A process can treat a gaseous material mixture obtained by catalytic conversion of synthesis gas that contains at least alkenes, possibly alcohols and possibly alkanes, and also possibly nitrogen as inert gas and unconverted components of the synthesis gas, comprising hydrogen, carbon monoxide and/or carbon dioxide. After catalytic conversion of synthesis gas, separation of the product mixture obtained in this reaction into a gas phase and a liquid phase is performed by at least partial absorption of the alkenes, possibly of the alcohols and possibly of the alkanes, in a high boiling point hydrocarbon or hydrocarbon mixture as an absorption medium, separation as the gas phase of the gases not absorbed into the absorption medium, separating an aqueous phase from the organic phase of the absorption medium, preferably by decanting, and desorption of the alkenes, possibly of the alcohols and possibly of the alkanes, from the absorption medium.

A process can produce alcohols having at least two carbon atoms by catalytic conversion of synthesis gas into a mixture containing alkanes, alkenes, and alcohols. Alkenes are converted into corresponding alcohols in a subsequent step by hydration of the alkanes. Before the hydration and after the catalytic conversion, gas and liquid phases may be separated. Specific catalysts can be employed that have a markedly higher selectivity for alkenes than for alkanes. These catalysts comprise grains of non-graphitic carbon having cobalt nanoparticles dispersed therein. The cobalt nanoparticles have an average diameter d.sub.p from 1 to 20 nm, and an average distance D between nanoparticles is from 2 to 150 nm. The combined total mass fraction of metal ω in the grains ranges from 30% to 70% by weight of the total mass of the grains of non-graphitic carbon, wherein 4.5 dp/ω>D≥0.25 dp/ω.

A process can produce alcohols having at least two carbon atoms by catalytic conversion of synthesis gas into a mixture containing alkanes, alkenes, and alcohols. Alkenes are converted into corresponding alcohols in a subsequent step by hydration of the alkanes. Before the hydration and after the catalytic conversion, gas and liquid phases may be separated. Specific catalysts can be employed that have a markedly higher selectivity for alkenes than for alkanes. These catalysts comprise grains of non-graphitic carbon having cobalt nanoparticles dispersed therein. The cobalt nanoparticles have an average diameter d.sub.p from 1 to 20 nm, and an average distance D between nanoparticles is from 2 to 150 nm. The combined total mass fraction of metal ω in the grains ranges from 30% to 70% by weight of the total mass of the grains of non-graphitic carbon, wherein 4.5 dp/ω>D≥0.25 dp/ω.

A method to make primary alcohols, carboxylic acids, amines, and other value-added chemicals from plastic waste. The method includes the steps of pyrolyzing plastic waste to yield pyrolysis oil; hydroformylating the pyrolysis oil in the absence of any added co-reactants to yield a mixture comprising aldehydes; and hydrogenating, oxidizing, aminating, or aldolizing the mixture to yield a product comprising primary alcohols, carboxylic acids, amines, or larger (>C10) chemicals with carbonyl function groups.

A method to make primary alcohols, carboxylic acids, amines, and other value-added chemicals from plastic waste. The method includes the steps of pyrolyzing plastic waste to yield pyrolysis oil; hydroformylating the pyrolysis oil in the absence of any added co-reactants to yield a mixture comprising aldehydes; and hydrogenating, oxidizing, aminating, or aldolizing the mixture to yield a product comprising primary alcohols, carboxylic acids, amines, or larger (>C10) chemicals with carbonyl function groups.

A process can produce alcohols having at least two carbon atoms by catalytic conversion of synthesis gas into a mixture containing alkanes, alkenes, and alcohols. Alkenes are converted into corresponding alcohols in a subsequent step by hydration of the alkanes. Before the hydration and after the catalytic conversion, gas and liquid phases may be separated. Specific catalysts can be employed that have a markedly higher selectivity for alkenes than for alkanes. These catalysts comprise grains of non-graphitic carbon having cobalt nanoparticles dispersed therein. The cobalt nanoparticles have an average diameter d.sub.p from 1 to 20 nm, and an average distance D between nanoparticles is from 2 to 150 nm. The combined total mass fraction of metal ? in the grains ranges from 30% to 70% by weight of the total mass of the grains of non-graphitic carbon, wherein 4.5 dp/?>D?0.25 dp/?.

A process can produce alcohols having at least two carbon atoms by catalytic conversion of synthesis gas into a mixture containing alkanes, alkenes, and alcohols. Alkenes are converted into corresponding alcohols in a subsequent step by hydration of the alkanes. Before the hydration and after the catalytic conversion, gas and liquid phases may be separated. Specific catalysts can be employed that have a markedly higher selectivity for alkenes than for alkanes. These catalysts comprise grains of non-graphitic carbon having cobalt nanoparticles dispersed therein. The cobalt nanoparticles have an average diameter d.sub.p from 1 to 20 nm, and an average distance D between nanoparticles is from 2 to 150 nm. The combined total mass fraction of metal ? in the grains ranges from 30% to 70% by weight of the total mass of the grains of non-graphitic carbon, wherein 4.5 dp/?>D?0.25 dp/?.

A method to make primary alcohols, carboxylic acids, amines, and other value-added chemicals from plastic waste. The method includes the steps of pyrolyzing plastic waste to yield pyrolysis oil; hydroformylating the pyrolysis oil in the absence of any added co-reactants to yield a mixture comprising aldehydes; and hydrogenating, oxidizing, aminating, or aldolizing the mixture to yield a product comprising primary alcohols, carboxylic acids, amines, or larger (>C10) chemicals with carbonyl function groups.

A method to make primary alcohols, carboxylic acids, amines, and other value-added chemicals from plastic waste. The method includes the steps of pyrolyzing plastic waste to yield pyrolysis oil; hydroformylating the pyrolysis oil in the absence of any added co-reactants to yield a mixture comprising aldehydes; and hydrogenating, oxidizing, aminating, or aldolizing the mixture to yield a product comprising primary alcohols, carboxylic acids, amines, or larger (>C10) chemicals with carbonyl function groups.