Ceramic matrix composite articles include, for example a first plurality of plies of ceramic fibers in a ceramic matrix defining a first extent, and a local at least one second ply in said ceramic matrix defining a second extent on and/or in said first plurality of plies with the second extent being less than said first extent. The first plurality of plies has a first property, the at least one second ply has at least one second property, and said first property being different from said at least one second property. The different properties may include one or more different mechanical (stress/strain) properties, one or more different thermal conductivity properties, one or more different electrical conductivity properties, one or more different other properties, and combinations thereof.

Systems, devices, and methods are provided for manufacturing a carbon ceramic brake disc. Generally, a plurality of uncured or partially-cured bulk molding compound preforms or molding compound layers and ventilation cores are placed in a mold cavity and warm-pressed at a first temperature. The ventilation cores are removed from the resulting cured green body. The cured green body is then removed from the mold, and treated through a polymer infiltration and pyrolysis or reactive melt infiltration process. Certain steps can be repeated until a desired target density or weight is attained.

A molding tool made of carbon or graphite, namely a casting mold or a casting core for the processing of molten metal or to a molding tool for the processing of molten glass, such as for example a blow mold and a method for producing the molding tool.

A method of preparing a lithium-ion conducting garnet via low-temperature solid-state synthesis is disclosed. The lithium-ion conducting garnet comprises a substantially phase pure aluminum-doped cubic lithium lanthanum zirconate (Li.sub.7La.sub.3Zr.sub.2O.sub.14). The method includes preparing nanoparticles comprising lanthanum zirconate (La.sub.2Zr.sub.2O.sub.7-np) via pyrolysis-mediated reaction of lanthanum nitrate (La(NO.sub.3).sub.3) and zirconium nitrate (Zr(NO.sub.3).sub.4). The method also includes pyrolyzing a solid-state mixture comprising the La.sub.2Zr.sub.2O.sub.7-np, lithium nitrate (LiNO.sub.3), and aluminum nitrate (Al(NO.sub.3).sub.3) to give the Li.sub.7La.sub.3Zr.sub.2O.sub.14 and thereby prepare the lithium-ion conducting garnet. A lithium-ion conducting garnet prepared via the method is also disclosed.

Disclosed herein are a polyimide film for graphite sheets and a graphite sheet manufactured using the same. The polyimide film is fabricated by imidizing a precursor composition including: a polyamic acid prepared by reacting a dianhydride monomer with a diamine monomer; and an organic solvent, wherein the diamine monomer includes about 30 mol % to about 70 mol % of 4,4′-methylenedianiline and about 30 mol % to about 70 mol % of 4,4′-oxydianiline based on the total number of moles of the diamine monomer, 4,4′-methylenedianiline and 4,4′-oxydianiline being present in total in an amount of about 85 mol % or more based on the total number of moles of the diamine monomer.

A ceramic component, wherein the component contains 20 to 60 wt. % SiC, 5 to 40 wt. % free silicon and 10 to 65 wt. % free carbon. The disclosure also relates to the use of the component. The method for producing the ceramic component includes the following steps: a) providing a green body based on carbon, which has been produced by means of a 3D-printing method, b) impregnating the green body with a solution selected from the group consisting of a sugar solution, a starch solution or a cellulose solution, or a resin system including a mixture containing at least one resin, at least one solvent and at least one curing agent, wherein the at least one resin and the at least one solvent are different, c) drying or curing the impregnated green body.

Provided are a high-entropy carbide ceramic, a rare earth-containing high-entropy carbide ceramic, fibers thereof, precursors thereof, and preparation methods thereof. The precursor includes at least four elements selected from Ti, Zr, Hf, V, Nb, Ta, Mo, and W, with each metal element accounting for 5-35% of the total molar quantity of metal elements in the precursor. The rare earth-containing high-entropy carbide ceramic precursor includes at least four transition metal elements and at least one rare-earth metal element. The high-entropy ceramic is a single-crystal-phase high-performance ceramic prepared from the precursor, with each element being homogenously distributed at molecular level. The method for preparing the high-entropy ceramic fiber includes uniformly mixing high-entropy carbide ceramic precursor containing target metal elements with spinning aid and solvent to prepare a spinnable precursor solution, followed by spinning, pyrolyzation, and high-temperature solid solution to prepare the high-entropy carbide ceramic fiber.

A nanoparticle cluster reduction method yields a new composition of matter including a large percentage (e.g., 75% or higher percentage) of primary nanoparticles in the new composition of matter. The particle reduction method reduces the size of nanoparticle clusters in material of the new composition of matter, allows particle reduction of specific nanoparticle cluster sizes, and allows particle reduction to primary nanoparticles. This new composition of matter can include a high permittivity and high resistivity dielectric compound. This new composition of matter, according to certain examples, has high permittivity, high resistivity, and low leakage current. In certain examples, the new composition of matter constitutes a dielectric energy storage device that is a battery with very high energy density, high operating voltage per cell, and an extended battery life cycle. An example method can include a controlled gas evolution reaction to reduce the size of nanoparticle clusters.

A preform for making a component of a braking system having a fibre-reinforced ceramic composite material, obtained by forming and subsequent pyrolysis of a pre-preg is described. Also described is a component of a braking system made wholly or in part from the preform, and a method for making a preform in a fibre-reinforced ceramic composite material.

In one aspect, the disclosure relates to nanocomposite radome materials incorporating boron nitride materials in a polymer derived ceramic matrix. In another aspect, the nanocomposite radome materials have superior electrochemical performance, excellent mechanical strength and stability, corrosion resistance and transparency to electromagnetic radiation, methods of making the same, and articles and components incorporating the same. In one aspect, the nanocomposite radome materials retain functionality in the presence of significant amounts of moisture. This abstract is intended as a scanning tool for purposes of searching in the particular art and is not intended to be limiting of the present disclosure.