A supported catalyst and preparation method thereof, the catalyst comprising an organic polymer material carrier and Raney alloy particles supported on the organic polymer material carrier, wherein substantially all of the Raney alloy particles are partially embedded in the organic polymer material carrier. The catalyst can be used in hydrogenation, dehydrogenation, amination, dehalogenation or desulfuration reactions.

A supported catalyst and preparation method thereof, the catalyst comprising an organic polymer material carrier and Raney alloy particles supported on the organic polymer material carrier, wherein substantially all of the Raney alloy particles are partially embedded in the organic polymer material carrier. The catalyst can be used in hydrogenation, dehydrogenation, amination, dehalogenation or desulfuration reactions.

The present invention relates to a supported nickel catalyst precursor comprising Ni, Si, Al, and O, wherein the catalyst precursor displays a specific total intrusion volume determined via Hg intrusion. Further, the present invention relates to a process for preparing said catalyst precursor. Yet further, the present invention relates to a supported nickel catalyst prepared from the said catalyst precursor. In addition thereto, the present invention relates to a use thereof in a hydrogenation reaction of aromatic compounds.

The present invention relates to a supported nickel catalyst precursor comprising Ni, Si, Al, and O, wherein the catalyst precursor displays a specific total intrusion volume determined via Hg intrusion. Further, the present invention relates to a process for preparing said catalyst precursor. Yet further, the present invention relates to a supported nickel catalyst prepared from the said catalyst precursor. In addition thereto, the present invention relates to a use thereof in a hydrogenation reaction of aromatic compounds.

The disclosure provides use of an efficient, recyclable, green and friendly catalyst to realize a method of hydrogenation of an unsaturated alkene, and a method for preparing biodiesel through the transesterification of soybean oil with ethanol. The method of hydrogenation of the unsaturated alkene comprises performing a hydrogenation reaction of an unsaturated alkene at ambient temperature and atmospheric pressure by using a CO.sub.2 and magnetic dual-responsive mesoporous poly(ionic liquid) as a catalyst I, and using n-hexane and water as a solvent, to obtain a corresponding saturated alkane. The method for preparing biodiesel through transesterification of soybean oil with ethanol comprises performing a transesterification reaction of soybean oil with ethanol at a temperature of 25-90° C. and atmospheric pressure by using a CO.sub.2 and magnetic dual-responsive mesoporous poly(ionic liquid) as a catalyst II, to obtain the biodiesel.

There is provided a novel optically active bisphosphinomethane useful as a ligand for an asymmetric catalyst, excellent in oxidation resistance in air, and easy in handling. There is also provided a transition metal complex using the optically active bisphosphinoraethane having excellent asymmetric catalytic ability as a ligand. The optically active bisphosphinomethane is represented by the general formula (1), and the transition metal complex has the optically active bisphosphinomethane as a ligand. ##STR00001##
(In the formula, R.sup.1 represents an adamantyl group; R.sup.2 represents a branched alkyl group having 3 or more carbon atoms; and * represents an asymmetric center on a phosphorus atom.)

Disclosed are methods for the preparation of ligands for complexes, methods for preparing complexes and complexes having those ligands. Also provided is the use of a complex as a catalyst in a method of synthesis.

Disclosed are methods for the preparation of ligands for complexes, methods for preparing complexes and complexes having those ligands. Also provided is the use of a complex as a catalyst in a method of synthesis.

A method of making highly an active mixed transition metal oxide material has been developed. The method may include sulfiding the metal oxide material to generate metal sulfides which are used as catalyst in a conversion process such as hydroprocessing. The hydroprocessing may include hydrodenitrification, hydrodesulfurization, hydrodemetallation, hydrodesilication, hydrodearomatization, hydroisomerization, hydrotreating, hydrofining, and hydrocracking.

A method of making highly an active mixed transition metal oxide material has been developed. The method may include sulfiding the metal oxide material to generate metal sulfides which are used as catalyst in a conversion process such as hydroprocessing. The hydroprocessing may include hydrodenitrification, hydrodesulfurization, hydrodemetallation, hydrodesilication, hydrodearomatization, hydroisomerization, hydrotreating, hydrofining, and hydrocracking.