Patent classifications
C07C1/041
Reactor for the Conversion of Carbon Dioxide
The present invention concerns a reactor for the conversion of carbon dioxide or carbon monoxide into hydrocarbon and/or alcohol comprising a support made from an electrically and thermally conductive material, forming the wall or walls of at least one longitudinal channel that passes through the support and also acting as the cathode of the reactor, at least one wire electrode forming an anode of the reactor, and extending within each longitudinal channel, and being arranged at a distance from the wall or walls of the longitudinal channel, each wire electrode optionally being covered with an electrically insulating layer along the part of the wire electrode extending within the longitudinal channel, a catalyst capable of catalysing a conversion reaction for the conversion of carbon dioxide or carbon monoxide into hydrocarbon and/or alcohol, the catalyst being situated between the wire electrode and the wall or walls of each longitudinal channel.
Reactor for the Conversion of Carbon Dioxide
The present invention concerns a reactor for the conversion of carbon dioxide or carbon monoxide into hydrocarbon and/or alcohol comprising a support made from an electrically and thermally conductive material, forming the wall or walls of at least one longitudinal channel that passes through the support and also acting as the cathode of the reactor, at least one wire electrode forming an anode of the reactor, and extending within each longitudinal channel, and being arranged at a distance from the wall or walls of the longitudinal channel, each wire electrode optionally being covered with an electrically insulating layer along the part of the wire electrode extending within the longitudinal channel, a catalyst capable of catalysing a conversion reaction for the conversion of carbon dioxide or carbon monoxide into hydrocarbon and/or alcohol, the catalyst being situated between the wire electrode and the wall or walls of each longitudinal channel.
Oxidative coupling of methane implementations for olefin production
The present disclosure provides oxidative coupling of methane (OCM) systems for small scale and world scale production of olefins. An OCM system may comprise an OCM subsystem that generates a product stream comprising C.sub.2+ compounds and non-C.sub.2+ impurities from methane and an oxidizing agent. At least one separations subsystem downstream of, and fluidically coupled to, the OCM subsystem can be used to separate the non-C.sub.2+ impurities from the C.sub.2+ compounds. A methanation subsystem downstream and fluidically coupled to the OCM subsystem can be used to react H.sub.2 with CO and/or CO.sub.2 in the non-C.sub.2+ impurities to generate methane, which can be recycled to the OCM subsystem. The OCM system can be integrated in a non-OCM system, such as a natural gas liquids system or an existing ethylene cracker.
METHOD FOR CONVERTING A GAS COMPRISING CARBON MONOXIDE INTO METHANE BY MEANS OF A CATALYTIC MATERIAL CONTAINING PRASEODYMIUM AND NICKEL ON ALUMINA
The invention relates to a method for converting a gas into methane (CH.sub.4) which includes: a step of activating a catalytic material including praseodymium oxide (Pr.sub.6O.sub.11) associated with nickel oxide (NiO) and alumina (Al.sub.2O.sub.3), the respective proportions of which are, relative to the total mass of these three compounds: Pr.sub.6O.sub.11: 1 wt % to 20 wt %, NiO: 1 wt % to 20 wt %, and Al.sub.2O.sub.3: 60 to 98 wt %; and a step of passing a gas including at least one carbon monoxide (CO) over the activated catalytic material.
METHANE PRODUCTION SYSTEM
A methane production system comprises: a reaction tank that produces methane and water by reacting CO and/or CO.sub.2 supplied to the reaction tank with hydrogen; a cleaning tank that is located at an upstream side of the reaction tank in a supply direction of the CO and/or CO.sub.2, and removes water-soluble impurities from a raw material gas including the CO and/or CO.sub.2 and the water-soluble impurities by bringing the raw material gas into contact with water; and a first supply line that supplies the raw material gas from which the water-soluble impurities are removed from the cleaning tank to the reaction tank; and a second supply line supplies water produced in the reaction tank from the reaction tank to the cleaning tank to bring the produced water into contact with the raw material gas in the cleaning tank.
DEVICE AND METHOD FOR HYBRID PRODUCTION OF SYNTHETIC DIHYDROGEN AND/OR SYNTHETIC METHAN
The device (100) for hybrid production of synthetic dihydrogen and/or synthetic methane comprises: an inlet (105) for a synthesis gas stream preferably comprising at least CO and H.sub.2, a catalytic conversion reactor (110), the following alternative configurations: a first configuration in which the operating conditions of the reactor promote a Sabatier reaction, so as to produce an outlet gas comprising mainly methane, or a second configuration in which the operating conditions of the reactor promote a water gas shift reaction, so as to produce an outlet gas comprising mainly dihydrogen; an outlet (115) for synthetic dihydrogen and/or synthetic methane and a control system (120) comprising a means (121) for selecting a configuration for operating the reactor and a control means (122) according to the selected configuration, the reactor being configured to operate according to a command.
DEVICE AND METHOD FOR HYBRID PRODUCTION OF SYNTHETIC DIHYDROGEN AND/OR SYNTHETIC METHAN
The device (100) for hybrid production of synthetic dihydrogen and/or synthetic methane comprises: an inlet (105) for a synthesis gas stream preferably comprising at least CO and H.sub.2, a catalytic conversion reactor (110), the following alternative configurations: a first configuration in which the operating conditions of the reactor promote a Sabatier reaction, so as to produce an outlet gas comprising mainly methane, or a second configuration in which the operating conditions of the reactor promote a water gas shift reaction, so as to produce an outlet gas comprising mainly dihydrogen; an outlet (115) for synthetic dihydrogen and/or synthetic methane and a control system (120) comprising a means (121) for selecting a configuration for operating the reactor and a control means (122) according to the selected configuration, the reactor being configured to operate according to a command.
METHODS AND SYSTEMS FOR CONVERTING CARBON OXIDES TO OLEFINS
A method of converting carbon oxides to olefins is provided. The method can include directing a renewable hydrogen feed stream and a carbon oxide feed stream to a methanation reactor to generate an oxidative coupling of methane (OCM) feed stream that includes methane. The OCM feed stream and an oxidant feed stream including oxygen are directed to an OCM reactor containing an OCM catalyst to produce an OCM effluent that includes ethylene. A system for converting carbon oxides to olefins is also provided. The methods and systems produce olefins including ethylene with negative carbon emissions.
Catalytic solar reactor
A catalytic solar reactor useful in chemical processes, more particularly, useful in endothermic chemical processes. The reactor comprises a reaction pathway defined by an exterior wall and an interior wall, the exterior wall comprising a solar radiation receiver capable of converting solar radiation into heat and transmitting the heat to the reaction pathway. Further, the reaction pathway has disposed therein, in alternating fashion, a plurality of catalytic elements and a plurality of heat transfer elements. Optionally, a supplementary heater, such as a conventional fossil fuel burner, is disposed in a plenum located within the interior of the reactor. The heater is employed as a supplemental source of heat, for example, when solar radiation is unavailable.
OFF-GAS UTILIZATION IN ELECTRICALLY HEATED REFORMING PLANT
A plant and a method are provided in which a first feed including hydrocarbons is subjected to electrical steam methane reforming (e-SMR) to generate a first syngas stream. An upgrading section receives the syngas stream and generates a first product stream and an off-gas stream from the syngas stream. A power generator receives at least a portion of the off-gas stream and/or a portion of said first product stream from the upgrading section and/or a portion of said first feed and generates a second electricity flow. At least a portion of the second electricity flow is arranged to provide at least a part of the first electricity flow to the e-SMR reactor.