Patent classifications
C07C409/38
DI-SEC-BUTYL PEROXYDICARBONATE EMULSION
The invention relates to an organic peroxide emulsion comprising at least one organic peroxide comprising di-sec-butyl peroxydicarbonate, at least one emulsifier, at least one antifreeze, and water; said emulsion being free of methanol and ethanol.
The invention also relates to a process for preparing such an emulsion, to the use of such an emulsion for the polymerization or copolymerization of one or more ethylenically unsaturated monomers, and also to a halogenated vinyl polymer obtained by using such an emulsion.
DI-SEC-BUTYL PEROXYDICARBONATE EMULSION
The invention relates to an organic peroxide emulsion comprising at least one organic peroxide comprising di-sec-butyl peroxydicarbonate, at least one emulsifier, at least one antifreeze, and water; said emulsion being free of methanol and ethanol.
The invention also relates to a process for preparing such an emulsion, to the use of such an emulsion for the polymerization or copolymerization of one or more ethylenically unsaturated monomers, and also to a halogenated vinyl polymer obtained by using such an emulsion.
DI-SEC-BUTYL PEROXYDICARBONATE EMULSION
The invention relates to an organic peroxide emulsion comprising at least one organic peroxide comprising di-sec-butyl peroxydicarbonate, at least one emulsifier, at least one antifreeze, and water; said emulsion being free of methanol and ethanol.
The invention also relates to a process for preparing such an emulsion, to the use of such an emulsion for the polymerization or copolymerization of one or more ethylenically unsaturated monomers, and also to a halogenated vinyl polymer obtained by using such an emulsion.
PROCESS FOR THE PRODUCTION OF A FERTILIZER
Process for the production of a compound comprising potassium phosphite comprising the steps of (a) reacting carboxylic acid of the formula R—(C(═O)OH).sub.n with phosphorous trichloride (PCl.sub.3) towards a mixture comprising phosphorous acid (H.sub.3PO.sub.3) and acid chloride of the formula R—(C(═O)Cl).sub.n; wherein R is a linear or branched alkyl or alkanediyl group with 1-20 carbon atoms and n is 1 or 2, (b) subjecting said mixture to a separation step, thereby obtaining (i) a fraction comprising crude phosphorous acid (H.sub.3PO.sub.3) and (ii) a fraction comprising acid chloride, (c) combining water, a potassium compound selected from KOH, KHCO.sub.3 and K.sub.2CO.sub.3, and the fraction comprising crude phosphorous acid, thereby forming an aqueous solution comprising potassium phosphite, and (d) removing organic compounds from said aqueous solution.
PROCESS FOR THE PRODUCTION OF A FERTILIZER
Process for the production of a compound comprising potassium phosphite comprising the steps of (a) reacting carboxylic acid of the formula R—(C(═O)OH).sub.n with phosphorous trichloride (PCl.sub.3) towards a mixture comprising phosphorous acid (H.sub.3PO.sub.3) and acid chloride of the formula R—(C(═O)Cl).sub.n; wherein R is a linear or branched alkyl or alkanediyl group with 1-20 carbon atoms and n is 1 or 2, (b) subjecting said mixture to a separation step, thereby obtaining (i) a fraction comprising crude phosphorous acid (H.sub.3PO.sub.3) and (ii) a fraction comprising acid chloride, (c) combining water, a potassium compound selected from KOH, KHCO.sub.3 and K.sub.2CO.sub.3, and the fraction comprising crude phosphorous acid, thereby forming an aqueous solution comprising potassium phosphite, and (d) removing organic compounds from said aqueous solution.
PROCESS FOR THE PRODUCTION OF PEROXYESTERS
Process for the production of a peroxyester involving the reaction of an anhydride with an organic hydroperoxide, separation of the formed carboxylic acid, production of an anhydride from said carboxylic acid, and recycling of the anhydride within the process.
PROCESS FOR THE PRODUCTION OF PEROXYESTERS
Process for the production of a peroxyester involving the reaction of an anhydride with an organic hydroperoxide, separation of the formed carboxylic acid, production of an anhydride from said carboxylic acid, and recycling of the anhydride within the process.
AQUEOUS ORGANIC PEROXIDE EMULSION
The present invention relates to an aqueous emulsion of peroxyester, comprising at least one peroxyester, at least one antifreeze and a combination of at least two emulsifiers chosen from the group consisting of a non-ethoxylated sorbitan ester, an ethoxylated sorbitan ester and an ethoxylated fatty alcohol.
AQUEOUS ORGANIC PEROXIDE EMULSION
The present invention relates to an aqueous emulsion of peroxyester, comprising at least one peroxyester, at least one antifreeze and a combination of at least two emulsifiers chosen from the group consisting of a non-ethoxylated sorbitan ester, an ethoxylated sorbitan ester and an ethoxylated fatty alcohol.
Organic compound, three-dimensional organic framework formed by using organic compound, separation sieve and optical layer, which comprise organic framework, and optical device comprising optical layer as optical amplification layer
An organic compound, a three-dimensional organic structure formed by using the organic compound, a separation sieve and an optical layer having the organic structure, and an optical device having the optical layer as an optical amplification layer are provided. The organic structure includes a plurality of organic molecules self-assembled by non-covalent bonding. Each of the unit organic molecules has an aromatic ring, a first pair of substituents being connected to immediately adjacent positions of substitutable positions of the aromatic ring, and a second pair of substituents being connected to immediately adjacent positions of remaining substitutable positions of the aromatic ring. The unit organic molecules are self-assembled by van der Waals interaction, London dispersion interaction or hydrogen bonding between the first and the second pairs of the substituents and by pi-pi interactions between the aromatic rings.