Catalysts for the hydrogenolysis of butane are described. A supported catalyst for hydrogenolysis of butane to ethane can include a support and a catalytic crystalline bimetallic composition that can include a molybdenum-iridium (Mo—Ir) crystalline composition attached to the support. The supported catalyst has a BET specific surface area of at least 100 m.sup.2/g, preferably 100 m.sup.2/g to 500 m.sup.2/g. Method of use and methods of making the catalyst are also described.

Systems and methods for producing an isomerization product. One or more isomerization reactors comprising a catalyst may be used to process an isomerization feedstock comprising a primary n-paraffin reactant and hydrogen gas, and the isomerization reactor may be operated at a pressure parameter at which the partial pressure of the primary n-paraffin is within about 70% to about 130% of its equilibrium vapor pressure to isomerize the primary n-paraffin reactant.

-- An electrolysis cell unit capable of efficiently electrolyzing water and carbon dioxide is obtained. An electrolysis cell unit includes at least an electrolysis cell in which an electrode layer and a counter electrode layer are formed with an electrolyte layer interposed therebetween and a discharge path for discharging hydrogen generated in the electrode layer, in which the electrolysis cell being formed in a thin layer on a support and a reverse water-gas shift reaction unit that generates carbon monoxide using carbon dioxide and the hydrogen by a reverse water-gas shift reaction being provided in at least a portion of the discharge path.--

As a hydrocarbon production system that synthesizes hydrocarbons using water and carbon dioxide as raw materials, a hydrocarbon production system capable of producing hydrocarbons by securing hydrogen and carbon monoxide required for hydrocarbon synthesis is provided. In a hydrocarbon production system that produces hydrocarbons from at least water and carbon dioxide, the hydrocarbon production system includes at least an electrolytic reaction unit, a reverse water-gas shift reaction unit, and a hydrocarbon synthesis reaction unit.

A hydrocarbon production system capable of efficiently producing hydrocarbon containing a high-calorie gas by securing hydrogen and carbon monoxide required for hydrocarbon synthesis using water and carbon dioxide as raw materials is obtained. The hydrocarbon production system includes an electrolytic reaction unit that converts water and carbon dioxide into hydrogen and carbon monoxide through an electrolytic reaction, a catalytic reaction unit that converts a product generated by the electrolytic reaction unit into hydrocarbon through a catalytic reaction, and branch paths and that branch a portion of an outlet component of the catalytic reaction unit.

To provide an egg shell-type platinum-loaded alumina catalyst demonstrating excellent performance in terms of catalyst life, an egg shell-type platinum-loaded alumina catalyst includes: an alumina carrier; platinum dispersed and loaded on an outer shell of the alumina carrier; and one or more second components selected from the group consisting of vanadium, chromium, molybdenum, and phosphorus. Preferably, the content of platinum is 0.05 to 5.0 wt % calculated as elemental platinum. The content of each second component preferably is 0.1 to 5.0 wt % calculated as each element. The alumina carrier has a surface area of 150 m.sup.2/g or more, a pore volume of 0.40 cm.sup.3/g or more, and an average pore diameter of 40 to 300 Å, with pores having a pore diameter in a range of ±30 Å from the average pore diameter occupying 60% or more of a total pore volume.

The presently disclosed subject matter relates to methods and systems for alkane dehydrogenation. In a particular non-limiting embodiment, the presently disclosed subject matter provides a system for the dehydrogenation of alkanes that includes two or more reactors configured to perform a dehydrogenation reaction of an alkane in the presence of a catalyst to produce an olefin and a catalyst regenerator, coupled to each of the two or more reactors through at least one transfer line to a regenerator, for the regeneration of spent catalyst.

Embodiments of methods of synthesizing a metathesis catalyst system, which include impregnating tungsten oxide on silica support in the presence of a precursor to produce a base catalyst; calcining the base catalyst; dispersing a solid metal-based co-catalyst onto the surface of the base catalyst to produce a doped catalyst; and calcining the doped catalyst to produce a metathesis catalyst system. Further embodiments of processes for the production of propylene, which include contacting a hydrocarbon feedstock comprising a mixture of 1-butene and 2-butene with embodiments of the metathesis catalyst system to produce, via metathesis conversion, a product stream comprising propylene.

A novel catalyst composition and its use in the dehydrogenation of alkanes to olefins. The catalyst comprises a Group VIII noble metal and a metal selected from the group consisting of manganese, vanadium, chromium, titanium, and combinations thereof, on a support. The Group VIII noble metal can be platinum, palladium, osmium, rhodium, rubidium, iridium, and combinations thereof. The support can be silicon dioxide, titanium dioxide, aluminum oxide, silica-alumina, cerium dioxide, zirconium dioxide, magnesium oxide, metal modified silica, silica-pillared clays, silica-pillared micas, metal oxide modified silica-pillared mica, silica-pillared tetrasilicic mica, silica-pillared taeniolite, zeolite, molecular sieve, and combinations thereof. The catalyst composition is an active and selective catalyst for the catalytic dehydrogenation of alkanes to olefins.

A process for producing an ether including treating (a) an ester with (b) hydrogen in the presence of (c) a heterogeneous catalyst to reduce the ester by hydrogenation to form an ether product.