The present disclosure provides a boron-heterocyclic compound having a structure represented by Chemical Formula 1, in which L.sub.1 and L.sub.2 are each independently selected from a single bond, C6-C30 aryl, C6-C30 fused aryl, C4-C30 heteroaryl, or C4-C30 fused heteroaryl; and R.sub.1 and R.sub.2 are each independently selected from carbazolyl and derivative groups thereof, acridinyl and derivative groups thereof, and diarylamino and derivative groups thereof. In an embodiment, the boron-heterocyclic structure is suitable for use not only as an electron acceptor group but also as a linking group. By linking a group having a large steric hindrance to the boron atom of the boron-heterocyclic ring, the compound molecules are prevented or limited from aggregating, and thus a π-aggregation or excimer formed by direct accumulation of conjugate planes is avoided or reduced, thereby improving luminous efficiency. The present disclosure further provides a display panel and a display apparatus containing the compound. ##STR00001##

Disclosed are a pincer-type ligand having a structurally rigid acridane structure and a metal complex consisting of the pincer-type ligand and a metal bound to each other, and exhibiting high reactivity and stability during a variety of bonding activation reactions. T-shaped complexes can be prepared from .sup.acriPNP(4,5-bis(diisopropylphosphino)-2,7,9,9-tetramethyl-9H-acridin-10-ide), which is a pincer-type PNP ligand having an acridane structure, and metal complexes, which can be structurally rigid and thus exhibit excellent reactivity and stability based on minimized structural change thereof, can be prepared by introducing an acridane structure into the backbone thereof. The PNP ligand is structurally stable and has novel chemical properties, as compared to conventional similar ligands, and thus can be utilized in a wide range of catalytic reactions and material chemistry.

Disclosed are a pincer-type ligand having a structurally rigid acridane structure and a metal complex consisting of the pincer-type ligand and a metal bound to each other, and exhibiting high reactivity and stability during a variety of bonding activation reactions. T-shaped complexes can be prepared from .sup.acriPNP(4,5-bis(diisopropylphosphino)-2,7,9,9-tetramethyl-9H-acridin-10-ide), which is a pincer-type PNP ligand having an acridane structure, and metal complexes, which can be structurally rigid and thus exhibit excellent reactivity and stability based on minimized structural change thereof, can be prepared by introducing an acridane structure into the backbone thereof. The PNP ligand is structurally stable and has novel chemical properties, as compared to conventional similar ligands, and thus can be utilized in a wide range of catalytic reactions and material chemistry.

Display comprising at least one organic light emitting diode, wherein the at least one organic light emitting diode comprises an anode, a cathode, a light emitting layer between the anode and the cathode, and at least one layer comprising a compound according to formula (I) between the cathode and the light emitting layer: ##STR00001## wherein A.sup.1 and A.sup.2 are independently selected from halogen, CN, substituted or unsubstituted C.sub.1-C.sub.20-alkyl or heteroalkyl, C.sub.6-C.sub.20-aryl or C.sub.5-C.sub.20-heteroaryl, C.sub.1-C.sub.20-alkoxy or C.sub.6-C.sub.20-aryloxy, A.sup.3 is selected from substituted or unsubstituted C.sub.6-C.sub.40-aryl or C.sub.5-C.sub.40-heteroaryl, m=0, 1 or 2, n=0, 1 or 2.

Display comprising at least one organic light emitting diode, wherein the at least one organic light emitting diode comprises an anode, a cathode, a light emitting layer between the anode and the cathode, and at least one layer comprising a compound according to formula (I) between the cathode and the light emitting layer: ##STR00001## wherein A.sup.1 and A.sup.2 are independently selected from halogen, CN, substituted or unsubstituted C.sub.1-C.sub.20-alkyl or heteroalkyl, C.sub.6-C.sub.20-aryl or C.sub.5-C.sub.20-heteroaryl, C.sub.1-C.sub.20-alkoxy or C.sub.6-C.sub.20-aryloxy, A.sup.3 is selected from substituted or unsubstituted C.sub.6-C.sub.40-aryl or C.sub.5-C.sub.40-heteroaryl, m=0, 1 or 2, n=0, 1 or 2.

Fluorescence quenching nitrodiarylethene analogs are useful in oligonucleotide conjugates and probes. These analogs, whose absorption spectra are substantially blue-shifted relatively to emission spectra of common fluorophores (such as fluorescein), do not need to rely on spectral overlap of quencher absorbance and fluorophore's emission for their quenching abilities. The oligonucleotide-quencher conjugates may be used in detection methods for nucleic acid targets.

An organic light-emitting device includes a first electrode; a second electrode facing the first electrode; and an organic layer between the first electrode and the second electrode, the organic layer including an emission layer. The emission layer includes at least one heterocyclic compound of Formula 1. The heterocyclic compound may be a host or a delayed fluorescent dopant. The organic light-emitting device including the heterocyclic compound may have a low driving voltage, high efficiency, high luminance, and a long lifespan.

An organic light-emitting device includes a first electrode; a second electrode facing the first electrode; and an organic layer between the first electrode and the second electrode, the organic layer including an emission layer. The emission layer includes at least one heterocyclic compound of Formula 1. The heterocyclic compound may be a host or a delayed fluorescent dopant. The organic light-emitting device including the heterocyclic compound may have a low driving voltage, high efficiency, high luminance, and a long lifespan.

Sulfonated 2(7)-aminoacridone and 1-aminopyrene dyes and their use as fluorescent tags, in particular for carbohydrate analysis The invention relates to fluorescent dyes with multiple negatively charged groups in their ionized form which are aminoacridone sulfonamides or 1-aminopyrenes having of one of the following general formulae A-D: Formula (A), Formula (B), Formula (C), Formula (D), wherein the ionizable groups X are typically selected from the following: SH, COOH, SO.sub.3H, OSO.sub.3H, OP(O)(OH).sub.2, OP(O)(OH)R.sup.a, P(O)(OH).sub.2, P(O)(OH)R.sup.a, where R.sup.a═C.sub.1-C.sub.4alkyl or substituted C.sub.1-C.sub.4alkyl. The invention further relates to the use of these dyes as fluorescent tags, in particular for reducing sugars and glycans.

##STR00001##

The present invention relates to an electrically doped semiconducting material comprising at least one metallic element as n-dopant and at least one electron transport matrix compound comprising at least one phosphine oxide group, a process for its preparation, and an electronic device comprising the electrically doped semiconducting material.