An epoxy compound, composition and cured product thereof are provided. The epoxy compound has a structure represented by Formula (I)

##STR00001##

wherein R.sup.1 and R.sup.2 are each independently cyano group, isocyanate group, oxiranyl, methyloxiranyl group, glycidyl group, methylglycidyl group, epoxypropyl group, oxetanyl group, oxetanemethyl group, or C.sub.1-C.sub.10 alkoxy group; Z is —O—,

##STR00002##

R.sup.3 and R.sup.4 are each independently hydrogen, fluorine, methyl, fluoromethyl, or ethyl; n and m are each independently 3, 4, 5, 6, 7, 8, 9, or 10; and i and j are each independently 1, 2, or 3.

An epoxy compound, composition and cured product thereof are provided. The epoxy compound has a structure represented by Formula (I)

##STR00001##

wherein R.sup.1 and R.sup.2 are each independently cyano group, isocyanate group, oxiranyl, methyloxiranyl group, glycidyl group, methylglycidyl group, epoxypropyl group, oxetanyl group, oxetanemethyl group, or C.sub.1-C.sub.10 alkoxy group; Z is —O—,

##STR00002##

R.sup.3 and R.sup.4 are each independently hydrogen, fluorine, methyl, fluoromethyl, or ethyl; n and m are each independently 3, 4, 5, 6, 7, 8, 9, or 10; and i and j are each independently 1, 2, or 3.

Disclosed herein are compositions and methods of making phenolic compounds, and resins comprising these phenolic compounds. The compounds include multifunctional epoxies, amino glycidyl derivatives, and multi-functional amines prepared from hydroxymethyl derivatives of phenols and bisphenols

A process for preparing an anticorrosive coating includes providing a substrate, providing a sacrificial metal particle, chemically binding a graphitic material to a first molecule comprising a first group, a first spacer, and a second group, chemically binding said graphitic material to a second molecule comprising a third group, a second spacer, and a fourth group, wherein said third group is a different group from said first group, binding said sacrificial metal particle to either said first or said third group, binding either said first or said third group with said substrate, wherein said group bound to said substrate is different from said group bound to said sacrificial metal particle, chemically binding said second group and said fourth group to said graphitic material, growing thermoset resin side chains on said graphitic material, and growing siloxane side chains on said graphitic material.

A process for preparing an anticorrosive coating includes providing a substrate, providing a sacrificial metal particle, chemically binding a graphitic material to a first molecule comprising a first group, a first spacer, and a second group, chemically binding said graphitic material to a second molecule comprising a third group, a second spacer, and a fourth group, wherein said third group is a different group from said first group, binding said sacrificial metal particle to either said first or said third group, binding either said first or said third group with said substrate, wherein said group bound to said substrate is different from said group bound to said sacrificial metal particle, chemically binding said second group and said fourth group to said graphitic material, growing thermoset resin side chains on said graphitic material, and growing siloxane side chains on said graphitic material.

Disclosed is a method for producing a biphenyl-skeleton-containing epoxy resin represented by Formula (1) described below including a step of allowing polyvalent hydroxy biphenyl obtained by a production step including a regioselective cross-coupling reaction to react with epihalohydrin. ##STR00001##
(In the formula, k1 and l1 each represent an integer of 0 to 4, m and n each represent an integer of 1 to 5, R.sup.1 and R.sup.2 each independently represent a hydrocarbon group having 1 to 10 carbon atoms which may have a substituent group, and R.sup.1 and R.sup.2 may be identical to each other or different from each other. (Provided that left and right phenyl structures of a biphenyl skeleton are different from each other.)

Disclosed is a method for producing a biphenyl-skeleton-containing epoxy resin represented by Formula (1) described below including a step of allowing polyvalent hydroxy biphenyl obtained by a production step including a regioselective cross-coupling reaction to react with epihalohydrin. ##STR00001##
(In the formula, k1 and l1 each represent an integer of 0 to 4, m and n each represent an integer of 1 to 5, R.sup.1 and R.sup.2 each independently represent a hydrocarbon group having 1 to 10 carbon atoms which may have a substituent group, and R.sup.1 and R.sup.2 may be identical to each other or different from each other. (Provided that left and right phenyl structures of a biphenyl skeleton are different from each other.)

One or more techniques are disclosed for a method for functionalized a graphitic material comprising the steps of: 1) providing a graphitic material; 2) providing a first molecule comprising a first group, a spacer, and a second group; 3) providing a second molecule comprising a third group, a spacer, and a fourth group, wherein the third group is a different group from the first group; and 4) bonding the first molecule and the second molecule to the graphitic material. Also disclosed is a tunable material composition comprising the functionalized carbon nanotubes or functionalized graphene prepared by the methods described herein.

One or more techniques are disclosed for a method for functionalized a graphitic material comprising the steps of: 1) providing a graphitic material; 2) providing a first molecule comprising a first group, a spacer, and a second group; 3) providing a second molecule comprising a third group, a spacer, and a fourth group, wherein the third group is a different group from the first group; and 4) bonding the first molecule and the second molecule to the graphitic material. Also disclosed is a tunable material composition comprising the functionalized carbon nanotubes or functionalized graphene prepared by the methods described herein.

A compound having end groups each having a reactive group that are disposed at both ends respectively, and between the end groups, either or both of a first structure in which an aromatic cyclic group, an ether oxygen, a methylene group, an aromatic cyclic group, a methylene group, an ether oxygen and an aromatic cyclic group are bonded together in this order and a second structure in which an aromatic cyclic group, a methylene group, an ether oxygen, an aromatic cyclic group, an ether oxygen, a methylene group and an aromatic cyclic group are bonded together in this order.