Patent classifications
C07C2523/60
Supported PtZn intermetallic alloy catalyst, method for preparing the same and application thereof
The present application discloses a supported PtZn intermetallic alloy catalyst, a method for preparing the same and application thereof. The catalyst uses SiO.sub.2 as a support and Zn as a promoter, and a small amount of active component Pt is supported; the weight percentage of Pt is 0.025%-1%, and the weight percentage of Zn is 0.025%-1.7%, a co-impregnation method is adopted in preparation, the SiO.sub.2 support is impregnated in aqueous solution of chloroplatinic acid and zinc nitrate, and then drying and high-temperature reduction are performed to obtain a PtZn/SiO.sub.2 catalyst. The catalyst has the advantages of high activity, high stability, low price and low toxicity. The catalyst provided by the present application is applicable to preparation of alkene through short-chain alkane dehydrogenation, in particular to preparation of propylene through propane dehydrogenation in a hydrogen atmosphere. Under high-temperature conditions, the dehydrogenation activity is very high, the propylene selectivity can reach more than 90%, the stability is good, and the amount of used Pt is small, the utilization rate is high, and it is cheaper than industrial Pt series catalysts.
DEHYDROGENATION CATALYST FOR PRODUCTION OF OLEFINS FROM ALKANE GASES AND PREPARATION METHOD THEREOF
The present disclosure is to provide a catalyst for olefin production which is eco-friendly and has excellent conversion rates and selectivity and a preparation method thereof, and the catalyst for olefin production according to the present disclosure is one in which cobalt and zinc are supported with alumina. Particularly, the catalyst according to the present disclosure uses an amount of platinum that is about 400 times smaller than that of the conventional catalysts, and has high conversion rates and selectivity under conditions in which continuous reaction-regeneration process is possible without an additional hydrogen reduction process.
CATALYST FOR PRODUCING ISOPROPYLBENZENE AND THE PRODUCTION METHOD AND USE THEREOF
Described are a catalyst for producing isopropylbenzene and the production method and use thereof. The catalyst includes a support and an active component supported on the support, wherein the support comprises a support substrate and a modifying auxiliary component supported on the support substrate, wherein the active component includes metal palladium and/or an oxide thereof, and the modifying auxiliary component is phosphorus and/or an oxide thereof; optionally, the active component further includes metal copper and/or an oxide thereof; the catalyst further includes a sulfur-containing compound.
Aromatization of light hydrocarbons using metal-modified zeolite catalysts
Embodiments of the present disclosure are directed to processes for aromatizing hydrocarbons includes contacting the hydrocarbons with a catalyst including at least two different metal modifiers dispersed on surfaces of a hydrogen-form medium-pore zeolite support. Each of the at least two different metal modifiers comprises a metal selected from the group consisting of IUPAC Groups 3-12, and lanthanide metals, and the catalyst is substantially free of gallium. Contacting the hydrocarbons with the catalyst causes a least a portion of the hydrocarbons to undergo a chemical reaction to form aromatic hydrocarbons.
Catalytic biomass conversion methods, catalysts, and methods of making the same
Described herein are processes for one-step delignification and hydrodeoxygenation of lignin fraction a biomass feedstock. The lignin feedstock is derived from by-products of paper production and biorefineries. Additionally described is a process for converting biomass-derived oxygenates to lower oxygen-content compounds and/or hydrocarbons in the liquid or vapor phase in a reactor system containing hydrogen and a catalyst comprised of a hydrogenation function and/or an oxophilic function and/or an acid function. Finally, also described herein is a process for converting biomass-derived oxygenates to lower oxygen-content compounds and/or hydrocarbons in the liquid or vapor phase in a reactor system containing hydrogen and a catalyst comprised of a hydrogenation function and/or an oxophilic function and/or an acid function.
PROCESS FOR 1-BUTENE PRODUCTION FROM N-BUTANE DEHYDROGENATION THROUGH EFFICIENT DOWNSTREAM SEPARATIONS
System and method for producing 1-butene are disclosed. The method includes dehydrogenating butane to form a mixture comprising butene isomers. 1-butene is separated from the mixture using a system that includes a membrane. The system also includes an isomerizing unit for isomerizing cis-2-butene and trans-2-butene to form additional 1-butene.
INTEGRATION OF OXIDATIVE DEHYDROGENATION PROCESS WITH CATALYTIC MEMBRANE DEHYDROGENATION REACTOR PROCESS
This disclosure relates to a process of converting one or more alkanes to one or more alkenes that includes providing a first stream containing one or more alkanes and oxygen to an oxidative dehydrogenation process which converts at least a portion of the one or more alkanes to one or more alkenes in an oxidative dehydrogenation reactor, a second stream exiting the oxidative dehydrogenation process comprising one or more alkanes, and one or more alkenes; and providing at least a portion of the alkanes in the second stream to a catalytic membrane dehydrogenation process containing a catalyst loaded into a catalytic dehydrogenation membrane reactor which converts at least a portion of the alkanes to the corresponding alkenes and hydrogen.
Process for 1-butene production from n-butane dehydrogenation through efficient downstream separations
System and method for producing 1-butene are disclosed. The method includes dehydrogenating butane to form a mixture comprising butene isomers. 1-butene is separated from the mixture using a system that includes a membrane. The system also includes an isomerizing unit for isomerizing cis-2-butene and trans-2-butene to form additional 1-butene.
AROMATIZATION OF LIGHT HYDROCARBONS USING METAL-MODIFIED ZEOLITE CATALYSTS
Embodiments of the present disclosure are directed to processes for aromatizing hydrocarbons includes contacting the hydrocarbons with a catalyst including at least two different metal modifiers dispersed on surfaces of a hydrogen-form medium-pore zeolite support. Each of the at least two different metal modifiers comprises a metal selected from the group consisting of IUPAC Groups 3-12, and lanthanide metals, and the catalyst is substantially free of gallium. Contacting the hydrocarbons with the catalyst causes a least a portion of the hydrocarbons to undergo a chemical reaction to form aromatic hydrocarbons.
SUPPORTED PtZn INTERMETALLIC ALLOY CATALYST, METHOD FOR PREPARING THE SAME AND APPLICATION THEREOF
The present application discloses a supported PtZn intermetallic alloy catalyst, a method for preparing the same and application thereof. The catalyst uses SiO.sub.2 as a support and Zn as a promoter, and a small amount of active component Pt is supported; the weight percentage of Pt is 0.025%-1%, and the weight percentage of Zn is 0.025%-1.7%, a co-impregnation method is adopted in preparation, the SiO.sub.2 support is impregnated in aqueous solution of chloroplatinic acid and zinc nitrate, and then drying and high-temperature reduction are performed to obtain a PtZn/SiO.sub.2 catalyst. The catalyst has the advantages of high activity, high stability, low price and low toxicity. The catalyst provided by the present application is applicable to preparation of alkene through short-chain alkane dehydrogenation, in particular to preparation of propylene through propane dehydrogenation in a hydrogen atmosphere. Under high-temperature conditions, the dehydrogenation activity is very high, the propylene selectivity can reach more than 90%, the stability is good, and the amount of used Pt is small, the utilization rate is high, and it is cheaper than industrial Pt series catalysts.