C07F9/5414

ORGANOPOLYSILOXANE COMPOUND, METHOD FOR PRODUCING SAME, AND ANTISTATIC AGENT AND CURABLE COMPOSITION, EACH OF WHICH CONTAINS SAME

An organopolysiloxane compound represented by average structural formula (1) is capable of imparting an electron beam curable resin with high antistatic properties, while having excellent antistatic performance durability.

##STR00001##

(In the formula, Z represents a single bond or a group having a functionality of 2-20 and containing an organopolysiloxane structure; R.sup.1 represents a single bond, or an unsubstituted or substituted alkylene group having 1-20 carbon atoms; each of R.sup.2 and R.sup.3 represents an unsubstituted or substituted alkyl group having 1-10 carbon atoms, or the like; Y represents a monovalent hydrocarbon group having a polymerizable reactive group; each of p and q represents a number of 1-10, with (p+q) being 2-20 in accordance with the valence of Z; and in cases where Z represents a single bond, p and q represent 1, A.sup.− represents an anion and Q.sup.+ represents a cationic group that is represented by one of formulae (2)-(4)

##STR00002##

(wherein each one of R.sup.4-R.sup.10 represents an alkyl group having 1-20 carbon atoms, or the like; each one of R.sup.11-R.sup.13 represents a hydrogen atom or the like; and * represents a bonding hand).)

Organopolysiloxane compound, method for producing same, and antistatic agent and curable composition, each of which contains same

An organopolysiloxane compound represented by average structural formula (1) is capable of imparting an electron beam curable resin with high antistatic properties, while having excellent antistatic performance durability. ##STR00001##
(In the formula, Z represents a single bond or a group having a functionality of 2-20 and containing an organopolysiloxane structure; R.sup.1 represents a single bond, or an unsubstituted or substituted alkylene group having 1-20 carbon atoms; each of R.sup.2 and R.sup.3 represents an unsubstituted or substituted alkyl group having 1-10 carbon atoms, or the like; Y represents a monovalent hydrocarbon group having a polymerizable reactive group; each of p and q represents a number of 1-10, with (p+q) being 2-20 in accordance with the valence of Z; and in cases where Z represents a single bond, p and q represent 1, A.sup.? represents an anion and Q.sup.+ represents a cationic group that is represented by one of formulae (2)-(4) ##STR00002##
(wherein each one of R.sup.4-R.sup.10 represents an alkyl group having 1-20 carbon atoms, or the like; each one of R.sup.11-R.sup.13 represents a hydrogen atom or the like; and * represents a bonding hand).)

Method for producing silica gel-immobolized phosphonium salt catalysts

Disclosed herein is a method for producing silica gel-immobilized phosphonium salt catalysts including the steps of (a) reacting a silane compound with a silica gel in the presence of xylene, to obtain a catalyst precursor having a haloalkyl group or a haloaryl group, wherein the silane compound has a haloalkyl group or a haloaryl group, and a proportion of the silane compound is from 0.001 to 0.06 mol relative to 1 mol of the silica gel, and (b) reacting the catalyst precursor with a tertiary phosphine in xylene, to obtain a catalyst for synthesizing a cyclic carbonate, in which the silane compound is represented by formula (1), and the tertiary phosphine is represented by formula (2):
XR.sup.1Si(OR.sup.2).sub.3(1) ##STR00001##

Functionalized ionic liquid electrolytes for lithium ion batteries

An ionic liquid that is a salt has a Formula: ##STR00001##
Such ionic liquids may be used in electrolytes and in electrochemical cells.

Reactive ionic liquid, and ion-immobilized metal oxide particle, ion-immobilized elastomer, and transducer using same

An ion-immobilized metal oxide particle includes a metal oxide particle and an anion that itself includes a) a reactive group that consists of an alkoxysilyl group and b) an anionic group consisting of a carboxylate (COO.sup.) group or a sulfonate (SO.sub.3.sup.) group, the anion being immobilized to the metal oxide particle via a silanol group derived from the reactive group. An elastomer includes the ion-immobilized metal oxide particle, and a transducer includes the elastomer.