A vitrimer composition includes a first plurality of polymer backbones cross-linked with cross-linkers that include at least one siloxane moiety having formula 1:

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wherein R.sub.1, R.sub.2, R.sub.3, and R.sub.4 are each independently H or C.sub.1-6 alkyl. A catalyst that accelerates siloxane exchange is dispersed within the first plurality of polymer backbones.

A vitrimer composition includes a first plurality of polymer backbones cross-linked with cross-linkers that include at least one siloxane moiety having formula 1:

##STR00001##

wherein R.sub.1, R.sub.2, R.sub.3, and R.sub.4 are each independently H or C.sub.1-6 alkyl. A catalyst that accelerates siloxane exchange is dispersed within the first plurality of polymer backbones.

The invention relates to a procatalyst for polymerization of olefins. The invention also relates to a process for preparing said procatalyst. Furthermore, the invention is directed to a catalyst system for polymerization of olefins comprising the said procatalyst, a co-catalyst and optionally an external electron donor; a process of preparing polyolefins by contacting an olefin with said catalyst system and to polyolefins obtained or obtainable by said process. The invention also relates to the use of said procatalyst in the polymerization of olefins.

The invention relates to a procatalyst for polymerization of olefins. The invention also relates to a process for preparing said procatalyst. Furthermore, the invention is directed to a catalyst system for polymerization of olefins comprising the said procatalyst, a co-catalyst and optionally an external electron donor; a process of preparing polyolefins by contacting an olefin with said catalyst system and to polyolefins obtained or obtainable by said process. The invention also relates to the use of said procatalyst in the polymerization of olefins.

A process for treatment of nanoparticles of mineral filler for obtaining 5 processed nanoparticles for use in polymerization in the presence of nanopartciles which includes the steps of (a) drying a mineral filler with an inert gas for remove catalyst poisons; (b) mixing the mineral filler dried obtained in step (a) with a swelling agent in a liquid state or near a critical state or in the supercritical state; (c) subjecting the swelling agent of the 10 mixture obtained in step (b) to an endoenthalpic or isoentalphic phase change by altering the conditions of the temperature and/or pressure; (d) subjecting the nanoparticles of the mixture obtained in step (c) to contact of scavenging agent to react with catalyst poisons; then the mixture obtained in step (d) can be dried in a step (e) with an inert gas to remove sub-products 15 from scavenging agent and catalyst poisons to obtain the treated nanoparticles.

A process for treatment of nanoparticles of mineral filler for obtaining 5 processed nanoparticles for use in polymerization in the presence of nanopartciles which includes the steps of (a) drying a mineral filler with an inert gas for remove catalyst poisons; (b) mixing the mineral filler dried obtained in step (a) with a swelling agent in a liquid state or near a critical state or in the supercritical state; (c) subjecting the swelling agent of the 10 mixture obtained in step (b) to an endoenthalpic or isoentalphic phase change by altering the conditions of the temperature and/or pressure; (d) subjecting the nanoparticles of the mixture obtained in step (c) to contact of scavenging agent to react with catalyst poisons; then the mixture obtained in step (d) can be dried in a step (e) with an inert gas to remove sub-products 15 from scavenging agent and catalyst poisons to obtain the treated nanoparticles.

Processing aid for aiding in orienting an extruded film layer including a preponderance, by weight, of a high crystal-line polypropylene is a crystalline polypropylene wax. An oriented film layer including a blend of crystalline polypropylene wax and high crystallinity polypropylene homopolymer is part of the invention. The invention includes a method of forming an oriented film layer including a preponderance by weight of a high crystallinity polypropylene and includes the steps of blending a high crystallinity polypropylene with a crystalline polypropylene wax, directing the blend through an extruder to form a film layer and then orienting the film layer. The invention includes a biaxially oriented, multi-layer film including a base layer and at least one skin layer. The base layer includes a blend of crystalline metallocene catalyzed polypropylene wax and a high crystallinity polypropylene.

Processing aid for aiding in orienting an extruded film layer including a preponderance, by weight, of a high crystal-line polypropylene is a crystalline polypropylene wax. An oriented film layer including a blend of crystalline polypropylene wax and high crystallinity polypropylene homopolymer is part of the invention. The invention includes a method of forming an oriented film layer including a preponderance by weight of a high crystallinity polypropylene and includes the steps of blending a high crystallinity polypropylene with a crystalline polypropylene wax, directing the blend through an extruder to form a film layer and then orienting the film layer. The invention includes a biaxially oriented, multi-layer film including a base layer and at least one skin layer. The base layer includes a blend of crystalline metallocene catalyzed polypropylene wax and a high crystallinity polypropylene.

Polypropylenes and impact copolymers with low organic volatiles. The impact copolymers comprising a polypropylene and within a range from 5 wt% to 40 wt% of an ethylene-propylene copolymer or rubber, by weight of the impact copolymer; wherein the polypropylene has a melt flow rate within a range from 100 g/10 min to 400 g/10 min, and the impact copolymer has a melt flow rate within a range from 15 g/10 min to 150 g/10 min; and wherein there are less than 1000 .Math.g of oligomer per gram of impact copolymer. The polymers may be made by combining olefins with the reaction product of a solid magnesium compound and a halogen-containing titanium compound with at least one phthalic acid ester compound and at least one diether compound as internal electron donors.

Polypropylenes and impact copolymers with low organic volatiles. The impact copolymers comprising a polypropylene and within a range from 5 wt% to 40 wt% of an ethylene-propylene copolymer or rubber, by weight of the impact copolymer; wherein the polypropylene has a melt flow rate within a range from 100 g/10 min to 400 g/10 min, and the impact copolymer has a melt flow rate within a range from 15 g/10 min to 150 g/10 min; and wherein there are less than 1000 .Math.g of oligomer per gram of impact copolymer. The polymers may be made by combining olefins with the reaction product of a solid magnesium compound and a halogen-containing titanium compound with at least one phthalic acid ester compound and at least one diether compound as internal electron donors.