Provided herein is a method of making a conductive network by combining uncoated carbon nanotubes and carbon nanotubes coated with an electroactive substance to create an electrically conductive network; and redistributing at least a portion of the electroactive substance. Also provided herein is an electrically conductive network with an active material coating; first carbon nanotubes coated with the active material coating; and second carbon nanotubes partially coated with the active material coating, wherein at least a portion of the surfaces of the second carbon nanotubes directly contact surfaces of other second carbon nanotubes without the active material coating between these second carbon nanotubes, and wherein the first carbon nanotubes and the second carbon nanotubes are entangled to form an electrically conductive network.

Provided herein is an electrically conductive, chemically insulated network of nanofibers that includes first carbon nanofibers electrically connected to second carbon nanofibers to form an electrically conductive network, and second carbon nanofibers electrically connected to other second carbon nanofibers, wherein at least one of the second carbon nanofibers is in direct surface contact with another of the second carbon nanofibers; and an active material that provides electrochemical insulation on surfaces of the first carbon nanofibers and partial surfaces of at least a portion of the second carbon nanofibers, wherein the active material comprises at least 50% by weight of the electrically conductive, chemically insulated network, and wherein the active material provides electrochemical insulation to the entirety of the electrically conductive, chemically insulated network of nanofibers including the area between the first carbon nanofibers and the second carbon nanofibers.

The present invention relates to a metal-halide composite, articles comprising a metal-halide composite and method of making and using same. The metal-halide matrix materials used in such composite have the desired properties of high thermal conductivity, resistance to thermal induced microstructural changes, and ease of use. As a result, they permit the fabrication of higher performance cryogenic magnets, motors, generators, and cables. Additionally, they permit the fabrication of plate reinforced composites that are useful in lightweight armor and other articles. Additionally, an optoelectronic composite could be built depending on the choice of metal-halide matrix and reinforcement.

A method of treating silicon carbide fibers comprises phosphating heat treatment in a reactive gas so as to form a coating around each fiber for protection against oxidation. The coating comprises a surface layer of silicon pyrophosphate crystals and at least one underlying bilayer system comprising a layer of a phosphosilicate glass and a layer of microporous carbon.

Provided herein is a method of manufacturing a nanoscale coated network, which includes providing nanofibers, capable of forming a network in the presence of a liquid vehicle and providing a nanoscale solid substance in the presence of the liquid vehicle. The method may also include forming a network of the nanofibers and the nanoscale solid substance and redistributing at least a portion of the nanoscale solid substance within the network to produce a network of nanofibers coated with the nanoscale solid substance. Also provided herein is a nanoscale coated network with an active material coating that is redistributed to cover and electrochemically isolate the network from materials outside the network.

A method of manufacturing a coated reinforcing fiber for use in Ceramic Matrix Composites, the method comprising pre-oxidizing a plurality of silicon-based fibers selected from the group consisting of silicon carbide (SiC) fibers, silicon nitride (Si.sub.3N.sub.4) fibers, SiCO fibers, SiCN fibers, SiCNO fibers, and SiBCN fibers at between 700 to 1300 degrees Celsius in an oxidizing atmosphere to form a silica surface layer on the plurality of silicon-based fibers, forming a plurality of pre-oxidized fibers; applying a rare earth orthophosphate (REPO.sub.4) coating to the plurality of pre-oxidized fibers; and heating the plurality of REPO.sub.4 coated pre-oxidized fibers at about 1000-1500 degrees Celsius in an inert atmosphere to react the REPO.sub.4 with the silica surface layer to form a rare earth silicate or disilicate. The pre-oxidizing step may be 0.5 hours to about 100 hours. The heating step may be about 5 minutes to about 100 hours.

A method of manufacturing a coated reinforcing fiber for use in Ceramic Matrix Composites, the method comprising pre-oxidizing a plurality of silicon-based fibers selected from the group consisting of silicon carbide (SiC) fibers, silicon nitride (Si.sub.3N.sub.4) fibers, SiCO fibers, SiCN fibers, SiCNO fibers, and SiBCN fibers at between 700 to 1300 degrees Celsius in an oxidizing atmosphere to form a silica surface layer on the plurality of silicon-based fibers, forming a plurality of pre-oxidized fibers; applying a rare earth orthophosphate (REPO.sub.4) coating to the plurality of pre-oxidized fibers; and heating the plurality of REPO.sub.4 coated pre-oxidized fibers at about 1000-1500 degrees Celsius in an inert atmosphere to react the REPO.sub.4 with the silica surface layer to form a rare earth silicate or disilicate. The pre-oxidizing step may be 0.5 hours to about 100 hours. The heating step may be about 5 minutes to about 100 hours.

Powder particles for forming a homogeneous green body having a sufficient strength and a process for producing a green body by using the powder particles. A green body is shaped by using powder particles of composite particles in which thermoplastic resin particles are scattered on surfaces of large particles in an amount within a predetermined volume ratio range with respect to the large particles, and loaded to form resin pools in contact point peripheral areas of adjoining ones of the large particles and form voids in areas other than the contact point peripheral areas when the thermoplastic resin particles are melted. A green body packed with the powder particles each having a small amount of the thermoplastic resin particles attached thereon is placed under a melting condition of the thermoplastic resin particles, the thermoplastic resin is melted and gathers around contact points (or proximal points) of the adjoining powder particles.

Provided herein is a method of making a conductive network by combining uncoated carbon nanotubes and carbon nanotubes coated with an electroactive substance to create an electrically conductive network; and redistributing at least a portion of the electroactive substance. Also provided herein is an electrically conductive network with an active material coating; first carbon nanotubes coated with the active material coating; and second carbon nanotubes partially coated with the active material coating, wherein at least a portion of the surfaces of the second carbon nanotubes directly contact surfaces of other second carbon nanotubes without the active material coating between these second carbon nanotubes, and wherein the first carbon nanotubes and the second carbon nanotubes are entangled to form an electrically conductive network.

Provided herein is a method of manufacturing a nanoscale coated network, which includes providing nanofibers, capable of forming a network in the presence of a liquid vehicle and providing a nanoscale solid substance in the presence of the liquid vehicle. The method may also include forming a network of the nanofibers and the nanoscale solid substance and redistributing at least a portion of the nanoscale solid substance within the network to produce a network of nanofibers coated with the nanoscale solid substance. Also provided herein is a nanoscale coated network with an active material coating that is redistributed to cover and electrochemically isolate the network from materials outside the network.