An apparatus for forming C1 to C5 alcohol, carboxylic acid, or mixture thereof from carbon dioxide and hydrogen is described. The apparatus comprises: a dielectric barrier discharge, DBD, device arranged to generate a plasma; and a passageway having an inlet for the carbon dioxide and the hydrogen and an outlet for the C1 to C5 alcohol, carboxylic acid, or mixture thereof and including therein a catalyst comprising nickel and/or cobalt and/or copper on a support. The passageway extends, at least in part, through the DBD device wherein, in use, the carbon dioxide is exposed to the catalyst in the presence of the hydrogen in the generated plasma, thereby forming the C1 to C5 alcohol, carboxylic acid, or mixture thereof from at least some of the carbon dioxide and the hydrogen. The DBD devices comprises a water electrode. A method and a catalyst are also described.

A catalyst containing, as an essential component, molybdenum; bismuth; and cobalt, in which, with respect to a peak intensity at 2θ=25.3°±0.2° in an X-ray diffraction pattern obtained by using CuKα rays as an X-ray source, a changing rate (Q1) per 1000 hours of reaction time represented by the following formulae (1) to (4) is 16 or less.

Q1={(U1/F1−1)×100}/T×1000  (1)

F1=(peak intensity of catalyst before oxidation reaction at 2θ=25.3°±)0.2°/(peak intensity of catalyst before oxidation reaction at 2θ=26.5°±0.2°)×100  (2)

U1=(peak intensity of catalyst after oxidation reaction at 2θ=25.3°±0.2°)/(peak intensity of catalyst after oxidation reaction at 2θ=26.5°±0.2°)×100  (3)

T=time (hr) during which oxidation reaction is carried out  (4)

A method is disclosed for rejuvenation a cobalt Fischer Tropsch catalyst used in a Fischer Tropsch process operating in recycle mode. The method permits the use of specific inert gases to adjust the mole weight of the gas so that the recycle compressor designed for normal steady state operation can also be used in the method. Hydrogen from a membrane permeate stream is added to the reactor loop at a temperature between 300 F and 400 F and the carbon oxides are reacted out to purify the hydrogen. This stream is continuously recycled and the temperature is raised to between 425 F and 500 F and held at the final temperature for between 4 hours and 48 hours. The cobalt Fischer Tropsch catalyst is effectively rejuvenated in-situ by the method.

There is provided a catalyst that enables the production of isobutylene with a high selectivity in the production of isobutylene by dehydration of isobutanol. The catalyst according to the present invention contains at least one metal selected from Group 6 to Group 14 metal elements in Period 4 to Period 6 of the periodic table, in alumina which includes alumina consisting of one or more crystal phases of a monoclinic crystal phase, a tetragonal crystal phase, and a cubic crystal phase.

A dehydrogenation catalyst for producing propylene by a dehydrogenation reaction of propane, the dehydrogenation catalyst including a platinum element and an element M1 and may contain an element M2 as active components, wherein the element M1 is one or more elements selected from the group consisting of a gallium element, a cobalt element, a copper element, a germanium element, a tin element and an iron element, the element M2 is one or more elements selected from the group consisting of a lead element and a calcium element, and the platinum element and the element M1 form an alloy.

Provided is a method for producing organic molecules having at least two carbon atoms chained together by the reaction of a hydrogen-containing source, a carbon-containing source and an optional nitrogen-containing source in the presence of a nanostructure or nanostructures, wherein the reaction is initiated by heat.

According to one or more embodiments presently disclosed, a catalyst for converting hydrocarbons may include catalytic oxidized metal materials comprising oxidized iron, oxidized cobalt, and oxidized copper. At least 95 wt. % of the catalytic oxidized metal materials may be a combination of oxidized iron, oxidized cobalt, and oxidized copper. The catalyst may additionally include a mesoporous support material comprising pores having an average pore diameter of from 2 nm to 50 nm. At least 95 wt. % of the mesoporous support material may comprise alumina. At least 95 wt. % of the catalyst may be the combination of the catalytic oxidized metal materials and the mesoporous support material. Additional embodiments are included, such as methods for making the presently disclosed catalysts.

The present invention provides a method for producing 1,3-butadiene that is capable of suppressing generation of reaction by-products. The method includes: a step (A) of to obtain a produced gas containing 1,3-butadiene; a step (B) of cooling the produced gas; and a step (C) of separating the produced gas cooled in the step (B) into molecular oxygen and inert gases, and other gases containing 1,3-butadiene, by selective absorption into an absorption solvent. In the method, in the step (A), the raw material gas and a molecular oxygen-containing gas are supplied to a fixed-bed reactor with a composite oxide catalyst containing molybdenum and bismuth; the molar ratio of molecular oxygen to n-butene in the gases is 1.0 to 2.0; and the molar ratio of water vapor to n-butene in the gases supplied to the fixed-bed reactor is not more than 1.2.

The present disclosure is to provide a catalyst for olefin production which is eco-friendly and has excellent conversion rates and selectivity and a preparation method thereof, and the catalyst for olefin production according to the present disclosure is one in which cobalt and zinc are supported with alumina. Particularly, the catalyst according to the present disclosure uses an amount of platinum that is about 400 times smaller than that of the conventional catalysts, and has high conversion rates and selectivity under conditions in which continuous reaction-regeneration process is possible without an additional hydrogen reduction process.

Fischer-Tropsch process for the synthesis of hydrocarbons by bringing a feedstock including synthesis gas into contact with a catalyst prepared by the following: a porous support is brought into contact with a cobalt metal salt of which the melting point of the cobalt metal salt is between 30 and 150° C. for between 5 minutes and 5 hours, in order to form a solid mixture, the weight ratio of said cobalt metal salt to the porous oxide support being between 0.1 and 1; the solid mixture obtained is heated with stirring under atmospheric pressure at a temperature between the melting point of the cobalt metal salt and 200° C. for a period of time of between 30 minutes and 12 hours; the solid obtained is calcined at a temperature above 200° C. and below or equal to 1100° C.