The present disclosure provides for a rhodium-catalyzed oxidative arene alkenylation from arenes and styrenes to prepare stilbene and stilbene derivatives. For example, the present disclosure provides for method of making arenes or substituted arenes, in particular stilbene and stilbene derivatives, from a reaction of an optionally substituted arene and/or optionally substituted styrene. The reaction includes a Rh catalyst or Rh pre-catalyst material and an oxidant, where the Rh catalyst or Rh catalyst formed Rh pre-catalyst material selectively functionalizes CH bond on the arene compound (e.g., benzene or substituted benzene).

A radio access network (RAN) configured to support real-time communications over a Long-Term Evolution (LTE) connection is described herein. When a request for a data transmission is received and a real-time communication session over the LTE connection is established, the RAN utilizes the LTE connection, not a New Radio (NR) connection, for the data transmission. When a request for a further real-time communication is received and there is an active data transmission session over the NR connection, the RAN performs at least one of ceasing to allocate traffic to the NR connection for downlink or reconfiguring the data transmission session to send data over the LTE connection.

The disclosure provides use of an efficient, recyclable, green and friendly catalyst to realize a method of hydrogenation of an unsaturated alkene, and a method for preparing biodiesel through the transesterification of soybean oil with ethanol. The method of hydrogenation of the unsaturated alkene comprises performing a hydrogenation reaction of an unsaturated alkene at ambient temperature and atmospheric pressure by using a CO.sub.2 and magnetic dual-responsive mesoporous poly(ionic liquid) as a catalyst I, and using n-hexane and water as a solvent, to obtain a corresponding saturated alkane. The method for preparing biodiesel through transesterification of soybean oil with ethanol comprises performing a transesterification reaction of soybean oil with ethanol at a temperature of 25-90° C. and atmospheric pressure by using a CO.sub.2 and magnetic dual-responsive mesoporous poly(ionic liquid) as a catalyst II, to obtain the biodiesel.

Provided is a mononuclear ruthenium complex that comprises a ruthenium-silicon bond that is represented by formula (1) and that exhibits excellent catalyst activity in each of a hydrosilylation reaction, a hydrogenation reaction, and reduction of a carbonyl compound. ##STR00001## In formula (1), R.sup.1-R.sup.6 either independently represent an alkyl group, an aryl group, an aralkyl group or the like that may be substituted with a hydrogen atom or X, or represent a crosslinking substituent in which at least one pair comprising one of R.sup.1-R.sup.3 and one of R.sup.4-R.sup.6 is combined. X represents a halogen atom, an organoxy group, or the like. L represents a two-electron ligand other than CO and phosphine. When a plurality of L are present, the plurality of L may be the same as or different from each other. When two L are present, the two L may be bonded to each other. n and m independently represent an integer of 1 to 3 with the stipulation that n+m equals 3 or 4.

A radio access network (RAN) configured to support real-time communications over a Long-Term Evolution (LTE) connection is described herein. When a request for a data transmission is received and a real-time communication session over the LTE connection is established, the RAN utilizes the LTE connection, not a New Radio (NR) connection, for the data transmission. When a request for a further real-time communication is received and there is an active data transmission session over the NR connection, the RAN performs at least one of ceasing to allocate traffic to the NR connection for downlink or reconfiguring the data transmission session to send data over the LTE connection.

A radio access network (RAN) configured to support real-time communications over a Long-Term Evolution (LTE) connection is described herein. When a request for a data transmission is received and a real-time communication session over the LTE connection is established, the RAN utilizes the LTE connection, not a New Radio (NR) connection, for the data transmission. When a request for a further real-time communication is received and there is an active data transmission session over the NR connection, the RAN performs at least one of ceasing to allocate traffic to the NR connection for downlink or reconfiguring the data transmission session to send data over the LTE connection.

A radio access network (RAN) configured to support real-time communications over a Long-Term Evolution (LTE) connection is described herein. When a request for a data transmission is received and a real-time communication session over the LTE connection is established, the RAN utilizes the LTE connection, not a New Radio (NR) connection, for the data transmission. When a request for a further real-time communication is received and there is an active data transmission session over the NR connection, the RAN performs at least one of ceasing to allocate traffic to the NR connection for downlink or reconfiguring the data transmission session to send data over the LTE connection.

A radio access network (RAN) configured to support real-time communications over a Long-Term Evolution (LTE) connection is described herein. When a request for a data transmission is received and a real-time communication session over the LTE connection is established, the RAN utilizes the LTE connection, not a New Radio (NR) connection, for the data transmission. When a request for a further real-time communication is received and there is an active data transmission session over the NR connection, the RAN performs at least one of ceasing to allocate traffic to the NR connection for downlink or reconfiguring the data transmission session to send data over the LTE connection.

Disclosed is a process for preparing 2,2,4,4-tetramethylcyclobutane-1,3-diol by reacting 2,2,4,4-tetramethylcyclobutanedione with a secondary alcohol in the presence of a transfer hydrogenation catalyst.

A process for producing alpha-olefins comprising contacting an ethylene feed with an oligomerization catalyst system in an oligomeriation reaction zone under oligomerization reaction conditions to produce a product stream comprising alpha-olefins wherein the catalyst system comprises a metal-ligand complex and a co-catalyst and the oligomerization reaction conditions comprise a reaction temperature of at least 115 C.