The present invention relates to a process for thermolytic fragmentation of a sugar into a composition comprising C.sub.1-C.sub.3 oxygenates. In particular, it relates to the use of heat carrying particles providing improved yields of C.sub.1-C.sub.3 oxygenates and improved fluidization characteristics making it suitable for industrial scale production of e.g. glycolaldehyde. It also regards a circulating fluidized bed system comprising the heat carrying particles.

The present invention relates to a process for thermolytic fragmentation of a sugar into a composition comprising C.sub.1-C.sub.3 oxygenates. In particular, it relates to the use of heat carrying particles providing improved yields of C.sub.1-C.sub.3 oxygenates and improved fluidization characteristics making it suitable for industrial scale production of e.g. glycolaldehyde. It also regards a circulating fluidized bed system comprising the heat carrying particles.

The present invention relates to the use of compounds of formula (I) in the treatment of products, in particular of aqueous or nonaqueous compositions, preferably water and aqueous compositions, against bacteria of the Burkholderia cepacia complex (Bcc), and also the use thereof in a process for treating an aqueous composition or water with respect to strains of the Bcc complex.

##STR00001##

formula (I) wherein: R2 represents a hydrogen atom or a methyl or ethyl radical; R3 represents a linear C.sub.1-C.sub.12 alkyl radical (saturated), optionally substituted with a hydroxyl group; or a linear C.sub.2-C.sub.12 alkenyl radical (C═C unsaturated), optionally substituted with a hydroxyl group.

The present invention relates to the use of compounds of formula (I) in the treatment of products, in particular of aqueous or nonaqueous compositions, preferably water and aqueous compositions, against bacteria of the Burkholderia cepacia complex (Bcc), and also the use thereof in a process for treating an aqueous composition or water with respect to strains of the Bcc complex.

##STR00001##

formula (I) wherein: R2 represents a hydrogen atom or a methyl or ethyl radical; R3 represents a linear C.sub.1-C.sub.12 alkyl radical (saturated), optionally substituted with a hydroxyl group; or a linear C.sub.2-C.sub.12 alkenyl radical (C═C unsaturated), optionally substituted with a hydroxyl group.

A process for large scale and energy efficient production of oxygenates from sugar is disclosed in which a sugar feedstock is introduced into a thermolytic fragmentation reactor including a fluidized stream of heat carrying particles which are separated from the reaction product and directed to a reheater comprising a resistance heating system.

A process for large scale and energy efficient production of oxygenates from sugar is disclosed in which a sugar feedstock is introduced into a thermolytic fragmentation reactor including a fluidized stream of heat carrying particles which are separated from the reaction product and directed to a reheater comprising a resistance heating system.

Disclosed is a method of removing calcium from a hydrocarbon fraction using an extraction agent including 2-oxopropanal or derivatives thereof, the method including (S1) adding a hydrocarbon fraction with an extraction agent including 2-oxopropanal or derivatives thereof to give a mixture, (S2) converting an oil-soluble calcium compound into a water-soluble calcium compound by reacting the hydrocarbon fraction with the 2-oxopropanal or derivatives thereof, and (S3) removing the water-soluble calcium compound.

Disclosed is a method of removing calcium from a hydrocarbon fraction using an extraction agent including 2-oxopropanal or derivatives thereof, the method including (S1) adding a hydrocarbon fraction with an extraction agent including 2-oxopropanal or derivatives thereof to give a mixture, (S2) converting an oil-soluble calcium compound into a water-soluble calcium compound by reacting the hydrocarbon fraction with the 2-oxopropanal or derivatives thereof, and (S3) removing the water-soluble calcium compound.

A (Z)-solanone has the steric formula of:

##STR00001##

with the name of (S,Z)-5-isopropyl-8-methyl-6,8-diene-2-one or (R,Z)-5-isopropyl-8-methyl-6,8-diene-2-one. A process for the preparation of the (Z)-type solanone and the use thereof in flavoring of cigarette shred are further disclosed. The process includes the following steps: (1) reacting isopentanal and methyl vinyl ketone, under the action of a catalyst and a co-catalyst, to give (S)-2-isopropyl-5-carbonylhexanal or (R)-2-isopropyl-5-carbonylhexanal; (2) reacting the (S)-2-isopropyl-5-carbonylhexanal or the (R)-2-isopropyl-5-carbonylhexanal obtained in step (1) with (iodomethyl)triphenylphosphonium iodide, to give (S,Z)-7-iodo-5-isopropyl-6-ene-2-one or (R,Z)-7-iodo-5-isopropyl-6-ene-2-one; and (3) reacting the (S,Z)-7-iodo-5-isopropyl-6-ene-2-one or the (R,Z)-7-iodo-5-isopropyl-6-ene-2-one obtained in step (2) with pinacol isopropenylborate in the presence of a catalyst to give the (Z)-solanone.

A (Z)-solanone has the steric formula of:

##STR00001##

with the name of (S,Z)-5-isopropyl-8-methyl-6,8-diene-2-one or (R,Z)-5-isopropyl-8-methyl-6,8-diene-2-one. A process for the preparation of the (Z)-type solanone and the use thereof in flavoring of cigarette shred are further disclosed. The process includes the following steps: (1) reacting isopentanal and methyl vinyl ketone, under the action of a catalyst and a co-catalyst, to give (S)-2-isopropyl-5-carbonylhexanal or (R)-2-isopropyl-5-carbonylhexanal; (2) reacting the (S)-2-isopropyl-5-carbonylhexanal or the (R)-2-isopropyl-5-carbonylhexanal obtained in step (1) with (iodomethyl)triphenylphosphonium iodide, to give (S,Z)-7-iodo-5-isopropyl-6-ene-2-one or (R,Z)-7-iodo-5-isopropyl-6-ene-2-one; and (3) reacting the (S,Z)-7-iodo-5-isopropyl-6-ene-2-one or the (R,Z)-7-iodo-5-isopropyl-6-ene-2-one obtained in step (2) with pinacol isopropenylborate in the presence of a catalyst to give the (Z)-solanone.