A copolymer may be obtained by polymerization reaction(s) using an anionic monomer and two polyethoxylated monomers. Such copolymers may have a polydispersity index, determined by size exclusion chromatography (SEC), of less than 3, and be obtained by at least one radical polymerisation reaction in water at a temperature ranging from 10 to 90° C. A composition may include such copolymers. Such copolymers may be prepared and use as a superplasticizer for a hydraulic binder composition.

The present invention relates to polycondensates containing at least a structural unit, which is an aromatic moiety bearing a polyether side chain, at least a structural unit, which is an aromatic moiety bearing at least one phosphoric acid monoester group, at least a structural unit, which is an aromatic moiety, bearing at least one hydroxy group and at least a methylene unit (—CH.sub.2—), which is attached to two aromatic structural units. The invention also concerns a process for the production of the polycondensates, their use for the dispersion of inorganic binders, for increasing the strength development of concrete and for improving the slump-retention of concrete. The invention relates also to building material mixtures comprising the polycondensates and inorganic binders.

A method for increasing the workability of a binder composition including calcined clay, limestone, and Portland cement. The method includes a step of adding an admixture comprising at least one PCE and at least one additive selected from the group including sugar acids, sugars, sugar alcohols, and hydroxycarboxylic acids. The invention also relates to an admixture to be used in said method and hardenable compositions, especially concrete and mortar, obtainable by the method.

The present invention relates to an additive for hydraulically setting compositions, comprising a colloidally disperse preparation of at least one salt of a mono- or polyvalent metal cation and of at least one compound which is able to release an anion which forms a low-solubility salt with the metal cation, and of at least one polymeric sulphonated dispersant. The additive is suitable particularly as a slump retainer.

The present invention relates to an additive for hydraulically setting compositions, comprising a colloidally disperse preparation of at least one salt of a mono- or polyvalent metal cation and of at least one compound which is able to release an anion which forms a low-solubility salt with the metal cation, and of at least one polymeric sulphonated dispersant. The additive is suitable particularly as a slump retainer.

The present invention relates to an additive for hydraulically setting compositions, comprising a colloidally disperse preparation of at least one water-soluble salt of a polyvalent metal cation, at least one compound capable of releasing an anion which forms a sparingly soluble salt with the polyvalent metal cation, and at least one polymeric dispersant which comprises anionic and/or anionogenic groups and polyether side chains.

The present disclosure relates to a cement additive composition including a polycarboxylic acid-based copolymer. When the cement additive composition of the present disclosure is used for cement formulation, it may improve fluidity of the composition even in a high water reducing ratio range of the particle and effectively prevent slump loss of the cement formulation, while improving initial dispersibility due to excellent water reducing performance.

Methods for plasticizing cementitious mixtures having relatively high water/cement ratio (at least 0.40 or higher) are surprisingly improved in terms of dosage efficiency, compared to conventional “superplasticizer” polycarboxylate polymers, when the comb-type carboxylate copolymer is formed from two different polyether side chains, specifically selected monomer constituents: (A) first polyoxyalkylene monomer represented by structural formula (R.sup.1)(R.sup.3)C═C(R.sup.2)((CH.sub.2).sub.m(CO).sub.nO(CH.sub.2).sub.o(AO).sub.pR.sup.4) wherein (AO).sub.p represents linear alkylene oxide and p is an integer of 5-23; (B) second polyoxyalkylene monomer represented by structural formula (R.sup.1)(R.sup.3)C═C(R.sup.2)((CH.sub.2).sub.m(CO).sub.nO(CH.sub.2).sub.o(AO).sub.qR.sup.4) wherein (AO).sub.q represents linear alkylene oxide groups and q is an integer of 20 to 200; (C) unsaturated carboxylic acid monomer represented by (R.sup.5)(R.sup.7)C═C(R.sup.6)(C(O)OM) wherein M represents an alkali metal, and the ratio of component A to component B is 20:80 to 50:50; and, optionally, (D) a water-soluble monomer represented by (R.sup.8)(R.sup.9)C═C(R.sup.10)(X) wherein R.sup.8, R.sup.9, and R.sup.10 each represent hydrogen or methyl group, and X represents C(O)NH.sub.2, C(O)NHR.sup.11, C(O)NR.sup.12R.sup.13, OR.sup.14, SO.sub.3H, C.sub.6H.sub.4SO.sub.3H, or C(O)NHC(CH.sub.3).sub.2CH.sub.2SO.sub.3H, or mixture thereof, wherein R.sup.11, R.sup.12, R.sup.13, and R.sup.14 each represent a C.sub.1 to C.sub.5 alkyl group.

A multifunctional cement additive includes a biochelant and a solvent. The biochelant includes a sodium glucarate liquid oxidation product including predominantly gluconate and glucarate anions with minor component species of n-keto-acids and C.sub.2-C.sub.5 diacids. A cement composition includes (i) a cementitious material and (ii) a biochelant, and (iii) a solvent. The biochelant includes a sodium glucarate liquid oxidation product including predominantly gluconate and glucarate anions with minor component species of n-keto-acids and C.sub.2-C.sub.5 diacids.

Methods, systems, and devices, are developed for in-situ placement of a concrete mix that can have the thixotropy to hold vertical dimension without containment, while maintaining pliability to be pumped into place and manipulated to a desired shape, and can be combined with concrete set accelerators, allowing subsequent layers of this concrete mix to be continuously stacked in place to build tall walls and such without the use of forms. Concrete without these special properties is pumped toward the point of placement where it is modified by injecting and mixing, into that line of pumped concrete, an admixture containing thixotropes, thickeners and/or set accelerators or other modifiers to provide these properties and other improvements. This method allows conventional plant batching with commonly available constituent materials for batching an economical concrete that is delivered to a jobsite and then is pumped most of the way to a point of placement.