Provided in this patent disclosure are two types of novel fluoro-monomers that can be polymerized for the fabrication of ion-exchange fluoropolymers. In addition, new proton-conductive zirconium-perfluorophosphonic acid fluoropolymer membranes that can reduce metal crossovers in redox flow batteries are also provided.

A method for producing an iodine-containing compound includes reacting a halogen-containing organic iodine compound and a compound containing a reactive carbon-carbon double bond in the presence of a compound of Formula (21) or Formula (22). Each of R.sup.21, R.sup.23 and R.sup.24 represents a hydrogen atom, an iodine atom, or an organic group having from 1 to 20 carbon atoms; R.sup.22 represents a hydrogen atom, an iodine atom, an organic group having from 1 to 20 carbon atoms, or a boron-containing group; R.sup.25 represents a hydrogen atom, an iodine atom, an organic group having from 1 to 20 carbon atoms, or a silicon-containing group; and each of A.sup.1 and A.sup.2 represents a hydrogen atom, a chlorine atom, a bromine atom, or an iodine atom.

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The present invention provides a surface-treating agent comprising a fluorine-containing compound having a carbon-carbon unsaturated bond at its molecular terminal as a group of —Y-A wherein Y is a single bond, an oxygen atom or a divalent organic group, and A is —CH═CH.sub.2 or —C≡CH, which is able to form a layer having higher alkaline resistance.

The present invention provides a surface-treating agent comprising a fluorine-containing compound having a carbon-carbon unsaturated bond at its molecular terminal as a group of —Y-A wherein Y is a single bond, an oxygen atom or a divalent organic group, and A is —CH═CH.sub.2 or —C≡CH, which is able to form a layer having higher alkaline resistance.

A surface-treating agent including a fluorine-containing compound having a carbon-carbon unsaturated bond at its molecular terminal as a group of —Y-A wherein Y is a single bond, an oxygen atom or a divalent organic group, and A is —CH═CH.sub.2 or —C≡CH, which is able to form a layer having higher alkaline resistance.

A surface-treating agent including a fluorine-containing compound having a carbon-carbon unsaturated bond at its molecular terminal as a group of —Y-A wherein Y is a single bond, an oxygen atom or a divalent organic group, and A is —CH═CH.sub.2 or —C≡CH, which is able to form a layer having higher alkaline resistance.

Described herein is method of making branched perfluorinated compounds, specifically (CF.sub.3).sub.2CFCF(CF.sub.3)OCF(CF.sub.3)C(═O)F and (CF.sub.3).sub.2CFCF(CF.sub.3)OCF═CF.sub.2. Also disclosed herein is a fluoropolymer derived from the branched perfluorovinyl ether monomer and methods of making the fluoropolymer.

Provided is a water repellent oil repellent agent composition capable of producing an article having excellent oil repellency. A water repellent oil repellent agent composition containing a fluorine-containing polymer comprising a unit based on a monomer (a) shown below and a unit based on a monomer (b) shown below.

Monomer (a): a compound represented by CH.sub.2═CH—[CH.sub.2CH.sub.2].sub.p—[CF.sub.2CF.sub.2].sub.q—[OCF.sub.2CF(CF.sub.3)].sub.r—O—C.sub.3F.sub.7
In the formula, p represents an integer of 0 to 4, q represents an integer of 1 to 4, and r represents an integer of 1 to 4.
Monomer (b): another monomer that is copolymerizable with the monomer (a).

A process for the preparation of perhaloacyl peroxides from perhaloacyl halides which is performed in the presence of a hydrofluoroether as the solvent.

To provide an organic photoelectronic element excellent in light emitting characteristics and long-term reliability. The organic photoelectronic element comprises a substrate, an anode provided on the substrate, a cathode facing the anode, a light emitting layer disposed between the anode and the cathode, a hole transport layer disposed between the light emitting layer and the anode, and an electron blocking layer provided in contact with the light emitting layer and the hole transport layer between the light emitting layer and the hole transport layer, wherein the hole transport layer contains a fluorinated polymer and an organic semiconductor material, and has a refractive index in the wavelength range of from 450 nm to 800 nm, of at most 1.60, the hole transport layer and the electron blocking layer are made of different materials from each other, and the LUMO energy level of the electron blocking layer is higher than the LUMO energy level of the light emitting layer and the LUMO energy level of the hole transfer layer.