An article includes a substrate, a ceramic barrier coating, and a layer of networked ceramic nanofibers. The ceramic barrier coating is disposed on the substrate and has a porous columnar microstructure. The layer of networked ceramic nanofibers is disposed on the ceramic barrier layer and seals the pores of the porous columnar microstructure.

The present invention relates to a method for producing a three-dimensional macroporous filament construct having interconnected microporous filaments showing a suitable surface roughness and microporosity. The method includes the steps of: a) preparing a suspension having particles of a predetermined material, a liquid solvent, one or more binders and optionally one or more dispersants, b) depositing the suspension in the form of filaments in a predetermined three-dimensional pattern, preferably in a non-solvent environment, thereby creating a three-dimensional filament-based porous structure, c) inducing phase inversion, whereby said filaments are transformed from a liquid to a solid state, by exposing the filaments during the deposition of the filaments with a non-solvent vapour and to a liquid non-solvent, d) thermally treating the structure of step d) by calcining and sintering the structure. The invention further provides a three-dimensional macroporous filament construct having interconnected microporous filaments showing a specific surface roughness and microporosity. The invention also relates to various uses of the construct, including its use for the manufacture of a biomedical product, such as a synthetic bone implant or bone graft.

The present application discloses and claims a method to make a flexible ceramic fibers (Flexiramics™) and polymer composites. The resulting composite has an improved mechanical strength (tensile) when compared with the Flexiramics™ alone. Several different polymers can be used, both thermosets and thermoplastics. Flexiramics™ has unique physical characteristics and the composite materials can be used for numerous industrial and laboratory applications.

In one aspect, a fiber delivery assembly is provided including a backing tape and a single-filament fiber coupled to the backing tape. In another aspect, a method of making a fiber delivery assembly is provided, which includes: providing a backing tape; providing a single-filament fiber; and coupling the single-filament fiber to the backing tape.

Disclosed are an inorganic nanofiber characterized in that the average fiber diameter is 2 μm or less, the average fiber length is 200 μm or less, and the CV value of the fiber length is 0.7 or less; and a method of manufacturing the same. In the manufacturing method, an inorganic nanofiber sheet consisting of inorganic nanofibers having an average fiber diameter of 2 μm or less is formed by electrospinning, and then, the inorganic nanofiber sheet is pressed using a press machine and crushed so that the average fiber length becomes 200 μm or less, and the CV value of the fiber length becomes 0.7 or less.

A polymetalloxane is described having a constituent unit represented by the following general formula (1):

##STR00001##

wherein R.sup.1, R.sup.2, R.sup.3, M a, b and m are as defined.

A ceramic material includes zirconia toughened alumina (ZTA), which is doped with zinc ions and other metal ions, in which the other metal ions are chromium (Cr) ions, titanium (Ti) ions, gadolinium (Gd) ions, manganese (Mn) ions, cobalt (Co) ions, iron (Fe) ions, or a combination thereof. The ceramic material may have a hardness of 1600 Hv10 to 2200 Hv10 and a bending strength of 600 MPa to 645 MPa. The ceramic material can be used as wire bonding capillary.

An object is to provide metal element-having ceramic continuous fibers suitable for use in the production of highly heat-resistant CMCs, and a CMC made therewith. The ceramic continuous fibers comprise ceramic continuous fibers and at least one metal element therein, with the concentration by mass of the metal element being 10 ppm or more and 1000 ppm or less.

The present application discloses and claims a method to make a flexible ceramic fibers (Flexiramics™) and polymer composites. The resulting composite has an improved mechanical strength (tensile) when compared with the Flexiramics™ respective the nanofibers alone. Additionally a composite has better properties than the polymer alone such as lower fire retardancy, higher thermal conductivity and lower thermal expansion. Several different polymers can be used, both thermosets and thermoplastics. Flexiramics™ has unique physical characteristic and the composite materials can be used for numerous industrial and laboratory applications.

The present invention is a method for obtaining a ceramic slurry for the production of filaments for 3D FDM printing, comprising adding a polysaccharide, a glycol or an ethanolamine as a gelling agent to a suspension of ceramic material in order to produce said ceramic slurry. The invention also comprises the green body obtained from said slurry and the ceramic filament extruded from the green body.