 16-118 ppm. Irradiation resistance of core rod glass can be effectively improved by sequentially performing pre-treatments, i.e. deuterium loading, pre-irradiation and thermal annealing on a preform core rod. Electron paramagnetic resonance test shows that, under the same radiation condition, the radiation induced color center concentration in a preform core rod treated by the method above is lower than in an untreated core rod by one or more orders of magnitude. The obtained core rod can be used for preparing a radiation-resistant rare earth-doped silica fiber, and has the advantages of high laser slope efficiency, low background loss, being able to be used stably in a vacuum environment for a long time, for example.

A manufacturing method of a porous glass base material for optical fiber includes: controlling a flow rate of a raw material liquid of an organic siloxane by a liquid mass flow controller; introducing raw material liquid to a raw material liquid nozzle of a vaporizer by a raw material liquid pipe; ejecting raw material liquid into the vaporizer; mixing raw material liquid and carrier gas to vaporize raw material liquid to form mixed gas; supplying mixed gas to a burner; combusting mixed gas together with a combustible gas and a combustion supporting gas in the burner to produce SiO.sub.2 particles; depositing SiO.sub.2 particles on a starting core base material to form the porous glass base material; and closing an open/close valve on a flow path of the raw material liquid pipe to stop supply of raw material liquid, while continuing to supply carrier gas, combustible gas, and combustion supporting gas.

A manufacturing method of a porous glass base material for optical fiber includes: controlling a flow rate of a raw material liquid of an organic siloxane by a liquid mass flow controller; introducing raw material liquid to a raw material liquid nozzle of a vaporizer by a raw material liquid pipe; ejecting raw material liquid into the vaporizer; mixing raw material liquid and carrier gas to vaporize raw material liquid to form mixed gas; supplying mixed gas to a burner; combusting mixed gas together with a combustible gas and a combustion supporting gas in the burner to produce SiO.sub.2 particles; depositing SiO.sub.2 particles on a starting core base material to form the porous glass base material; and closing an open/close valve on a flow path of the raw material liquid pipe to stop supply of raw material liquid, while continuing to supply carrier gas, combustible gas, and combustion supporting gas.

A manufacturing apparatus of a porous glass base material for optical fiber includes: a liquid mass flow controller for controlling a flow rate of a raw material liquid of an organic siloxane; a vaporizer for mixing the raw material liquid and a carrier gas to vaporize the raw material liquid to form a mixed gas in which a raw material gas and the carrier gas are mixed; a raw material liquid nozzle for ejecting the raw material liquid into the vaporizer; a carrier gas supply pipe for supplying the carrier gas into the vaporizer; a raw material liquid pipe for introducing the raw material liquid into the raw material liquid nozzle; a burner for combusting the mixed gas together with a combustible gas and a combustion supporting gas to produce SiO.sub.2 fine particles; a mixed gas pipe; an open/close valve; and a purge gas supply pipe.

A manufacturing apparatus of a porous glass base material for optical fiber includes: a liquid mass flow controller for controlling a flow rate of a raw material liquid of an organic siloxane; a vaporizer for mixing the raw material liquid and a carrier gas to vaporize the raw material liquid to form a mixed gas in which a raw material gas and the carrier gas are mixed; a raw material liquid nozzle for ejecting the raw material liquid into the vaporizer; a carrier gas supply pipe for supplying the carrier gas into the vaporizer; a raw material liquid pipe for introducing the raw material liquid into the raw material liquid nozzle; a burner for combusting the mixed gas together with a combustible gas and a combustion supporting gas to produce SiO.sub.2 fine particles; a mixed gas pipe; an open/close valve; and a purge gas supply pipe.

The invention discloses porous, bioactive glass and glass ceramic morsels or pellets to be used as tissue graft substitute materials and processes for obtaining the same wherein the bioactive glass and glass ceramic morsels or pellets are made up of natural agents like phosphate, calcium, sodium and other elements which are not alien to the human or animal body. The said preparation process encompasses various steps like quenching sintering, foaming, and sol-gel casting which render the glass morsels or pellets unique bioactivity and enhanced porosity which may facilitate tissue repair and augmentation during tissue graft replacement.

The invention discloses porous, bioactive glass and glass ceramic morsels or pellets to be used as tissue graft substitute materials and processes for obtaining the same wherein the bioactive glass and glass ceramic morsels or pellets are made up of natural agents like phosphate, calcium, sodium and other elements which are not alien to the human or animal body. The said preparation process encompasses various steps like quenching sintering, foaming, and sol-gel casting which render the glass morsels or pellets unique bioactivity and enhanced porosity which may facilitate tissue repair and augmentation during tissue graft replacement.

A porous glass base material manufacturing apparatus for an optical fiber includes: a liquid mass flow controller for controlling a flow rate of raw material liquid of an organic siloxane; a vaporizer for mixing raw material liquid and carrier gas to vaporize raw material liquid to form mixed gas; a raw material liquid nozzle for ejecting raw material liquid into the vaporizer; a carrier gas supply pipe for supplying carrier gas into the vaporizer; a raw material liquid pipe for introducing raw material liquid into the nozzle; a burner for combusting mixed gas with combustible gas and combustion supporting gas to produce SiO.sub.2 particles; a mixed gas pipe for supplying mixed gas to the burner; an open/close valve on a flow path of the raw material liquid pipe; and a purge gas supply pipe that joins the raw material liquid pipe between the valve and the raw material liquid nozzle.

A porous glass base material manufacturing apparatus for an optical fiber includes: a liquid mass flow controller for controlling a flow rate of raw material liquid of an organic siloxane; a vaporizer for mixing raw material liquid and carrier gas to vaporize raw material liquid to form mixed gas; a raw material liquid nozzle for ejecting raw material liquid into the vaporizer; a carrier gas supply pipe for supplying carrier gas into the vaporizer; a raw material liquid pipe for introducing raw material liquid into the nozzle; a burner for combusting mixed gas with combustible gas and combustion supporting gas to produce SiO.sub.2 particles; a mixed gas pipe for supplying mixed gas to the burner; an open/close valve on a flow path of the raw material liquid pipe; and a purge gas supply pipe that joins the raw material liquid pipe between the valve and the raw material liquid nozzle.

The invention discloses porous, bioactive glass and glass ceramic morsels or pellets to be used as tissue graft substitute materials and processes for obtaining the same wherein the bioactive glass and glass ceramic morsels or pellets are made up of natural agents like phosphate, calcium, sodium and other elements which are not alien to the human or animal body. The said preparation process encompasses various steps like quenching sintering, foaming, and sol-gel casting which render the glass morsels or pellets unique bioactivity and enhanced porosity which may facilitate tissue repair and augmentation during tissue graft replacement.